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1. 发明授权

US6096912A Soluble catalyst systems for the preparation of polyalk-1-enes having high molecular weights 失效
标题翻译：用于制备高分子量聚烯-1-烯的可溶性催化剂体系
公开(公告)号：US6096912A
公开(公告)日：2000-08-01
申请号：US642491
申请日：1996-05-03
申请人： Eberhard Karl , Werner Roell , Hans Brintzinger , Bernhard Rieger , Udo Stehling
发明人： Eberhard Karl , Werner Roell , Hans Brintzinger , Bernhard Rieger , Udo Stehling
IPC分类号： C08F4/642 , C07F17/00 , C08F4/60 , C08F4/622 , C08F4/639 , C08F4/6392 , C08F4/646 , C08F4/649 , C08F4/6592 , C08F4/68 , C08F10/00 , C08F10/06 , C08F110/06
CPC分类号： C08F10/06 , C07F17/00 , C08F10/00 , C08F110/06 , C08F4/63912 , C08F4/63927 , Y10S526/943
摘要： Abstract of the Disclosure: Catalyst systems for the polymerization of C.sub.2 -C.sub.10 -alk-1-enes contain, as active components,a) a metallocene complex of the general formula I ##STR1## where M is titanium, zirconium, hafnium, vanadium, niobium or tantalum, X is halogen or C.sub.1 -C.sub.8 -alkyl, Y is carbon, phosphorus, sulfur, silicon or germanium, Z is C.sub.1 -C.sub.8 -alkyl, C.sub.3 -C.sub.10 -cycloalkyl or C.sub.6 -C.sub.10 -aryl, R.sup.1 and R.sup.2 are identical or different and are each C.sub.1 -C.sub.4 -alkyl, R.sup.3 to R.sup.6 are identical or different and are each hydrogen or C.sub.1 -C.sub.8 -alkyl, or two adjacent radicals R.sup.3 and R.sup.4 and R.sup.5 and R.sup.6 in each case together form a hydrocarbon ring system of 4 to 15 carbon atoms and n is 0, 1 or 2, andb) an open-chain or cyclic alumoxane compound of the general formula II or III ##STR2## where R.sup.7 is C.sub.1 -C.sub.4 -alkyl and n is from 5 to 30. The novel catalyst systems are particularly suitable for the preparation of polyalk-1-enes having high molecular weights.
摘要翻译：本发明摘要：用于C2-C10-烷-1-烯的聚合的催化剂体系包含作为活性组分的a）通式I的茂金属络合物，其中M是钛，锆，铪，钒，铌或钽 X是卤素或C 1 -C 8烷基，Y是碳，磷，硫，硅或锗，Z是C 1 -C 8 - 烷基，C 3 -C 10 - 环烷基或C 6 -C 10 - 芳基，R 1和R 2是相同或不同的并且各自是C 1 -C 4 - 烷基，R 3至R 6相同或不同，并且各自为氢或C 1 -C 8 - 烷基，或两个相邻基团R 3和R 4以及R 5和R 6在每种情况下一起形成4〜 15个碳原子，n为0,1或2，以及b）通式II或III的开链或环状铝氧烷化合物，其中R 7为C 1 -C 4 - 烷基且n为5至30.新型催化剂体系特别适用于制备具有高分子量的聚酮-1-烯。

