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1. 发明授权

US09527067B2 Inorganic/polymeric hybrid catalytic materials containing metal nano-particles therein 有权
标题翻译：其中含有金属纳米颗粒的无机/聚合物杂化催化材料
公开(公告)号：US09527067B2
公开(公告)日：2016-12-27
申请号：US14129009
申请日：2011-06-24
申请人： Haruo Sawa , Pierluigi Barbaro , Claudio Bianchini , Francesca Liguori
发明人： Haruo Sawa , Pierluigi Barbaro , Claudio Bianchini , Francesca Liguori
IPC分类号： B01J21/00 , B01J23/00 , B01J25/00 , B01J29/00 , B01J31/00 , B01J31/12 , B01D67/00 , B01D69/14 , B01J31/16 , B01J35/06 , B01J21/06 , B01J21/08 , B01J23/38 , B01J23/44 , B01J23/46 , B01J23/52 , B01J23/70 , B01J37/02 , B01D71/38 , B01J37/06 , B01J37/16 , B01J37/18 , B01J23/42 , B01J23/50 , B01J35/00
CPC分类号： B01J31/123 , B01D67/0079 , B01D69/145 , B01D69/148 , B01D71/38 , B01D2325/10 , B01J21/066 , B01J21/08 , B01J23/38 , B01J23/42 , B01J23/44 , B01J23/462 , B01J23/464 , B01J23/50 , B01J23/52 , B01J23/70 , B01J31/069 , B01J31/165 , B01J35/0013 , B01J35/002 , B01J35/006 , B01J35/065 , B01J37/0203 , B01J37/0209 , B01J37/06 , B01J37/16 , B01J37/18 , B01J2231/645 , B01J2531/824 , C08F8/42 , Y02E60/522 , Y02E60/523 , C08F216/06
摘要： Catalytic materials with high activity in various chemical reactions as well as high durability are described. The catalytic materials are composed of specific, hybrid combinations of inorganic/polymeric compounds containing metal nano-particles therein, and can be easily reused with negligible catalysts leaching. They are particularly useful, but not limited to, the hydrogenation of substituted α,β unsaturated acids or esters.
摘要翻译：描述了在各种化学反应中具有高活性的催化材料以及高耐久性。催化材料由其中含有金属纳米颗粒的无机/聚合物的特定杂化组合组成，并且可以容易地用可忽略的催化剂浸出再利用。它们特别有用但不限于取代的α，β不饱和酸或酯的氢化。

2. 发明申请

US20130035225A1 ORGANIC/INORGANIC HYBRID CATALYTIC MATERIALS, THEIR PREPARATION, USE IN SELECTIVE PROCESSES AND REACTORS CONTAINING THEM 审中-公开
标题翻译：有机/无机混合催化材料，其制备，在选择过程中使用及其含有的反应物
公开(公告)号：US20130035225A1
公开(公告)日：2013-02-07
申请号：US13120470
申请日：2010-03-31
申请人： Pierluigi Barbaro , Claudio Bianchini , Francesca Liguori , Haruo Sawa , Francesco Vizza
发明人： Pierluigi Barbaro , Claudio Bianchini , Francesca Liguori , Haruo Sawa , Francesco Vizza
IPC分类号： B01J31/06 , B01J31/22 , B01J31/24 , B01J31/16
CPC分类号： B01J31/069 , B01J31/1683 , B01J31/1691 , B01J31/2226 , B01J31/2295 , B01J31/2414 , B01J31/2447 , B01J31/2466 , B01J2231/645 , B01J2531/0266 , B01J2531/0272 , B01J2531/18 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/847 , C07B53/00 , C07B2200/07 , C07C231/18 , C07C233/47
摘要： A low cost, viable and modular method to prepare new, highly selective catalytic materials, especially “catalytic membranes”, is described. A method for the engineering and use of various types of reactors based on these catalytic membranes, even in a one-pot procedure, is also disclosed. The catalytic membranes are versatile, in terms of variety of chemical reactions promoted, and can be easily reused with negligible catalysts leaching. They are particularly useful, but not limited to, the asymmetric hydrogenation of substituted α,β unsaturated acids or esters.
摘要翻译：描述了制备新的高选择性催化材料，特别是催化膜的低成本，可行和模块化方法。还公开了一种用于基于这些催化膜的各种类型的反应器的工程和使用的方法，甚至在一锅法中。催化膜在多种促进的化学反应方面是通用的，并且可以容易地用可忽略的催化剂浸出再利用。它们特别有用，但不限于取代的α，bgr的不对称氢化; 不饱和酸或酯。

