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1. 发明授权

US09062266B2 Imidazolium salts as additives for fuels 有权
标题翻译：咪唑盐作燃料添加剂
公开(公告)号：US09062266B2
公开(公告)日：2015-06-23
申请号：US13761644
申请日：2013-02-07
申请人： Maxim Peretolchin , Ludwig Voelkel , Harald Boehnke , Markus Hansch , Boris Gaspar , Christian Seitz
发明人： Maxim Peretolchin , Ludwig Voelkel , Harald Boehnke , Markus Hansch , Boris Gaspar , Christian Seitz
IPC分类号： C10L10/18 , C10L1/22 , C10L1/224 , C10L1/232 , C10L10/14
CPC分类号： C10L1/232 , C10L10/14 , C10L10/18
摘要： The use of imidazolium salts (I) where R1 and R3 are each independently an organic radical having 1 to 3000 carbon atoms, R2, R4 and R5 are each independently hydrogen or an organic radical having 1 to 3000 carbon atoms, X is an anion and n is the number 1, 2 or 3 as additives for fuels, especially as detergent additives for diesel fuels, as wax antisettling additives for middle distillate fuels and as lubricity improvers, and for improving the use properties of mineral and synthetic nonaqueous industrial fluids.
摘要翻译：使用咪唑鎓盐（I），其中R 1和R 3各自独立地为具有1至3000个碳原子的有机基团，R 2，R 4和R 5各自独立地为氢或具有1至3000个碳原子的有机基团，X为阴离子， n是数字1,2或3，作为燃料的添加剂，特别是用作柴油燃料的洗涤剂添加剂，作为中间馏分燃料的蜡防沉淀添加剂和润滑性改进剂，以及用于改善矿物和合成非水性工业流体的使用性质。

2. 发明授权

US08790426B2 Quaternized terpolymer 有权
标题翻译：季铵化三元共聚物
公开(公告)号：US08790426B2
公开(公告)日：2014-07-29
申请号：US13093247
申请日：2011-04-25
申请人： Ivette Garcia Castro , Cornelia Roeger-Goepfert , Wolfgang Grabarse , Klaus Muehlbach , Ludwig Voelkel , Harald Boehnke , Christian Tock
发明人： Ivette Garcia Castro , Cornelia Roeger-Goepfert , Wolfgang Grabarse , Klaus Muehlbach , Ludwig Voelkel , Harald Boehnke , Christian Tock
IPC分类号： C10L1/192 , C10L1/234
CPC分类号： C10L1/221 , C08F8/44 , C08F210/02 , C08F2800/10 , C08F2810/50 , C10L1/1641 , C10L1/1963 , C10L1/2366 , C10L1/2368 , C10L10/08 , C10L2200/0259 , C10L2230/22 , C10L2270/026 , C08F218/08 , C08F220/34 , C08F8/02 , C08F2500/02
摘要： Quaternized terpolymer formed from (A) ethylene, (B) C2-C14-alkenyl esters of one or more aliphatic C1-C20-monocarboxylic acids or C1-C24-alkyl esters of acrylic acid or of methacrylic acid and (Cq) ethylenically unsaturated monomers which comprise at least one tertiary nitrogen atom which is partly or fully in quaternized form. The quaternized terpolymer is suitable as a fuel additive for reducing or preventing deposits, for reducing fuel consumption and for minimizing power loss in direct-injection diesel engines, especially in diesel engines with common-rail injection systems.
摘要翻译：由（A）乙烯，（B）一种或多种脂族C 1 -C 20 - 一元羧酸或丙烯酸或甲基丙烯酸和（Cq）烯属不饱和单体的C 1 -C 24烷基酯形成的季铵化三元共聚物其包含部分或全部为季铵化形式的至少一个叔氮原子。季铵化三元共聚物适合用作减少或防止沉积物的燃料添加剂，用于降低燃料消耗和最小化直喷式柴油发动机，特别是在具有共轨喷射系统的柴油发动机中的功率损耗。