2. 发明授权

US5514760A Soluble catalyst systems for the preparation of polyalk-1-enes having high molecular weights 失效
标题翻译：用于制备高分子量聚烯-1-烯的可溶性催化剂体系
公开(公告)号：US5514760A
公开(公告)日：1996-05-07
申请号：US375278
申请日：1995-01-19
申请人： Eberhard Karl , Werner Roell , Hans Brintzinger , Bernhard Rieger , Udo Stehling
发明人： Eberhard Karl , Werner Roell , Hans Brintzinger , Bernhard Rieger , Udo Stehling
IPC分类号： C08F4/642 , C07F17/00 , C08F4/60 , C08F4/622 , C08F4/639 , C08F4/6392 , C08F4/646 , C08F4/649 , C08F4/6592 , C08F4/68 , C08F10/00 , C08F10/06 , C08F110/06 , C08F4/64
CPC分类号： C08F10/06 , C07F17/00 , C08F10/00 , C08F110/06 , C08F4/63912 , C08F4/63927 , Y10S526/943
摘要： Catalyst systems for the polymerization of C.sub.2 -C.sub.10 -alk-1-enes contain, as active components,a) a metallocene complex of the general formula I ##STR1## where M is titanium, zirconium, hafnium, vanadium, niobium or tantalum, X is halogen or C.sub.1 -C.sub.8 -alkyl, Y is carbon, phosphorus, sulfur, silicon or germanium, Z is C.sub.1 -C.sub.8 -alkyl, C.sub.3 -C.sub.10 -cycloalkyl or C.sub.6 -C.sub.10 -aryl, R.sup.1 and R.sup.2 are identical or different and are each C.sub.1 -C.sub.4 -alkyl, R.sup.3 to R.sup.6 are identical or different and are each hydrogen or C.sub.1 -C.sub.8 -alkyl, or two adjacent radicals R.sup.3 and R.sup.4 and R.sup.5 and R.sup.6 in each case together form a hydrocarbon ring system of 4 to 15 carbon atoms and n is 0, 1 or 2, andb) an open-chain or cyclic alumoxane compound of the general formula II or III ##STR2## where R.sup.7 is C.sub.1 -C.sub.4 -alkyl and n is from 5 to 30. The novel catalyst systems are particularly suitable for the preparation of polyalk-1-enes having high molecular weights.
摘要翻译：用于C2-C10-烷-1-烯的聚合的催化剂体系包含作为活性组分的a）通式I的茂金属络合物，其中M是钛，锆，铪，钒，铌或钽， X是卤素或C 1 -C 8烷基，Y是碳，磷，硫，硅或锗，Z是C 1 -C 8 - 烷基，C 3 -C 10 - 环烷基或C 6 -C 10 - 芳基，R 1和R 2是相同或不同的，各自为C 1 -C 4 - 烷基，R 3至R 6相同或不同，并且各自为氢或C 1 -C 8 - 烷基，或两个相邻基团R 3和R 4以及R 5和R 6在每种情况下一起形成4至15的烃环体系碳原子，n为0,1或2，以及b）通式II或III的开链或环状铝氧烷化合物（II）为5-30。新的催化剂体系特别适用于制备的具有高分子量的聚酮-1-烯。

3. 发明授权

US5496902A Catalyst systems for the polymerization of C.sub.2 -C.sub.10 -alk-1-enes 失效
标题翻译：用于C2-C10-烷-1-烯的聚合的催化剂体系
公开(公告)号：US5496902A
公开(公告)日：1996-03-05
申请号：US244747
申请日：1994-06-13
申请人： Kaspar Evertz , Ruerger Schlund , Guenther Schweier , Hans Brintzinger , Werner Roell , Peter Jutzi , Ingrid Mieling , Winfried Mengele
发明人： Kaspar Evertz , Ruerger Schlund , Guenther Schweier , Hans Brintzinger , Werner Roell , Peter Jutzi , Ingrid Mieling , Winfried Mengele
IPC分类号： C07F17/00 , C08F4/42 , C08F4/60 , C08F4/602 , C08F4/619 , C08F4/6192 , C08F4/642 , C08F4/6592 , C08F4/68 , C08F10/00
CPC分类号： C07F17/00 , C08F10/00 , C08F4/61912 , C08F4/61927
摘要： Catalyst systems for the polymerization of C.sub.2 -C.sub.10 -alk-1-enes contain, as active components,a) a metallocene complex of the general formula I ##STR1## where M is a metal of the subgroup III, IV or v of the Periodic Table of elements or a metal selected from the group consisting of the lanthanides,X is fluorine, chlorine, bromine, iodine, hydrogen, C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.15 -aryl or --OR.sup.7,R.sup.7 is C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.15 -aryl, alkylaryl, arylalkyl, fluoroalkyl or fluoroaryl, in each case having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical,n is the valency of M minus two,R.sup.1 to R.sup.6 are each hydrogen, C.sub.1 -C.sub.10 -alkyl, 5-membered to 7-membered cycloalkyl which in turn may carry C.sub.1 -C.sub.10 -alkyl as a substituent, C.sub.6 -C.sub.15 -aryl or arylalkyl, where two adjacent radicals together may furthermore form a cyclic group of 4 to 15 carbon atoms, or Si(R.sup.8).sub.3,R.sup.8 is C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.15 -aryl or C.sub.3 -C.sub.10 -cycloalkyl,E.sup.1 and E.sup.2 are independent of one another and are each Si(R.sup.9).sub.2, Ge(R.sup.9).sub.2, Sn(R.sup.9).sub.2 or C(R.sup.9).sub.2 --C(R.sup.9).sub.2 andR.sup.9 is C.sub.1 -C.sub.10 -alkyl, C.sub.3 -C.sub.10 -cycloalkyl or C.sub.6 -C.sub.15 -aryl, andb) an open-chain or cyclic alumoxane compound of the general formula II or III ##STR2## where R.sup.10 is C.sub.1 -C.sub.4 -alkyl and m is an integer of from 5 to 30.
摘要翻译： PCT No.PCT / EP93 / 00694 371日期1994年6月13日 102（e）日期1994年6月13日PCT 1993年3月23日PCT公布。公开号WO93 / 20113 PCT 日期：1993年10月14日。用于C2-C10-烷-1-烯的聚合的催化剂体系包含作为活性组分的a）元素周期表的通式I III，IV或v的茂金属络合物或选自镧系元素的金属，X是氟，氯，溴，碘，氢，C1-C10-烷基，C6-C15-芳基或-OR7，R7是C1-C10-烷基，C6-C15- 芳基，烷基芳基，芳基烷基，氟烷基或氟代芳基，在每个情况下在烷基中具有1-10个碳原子，在芳基中具有6-20个碳原子，n是M的化合价减去2，R 1至R 6各自为氢， C 1 -C 10 - 烷基，5元至7元环烷基，其又可以携带作为取代基的C 1 -C 10 - 烷基，C 6 -C 15 - 芳基或芳基烷基，其中两个相邻的基团可以进一步形成4至 15个碳原子或Si（R8）3，R8是C1-C10-烷基，C6-C15-芳基或C3-C10-环烷基，E1和E2彼此独立，分别是Si（R9）2，Ge R9）2，Sn（R9）2或C（R9）2-C（R， 9）2和R9是C 1 -C 10 - 烷基，C 3 -C 10 - 环烷基或C 6 -C 15 - 芳基，和b）通式II或III的开链或环状铝氧烷化合物 5到30。