3. 发明申请

US20150005154A1 INORGANIC/POLYMERIC HYBRID CATALYTIC MATERIALS WITH HIGH ACTIVITY IN VARIOUS SOLVENTS 有权
标题翻译：在各种溶剂中具有高活性的无机/聚合物混合催化材料
公开(公告)号：US20150005154A1
公开(公告)日：2015-01-01
申请号：US14378207
申请日：2012-02-14
申请人： Haruo Sawa , Pierluigi Barbaro , Claudio Bianchini , Francesca Liguori , Masatoshi Sashika
发明人： Haruo Sawa , Pierluigi Barbaro , Claudio Bianchini , Francesca Liguori , Masatoshi Sashika
IPC分类号： B01J31/38 , B01J31/34
CPC分类号： B01J31/38 , B01D67/0079 , B01D69/145 , B01D69/148 , B01D71/024 , B01D71/38 , B01D71/70 , B01J21/066 , B01J21/08 , B01J23/30 , B01J23/40 , B01J23/44 , B01J23/48 , B01J23/70 , B01J31/068 , B01J31/069 , B01J31/127 , B01J31/34 , B01J35/0013 , B01J35/006 , B01J2231/645 , B01J2531/824
摘要： Catalytic materials, particularly membranes, exhibiting high activity, high stability and low metal leaching in a variety of chemical reactions, particularly selective hydrogenations of unsaturated organic compounds, are described. These membranes are inorganic/polymeric hybrid materials in which metal complex molecular catalysts are immobilized or metal nano-particle catalysts are embedded. More specifically, the catalytic materials of the present invention exhibit higher activity and selectivity, and can be used in more extensive kinds of organic solvents than the conventional hybrid catalytic materials due to improvement in the affinity to organic solvents by containing the specific polymeric additives.
摘要翻译：描述了在各种化学反应，特别是不饱和有机化合物的选择性氢化中表现出高活性，高稳定性和低金属浸出的催化材料，特别是膜。这些膜是固定金属络合物分子催化剂或嵌入金属纳米颗粒催化剂的无机/聚合物混合材料。更具体地说，本发明的催化剂材料表现出更高的活性和选择性，并且由于通过含有特定的聚合物添加剂而改善对有机溶剂的亲和性，可以比常规的混合催化材料使用更广泛的有机溶剂。

4. 发明申请

US20090068531A1 SOLID ELECTROLYTE WITH HIGH ION-CONDUCTIVITY AND METHOD FOR MANUFACTURING THE SAME, AND ELECTROCHEMICAL SYSTEM USING SOLID ELECTROLYTE 有权
标题翻译：具有高导电性的固体电解质及其制造方法，以及使用固体电解质的电化学系统
公开(公告)号：US20090068531A1
公开(公告)日：2009-03-12
申请号：US12165860
申请日：2008-07-01
申请人： Haruo SAWA , Haruyuki Nakanishi , Shinichi Matsumoto
发明人： Haruo SAWA , Haruyuki Nakanishi , Shinichi Matsumoto
IPC分类号： H01M8/10 , H01M6/18 , G01N27/26 , C25B9/00 , C01G25/02 , C01B35/12 , C01B33/20 , C01F7/02
CPC分类号： C25B13/08 , C08J5/2256 , C08J5/2268 , C08J2329/04 , C08J2379/04 , H01M6/181 , H01M6/188 , H01M8/0289 , H01M8/1027 , H01M8/103 , H01M8/1046 , H01M8/1072 , H01M10/056 , H01M10/26 , H01M10/347 , H01M2300/0082 , H01M2300/0091 , Y02P70/56
摘要： The present invention provides a solid electrolyte with high ion-conductivity which is cheap and exhibits high conductivity in an alkaline form, and stably keeps high conductivity because of a small amount of the leak of a compound bearing conductivity even in a wet state. The invention is useful in an electrochemical system using the solid electrolyte, such as a fuel cell.The solid electrolyte with high ion-conductivity comprises a hybrid compound which contains at least polyvinyl alcohol and a zirconic acid compound, and also a nitrogen-containing organic compound having a structure of amine, quaternary ammonium compound and/or imine, obtained by hydrolyzing a zirconium salt or an oxyzirconium salt in a solution including water, polyvinyl alcohol, a zirconium salt or an oxyzirconium salt and a nitrogen-containing organic compound having a structure of amine, quaternary ammonium compound and/or imine coexist, removing a solvent and contacting with alkali.
摘要翻译：本发明提供一种廉价且具有高导电性的碱性形式的高离子电导率的固体电解质，并且由于即使在潮湿状态下也具有导电性的化合物的泄漏量少，因而稳定地保持高导电性。本发明在使用诸如燃料电池的固体电解质的电化学系统中是有用的。具有高离子传导性的固体电解质包括至少包含聚乙烯醇和锆酸化合物的杂化化合物，以及具有胺，季铵化合物和/或亚胺结构的含氮有机化合物，其通过水解锆盐或氧锆盐在包括水，聚乙烯醇，锆盐或氧锆盐的溶液中，以及具有胺，季铵化合物和/或亚胺结构的含氮有机化合物共存，除去溶剂并与碱。