3. 发明申请

US20130225463A1 QUATERNIZED POLYETHER AMINES AND THEIR USE AS ADDITIVE FOR FUELS AND LUBRICANTS 审中-公开
公开(公告)号：US20130225463A1
公开(公告)日：2013-08-29
申请号：US13668985
申请日：2012-11-05
申请人： Markus HANSCH , Harald BOEHNKE , Ludwig VOELKEL , Marc WALTER , Wolfgang GRABARSE
发明人： Markus HANSCH , Harald BOEHNKE , Ludwig VOELKEL , Marc WALTER , Wolfgang GRABARSE
IPC分类号： C10L1/222 , C07C213/02 , C10M133/06 , C07C217/08
CPC分类号： C10L1/22 , C07C213/02 , C07C217/08 , C10L1/2225 , C10L1/2387 , C10L10/04 , C10L10/18 , C10L2200/0259 , C10L2200/0446 , C10L2230/14 , C10L2270/023 , C10L2270/026 , C10M133/06 , C10M133/08 , C10M149/12 , C10M2215/042 , C10M2217/041 , C10N2230/04 , C10N2240/10 , C10N2240/104
摘要： The present invention relates to novel quaternized polyetheramines and to the preparation thereof. The present invention further relates to the use of these compounds as a fuel and lubricant additive. More particularly, the invention relates to the use of these quaternized nitrogen compounds as a fuel additive for reducing or preventing deposits in the injection systems of direct injection diesel engines, especially in common rail injection systems, for reducing the fuel consumption of direct injection diesel engines, especially of diesel engines with common rail injection systems, and for minimizing power loss in direct injection diesel engines, especially in diesel engines with common rail injection systems. The invention also provides additive packages comprising these polyetheramines; and fuels and lubricants additized therewith. The invention further relates to the use of these quaternized nitrogen compounds as an additive for gasoline fuels, especially for improving the intake system cleanliness of gasoline engines.

4. 发明授权

US08911516B2 Quaternized copolymer 有权
标题翻译：季铵化共聚物
公开(公告)号：US08911516B2
公开(公告)日：2014-12-16
申请号：US13168405
申请日：2011-06-24
申请人： Wolfgang Grabarse , Hannah Maria Koenig , Christian Tock , Cornelia Roeger-Goepfert , Ludwig Voelkel , Harald Boehnke
发明人： Wolfgang Grabarse , Hannah Maria Koenig , Christian Tock , Cornelia Roeger-Goepfert , Ludwig Voelkel , Harald Boehnke
IPC分类号： C10L1/22 , C08F222/06 , C10L1/236 , C10L10/08 , C10L10/18 , C10L10/04
CPC分类号： C08F222/06 , C08F8/44 , C10L1/2364 , C10L1/2366 , C10L10/04 , C10L10/08 , C10L10/18 , C08F220/14 , C08F8/32 , C08F8/14
摘要： A quaternized copolymer obtainable by: (A) copolymerization of straight-chain, branched or cyclic, ethylenically unsaturated C2 to C100 hydrocarbons, which may bear oxygen- or nitrogen-functional substituents which cannot be reacted with amines to give amides or imides or with alcohols to give esters, with ethylenically unsaturated C3- to C12-mono- or dicarboxylic acids or acid derivatives, which can be reacted with amines to give amides or imides or with alcohols to give esters, to give a copolymer with a number-average molecular weight of 500 to 20 000; (B) partial or full amidation or imidation or esterification of the carboxylic acid functions by reacting them with oligoamines having 2 to 6 nitrogen atoms or alcoholamines, each of which comprises primary or secondary nitrogen atom or a hydroxyl group and a quaternizable tertiary nitrogen atom; (C) partial or full quaternization of the tertiary nitrogen atom with a quaternizing agent. The quaternized copolymer thus prepared is suitable as a fuel additive in direct-injection diesel engines.
摘要翻译：可以通过以下方法获得的季铵化共聚物：（A）直链，支链或环状的烯属不饱和C2至C100烃的共聚，其可承载不能与胺反应得到酰胺或酰亚胺或与醇反应的氧或氮官能取代基得到具有烯键式不饱和C 3 -C 12 - 单 - 或二羧酸或酸衍生物的酯，其可以与胺反应得到酰胺或酰亚胺或与醇反应得到酯，得到具有数均分子量的共聚物 500至20,000; （B）通过使羧酸官能团与具有2-6个氮原子的低聚胺或醇胺进行部分或完全酰化或酰化或酯化，其各自包含伯或仲氮原子或羟基和可季铵化的叔氮原子; （C）叔氮原子与季铵化剂部分或全部季铵化。如此制备的季铵化共聚物适合作为直接喷射柴油发动机中的燃料添加剂。

5. 发明申请

US20130296210A1 USE OF QUATERNIZED ALKYL AMINES AS ADDITIVE IN FUELS AND LUBRICANTS 审中-公开
标题翻译：使用季铵化的烷基胺作为燃料和润滑剂中的添加剂
公开(公告)号：US20130296210A1
公开(公告)日：2013-11-07
申请号：US13712297
申请日：2012-12-12
申请人： Markus HANSCH , Harald BOEHNKE , Ludwig VOELKEL , Wolfgang GRABARSE , Jan STRITTMATTER
发明人： Markus HANSCH , Harald BOEHNKE , Ludwig VOELKEL , Wolfgang GRABARSE , Jan STRITTMATTER
IPC分类号： C10L1/222 , C10M133/04
CPC分类号： C10L10/06 , C10L1/1881 , C10L1/1883 , C10L1/189 , C10L1/1895 , C10L1/1905 , C10L1/222 , C10L1/2222 , C10L10/04 , C10L10/18 , C10L2200/0423 , C10L2200/0446 , C10L2200/0476 , C10L2270/023 , C10L2270/026 , C10M133/04 , C10M133/06 , C10M2207/123 , C10M2207/126 , C10M2207/288 , C10M2215/04 , C10N2230/04 , C10N2240/103
摘要： The present invention relates to the use of quaternized alkylamine nitrogen compounds as a fuel additive and lubricant additive, such as, more particularly, as a detergent additive; for reduction or prevention of deposits in the injection systems of direct injection diesel engines, especially in common rail injection systems, for reduction of the fuel consumption of direct injection diesel engines, especially of diesel engines with common rail injection systems, and for minimization of power loss in direct injection diesel engines, especially in diesel engines with common rail injection systems; and as an additive for gasoline fuels, especially for operation of DISI engines.
摘要翻译：本发明涉及使用季铵化的烷基胺氮化合物作为燃料添加剂和润滑剂添加剂，尤其是作为洗涤剂添加剂; 用于减少或防止直喷式柴油发动机，特别是共轨喷射系统的喷射系统中的沉积物，用于降低直喷式柴油发动机，特别是具有共轨喷射系统的柴油发动机的燃料消耗，以及用于最小化功率直喷柴油发动机的损失，特别是在具有共轨喷射系统的柴油发动机中; 并且作为汽油燃料的添加剂，特别是用于DISI发动机的操作。