5. 发明授权

US06838210B2 Solid electrolyte with high ion conductivity and electrochemical system using the solid electrolyte 有权
标题翻译：具有高离子电导率的固体电解质和使用固体电解质的电化学系统
公开(公告)号：US06838210B2
公开(公告)日：2005-01-04
申请号：US10359063
申请日：2003-02-06
申请人： Haruo Sawa
发明人： Haruo Sawa
IPC分类号： H01B1/06 , C25B13/04 , H01B1/12 , H01M6/06 , H01M6/18 , H01M8/02 , H01M8/10 , H01M10/26 , H01M10/08 , C25C7/00
CPC分类号： H01M10/347 , C25B13/04 , H01B1/122 , H01M6/181 , H01M8/0289 , H01M8/1023 , H01M8/1048 , H01M2300/0082 , H01M2300/0091
摘要： It is an object to provide a high ion conductive solid electrolyte which uses organic and inorganic complex compound having water absorption and water resistance and to provide an electrochemical system using the high ion conductive solid electrolyte. The high ion conductive solid electrolyte is composed of a complex compound including water that has zirconic acid compound and polyvinyl alcohol. An aqueous solution in which zirconium salt or oxyzirconnium salt and polyvinyl alcohol are dissolved is neutralized by alkali. After removing water used as solvent, unnecessary salts are removed from the neutralized solution. The high ion conductive solid electrolyte is obtained which is composed of the complex compound having zirconic acid compound, polyvinyl alcohol, and water. Various electrochemical systems are obtained each of which use the high ion conductive solid electrolyte.
摘要翻译：本发明的目的是提供使用具有吸水性和耐水性的有机和无机复合化合物的高离子传导性固体电解质，并提供使用高离子传导性固体电解质的电化学系统。高离子导电固体电解质由包含具有锆酸化合物和聚乙烯醇的水的络合物组成。其中锆盐或氧化锆鎓盐和聚乙烯醇溶解的水溶液被碱中和。除去用作溶剂的水后，从中和溶液中除去不需要的盐。得到由具有锆酸化合物，聚乙烯醇和水的络合物组成的高离子传导性固体电解质。获得各种使用高离子传导性固体电解质的电化学系统。

6. 发明授权

US5865982A Process for preparing compound 失效
标题翻译：化合物的制备方法
公开(公告)号：US5865982A
公开(公告)日：1999-02-02
申请号：US876981
申请日：1997-06-16
申请人： Haruo Sawa , Hidetoshi Abe
发明人： Haruo Sawa , Hidetoshi Abe
IPC分类号： C07B61/00 , B01J15/00 , B01J16/00 , B01J19/00 , C07C1/04 , C25B1/00 , C25B3/00
CPC分类号： B01J16/005 , B01J15/005 , C07C1/0485
摘要： Disclosed is a novel process for preparing a compound, in which materials difficult to prepare at low temperature can be prepared even if the temperature is such a low temperature as room temperature. In this process, a solid catalyst is disposed in a vessel, a sub-reaction field f is formed on the surface of the solid catalyst, and materials for reaction are supplied to the sub-reaction field f whereby the reaction is progressed to synthesize an objective compound.
摘要翻译：公开了一种制备化合物的新方法，其中即使温度如此低的室温也可制备难以在低温下制备的材料。在该方法中，将固体催化剂设置在容器中，在固体催化剂的表面上形成副反应场f，将反应物质供给到副反应场f，由此进行反应以合成目的化合物。