6. 发明申请

US20130205654A1 IMIDAZOLIUM SALTS AS ADDITIVES FOR FUELS 有权
标题翻译：作为燃料添加剂的咪达拉斯盐
公开(公告)号：US20130205654A1
公开(公告)日：2013-08-15
申请号：US13761644
申请日：2013-02-07
申请人： Maxim PERETOLCHIN , Ludwig VOELKEL , Harald BOEHNKE , Markus HANSCH , Boris GASPAR , Christian SEITZ
发明人： Maxim PERETOLCHIN , Ludwig VOELKEL , Harald BOEHNKE , Markus HANSCH , Boris GASPAR , Christian SEITZ
IPC分类号： C10L1/232 , C10L10/18
CPC分类号： C10L1/232 , C10L10/14 , C10L10/18
摘要： The use of imidazolium salts (I) where R1 and R3 are each independently an organic radical having 1 to 3000 carbon atoms, R2, R4 and R5 are each independently hydrogen or an organic radical having 1 to 3000 carbon atoms, X is an anion and n is the number 1, 2 or 3 as additives for fuels, especially as detergent additives for diesel fuels, as wax antisettling additives for middle distillate fuels and as lubricity improvers, and for improving the use properties of mineral and synthetic nonaqueous industrial fluids.
摘要翻译：使用咪唑鎓盐（I），其中R 1和R 3各自独立地为具有1至3000个碳原子的有机基团，R 2，R 4和R 5各自独立地为氢或具有1至3000个碳原子的有机基团，X为阴离子， n是数字1,2或3，作为燃料的添加剂，特别是用作柴油燃料的洗涤剂添加剂，作为中间馏分燃料的蜡防沉淀添加剂和润滑性改进剂，以及用于改善矿物和合成非水性工业流体的使用性质。

7. 发明授权

US07776957B2 Aqueous formulations containing polyaromatic compounds with acid groups 失效
标题翻译：含有酸性基团的多芳族化合物的含水配方
公开(公告)号：US07776957B2
公开(公告)日：2010-08-17
申请号：US11994208
申请日：2006-06-29
申请人： Alexander Khvorost , Gerhard Eugen Wahsner , Sven Thate , Harald Boehnke , Dennis Loesch
发明人： Alexander Khvorost , Gerhard Eugen Wahsner , Sven Thate , Harald Boehnke , Dennis Loesch
IPC分类号： C08G73/02
CPC分类号： C08J3/03 , C08G2650/02 , C08J5/2256 , C08J5/2287 , C08J2371/10 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M8/1072 , H01M2008/1095 , H01M2300/0082 , Y02P70/56
摘要： The present invention relates to a process for preparing aqueous formulations (A) comprising at least one polyaromatic compound bearing acid groups, in particular a sulfonated polyaromatic compound, and also aqueous formulations (A) which have been prepared by the process of the invention. Furthermore, the present invention relates to a process for preparing dried formulations (B) by removing the water from the aqueous formulations (A) and also the dried formulations (B) themselves. The present invention further provides a formulation (C) comprising the dried formulation (B) of the invention and water or the formulation A of the invention and a water-comprising formulation (D) comprising the aqueous formulation (A) or the formulation (C) of the invention and additionally at least 2% by weight of an organic solvent. Furthermore, the present invention relates to dry formulations (E) which are obtained by removing water and solvent from the water-comprising formulations (D) of the invention. The present invention further provides for the use of the water-comprising formulations (D) of the invention and of the dry formulations (E) obtained from these for producing a polymer electrolyte membrane and also the polymer electrolyte membrane itself and a membrane-electrode assembly (MEA) and also a fuel cell comprising the polymer electrolyte membrane of the invention.
摘要翻译：本发明涉及一种制备水性制剂（A）的方法，该制剂包含至少一种带有酸基的多芳族化合物，特别是磺化多芳族化合物，以及通过本发明方法制备的水性制剂（A）。此外，本发明涉及通过从水性制剂（A）中除去水以及干燥制剂（B）本身来制备干燥制剂（B）的方法。本发明还提供了包含本发明的干燥制剂（B）和水或本发明的制剂A的含水制剂（D）的制剂（C）和包含水性制剂（A）或制剂（C ）和另外至少2重量％的有机溶剂。此外，本发明涉及通过从本发明的含水制剂（D）中除去水和溶剂而获得的干燥制剂（E）。本发明还提供了本发明的含水制剂（D）和由它们获得的干燥制剂（E）用于制备聚合物电解质膜的用途，以及聚合物电解质膜本身和膜 - 电极组件（MEA）以及包含本发明的高分子电解质膜的燃料电池。

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