7. 发明申请

US20140128251A1 INORGANIC/POLYMERIC HYBRID CATALYTIC MATERIALS CONTAINING METAL NANO-PARTICLES THEREIN 有权
标题翻译：含有金属纳米颗粒的无机/聚合物混合催化材料
公开(公告)号：US20140128251A1
公开(公告)日：2014-05-08
申请号：US14129009
申请日：2011-06-24
申请人： Haruo Sawa , Pierluigi Barbaro , Claudio Bianchini , Francesca Liguori
发明人： Haruo Sawa , Pierluigi Barbaro , Claudio Bianchini , Francesca Liguori
IPC分类号： B01J31/12
CPC分类号： B01J31/123 , B01D67/0079 , B01D69/145 , B01D69/148 , B01D71/38 , B01D2325/10 , B01J21/066 , B01J21/08 , B01J23/38 , B01J23/42 , B01J23/44 , B01J23/462 , B01J23/464 , B01J23/50 , B01J23/52 , B01J23/70 , B01J31/069 , B01J31/165 , B01J35/0013 , B01J35/002 , B01J35/006 , B01J35/065 , B01J37/0203 , B01J37/0209 , B01J37/06 , B01J37/16 , B01J37/18 , B01J2231/645 , B01J2531/824 , C08F8/42 , Y02E60/522 , Y02E60/523 , C08F216/06
摘要： Catalytic materials with high activity in various chemical reactions as well as high durability are described. The catalytic materials are composed of specific, hybrid combinations of inorganic/polymeric compounds containing metal nano-particles therein, and can be easily reused with negligible catalysts leaching. They are particularly useful, but not limited to, the hydrogenation of subsituted α,β unsaturated acids or esters.
摘要翻译：描述了在各种化学反应中具有高活性的催化材料以及高耐久性。催化材料由其中含有金属纳米颗粒的无机/聚合物的特定杂化组合组成，并且可以容易地用可忽略的催化剂浸出再利用。它们特别有用，但不限于，取代的α，bgr的氢化; 不饱和酸或酯。

8. 发明授权

US07396616B2 Solid electrolyte and electrochemical system using the solid electrolyte 有权
标题翻译：固体电解质和电化学系统使用固体电解质
公开(公告)号：US07396616B2
公开(公告)日：2008-07-08
申请号：US10765862
申请日：2004-01-29
申请人： Haruo Sawa
发明人： Haruo Sawa
IPC分类号： H01M8/10 , H01M10/08
CPC分类号： H01M6/181 , B01D53/32 , C02F1/4618 , C02F2201/46195 , C25B13/08 , H01M8/04197 , H01M8/04291 , H01M8/1023 , H01M8/1081 , H01M2300/0082 , H01M2300/0091 , Y02P70/56
摘要： It is an object to provide a solid electrolyte and an electrochemical system using the solid electrolyte which has a little expansion (swelling) and whose strength does not decrease in case of positioning the solid electrolyte including a complex compound composed of an inorganic compound, polyvinyl alcohol, and water, in a wet condition. It is possible to use the solid electrolyte in a device such as a fuel cell or an electrolytic device used with the wet condition. The solid electrolyte has a little size variation even if humidity varies and has a low methanol permeability. The solid electrolyte is produced by replacing a part or all of hydroxyl groups of polyvinyl alcohol domain to groups each of which has a water absorption less than that of said hydroxyl group, in the solid electrolyte including a complex compound which is composed of polyvinyl alcohol, water, and at least one inorganic compound selected from silicic acid compound, tungstic acid compound, molybdic acid compound, stannic acid compound, and zirconic acid compound.
摘要翻译：本发明的目的是提供一种使用固体电解质的固体电解质和电化学体系，所述固体电解质具有很小的膨胀（膨胀），并且在将含有由无机化合物构成的络合物的固体电解质，聚乙烯醇，和水，在潮湿的条件。可以在诸如燃料电池或与潮湿条件一起使用的电解装置的装置中使用固体电解质。固体电解质即使湿度变化且甲醇渗透性低，也具有小的变化。固体电解质是通过将聚乙烯醇结构域的一部分或全部的羟基替换为比所述羟基的吸水率小的基团而制造的固体电解质，其包含由聚乙烯醇，水和至少一种选自硅酸化合物，钨酸化合物，钼酸化合物，锡酸化合物和锆酸化合物的无机化合物。

9. 发明授权

US07101638B2 Ionic conductive solid electrolyte, method of manufacturing the same and electrochemical system using the same 有权
公开(公告)号：US07101638B2
公开(公告)日：2006-09-05
申请号：US10263958
申请日：2002-10-04
申请人： Haruo Sawa
发明人： Haruo Sawa
IPC分类号： H01M8/10
CPC分类号： H01M10/052 , H01M10/056
摘要： An object of the present invention is to provide a low cost and highly ionic conductive solid electrolyte which is an organic-inorganic composite compound and is water-absorbing as well as water-resistive. Another object of the present invention is to provide electrochemical systems utilizing the above-mentioned electrolyte. The solid electrolyte of the present invention is a composite compound comprising tungstic and/or molybdic acid compound and polyvinylalcohol (PVA), and containing water. Tungstate and/or molybdate and other salt are neutralized by an acid in the aqueous solution dissolving PVA. Then, the water as the solvent of the aqueous solution is removed, and then the unnecessary salts are removed, thereby obtaining the composite compound.

10. 发明申请

US20060008692A1 Solid electrolyte and electrochemical system including the solid electrolyte 审中-公开
标题翻译：固体电解质和电化学系统包括固体电解质
公开(公告)号：US20060008692A1
公开(公告)日：2006-01-12
申请号：US11149248
申请日：2005-06-10
申请人： Haruo Sawa
发明人： Haruo Sawa
IPC分类号： H01M8/10
CPC分类号： G01N27/4073 , C08F8/28 , C08F8/34 , C08F8/40 , C08F8/42 , C08K3/32 , C08K3/38 , H01B1/122 , H01M8/1048 , H01M8/1072 , H01M2300/0082 , H01M2300/0094 , Y02P70/56 , C08F16/06
摘要： Solid electrolyte comprising organic compound containing the organic polymer with hydroxyl group, inorganic compound, and water intended to provide the solid electrolyte that is less susceptible to performance deterioration even under high temperatures of 100° C. or higher and the electrochemical system using the said solid electrolyte. It is a principal object of this invention to provide the basic means for producing the solid electrolyte comprising the hybrid compound where part of or all of the hydroxyl groups of the organic polymer with hydroxyl group are combined with at least one species of phosphoric acid and boric acid by immersing the hybrid compound in the solution containing at least one species of phosphoric acid and boric acid; otherwise by coating it with the said solution. Moreover, the said hybrid compound is made by neutralizing inorganic salt by acid in the raw material solution with the organic compound containing the organic polymer with hydroxyl group coexisting, removing solvent, where the solution after the neutralization process contains at least one species of phosphoric acid and boric acid. Hereby, part of or all of the hydroxyl groups of the organic polymer with hydroxyl group are combined with at least one species of phosphoric acid and boric acid.
摘要翻译：含有含有羟基有机聚合物的有机化合物的固体电解质，无机化合物和水，即使在100℃或更高的高温下也能提供即使不影响性能劣化的固体电解质的电解质，以及使用所述固体的电化学系统电解液本发明的主要目的是提供生产包含杂化化合物的固体电解质的基本方法，其中部分或全部羟基有机聚合物的羟基与至少一种磷酸和硼酸结合将杂化化合物浸渍在含有至少一种磷酸和硼酸的溶液中; 否则通过用所述溶液涂布。此外，所述杂化化合物是通过在原料溶液中中和无机盐而制备的，其中含有具有羟基的有机聚合物的有机化合物共存，除去溶剂，其中中和过程中的溶液含有至少一种磷酸和硼酸。因此，具有羟基的有机聚合物的一部分或全部羟基与至少一种磷酸和硼酸组合。

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