4. 发明授权

US5296434A Soluble catalyst systems for the preparation of polyalk-1-enes having high molecular weights 失效
标题翻译：用于制备高分子量聚烯-1-烯的可溶性催化剂体系
公开(公告)号：US5296434A
公开(公告)日：1994-03-22
申请号：US900427
申请日：1992-06-18
申请人： Eberhard Karl , Werner Roell , Hans Brintzinger , Bernhard Rieger , Udo Stehling
发明人： Eberhard Karl , Werner Roell , Hans Brintzinger , Bernhard Rieger , Udo Stehling
IPC分类号： C08F4/642 , C07F17/00 , C08F4/60 , C08F4/622 , C08F4/639 , C08F4/6392 , C08F4/646 , C08F4/649 , C08F4/6592 , C08F4/68 , C08F10/00 , C08F10/06 , C08F110/06
CPC分类号： C08F10/06 , C07F17/00 , C08F10/00 , C08F110/06 , C08F4/63912 , C08F4/63927 , Y10S526/943
摘要： Catalyst systems for the polymerization of C.sub.2 -C.sub.10 -alk-1-enes contain, as active components,a) a metallocene complex of the general formula I ##STR1## where M is titanium, zirconium, hafnium, vanadium, niobium or tantalum, X is halogen or C.sub.1 --C.sub.8 -alkyl, Y is carbon, phosphorus, sulfur, silicon or germanium, Z is C.sub.1 -C.sub.8 -alkyl, C.sub.3 -C.sub.10 -cycloalkyl or C.sub.6 -C.sub.10 -aryl, R.sup.1 and R.sup.2 are identical or different and are each C.sub.1 -C.sub.4 -alkyl, R.sup.3 to R.sup.6 are identical or different and are each hydrogen or C.sub.1 -C.sub.8 -alkyl, or two adjacent radicals R.sup.3 and R.sup.4 and R.sup.5 and R.sup.6 in each case together form a hydrocarbon ring system of 4 to 15 carbon atoms and n is 0, 1 or 2, andb) an open-chain or cyclic alumoxane compound of the general formula II or III ##STR2## where R.sup.7 is C.sub.1 -C.sub.4 -alkyl and n is from 5 to 30. The novel catalyst systems are particularly suitable for the preparation of polyalk-1-enes having high molecular weights.
摘要翻译：用于C2-C10-烷-1-烯的聚合的催化剂体系包含a）通式I（*化学结构*）I的茂金属络合物，其中M是钛，锆，铪，钒，铌或钽，X是卤素或C 1 -C 8烷基，Y是碳，磷，硫，硅或锗，Z是C 1 -C 8 - 烷基，C 3 -C 10 - 环烷基或C 6 -C 10 - 芳基，R 1和R 2是相同或不同，并且各自为C 1 -C 4 - 烷基，R 3至R 6相同或不同，并且各自为氢或C 1 -C 8 - 烷基，或两个相邻基团R 3和R 4以及R 5和R 6在每种情况下一起形成烃环体系 4〜15个碳原子，n为0,1或2，b）通式II或III的开链或环状铝氧烷化合物（*化学结构*）（II）（*化学结构*）（III ）其中R 7是C 1 -C 4 - 烷基，n是5至30.新的催化剂体系特别适用于制备具有高分子量的聚烯-1-烯。

5. 发明授权

US5132262A Soluble catalyst systems for the polymerization of C.sub.2 - to C.sub.10 -alk-l-enes 失效
标题翻译：用于C2-C10-ALK-L-ENES聚合的可溶性催化剂体系
公开(公告)号：US5132262A
公开(公告)日：1992-07-21
申请号：US653546
申请日：1991-02-11
申请人： Bernhard Rieger , Hans Brintzinger , Werner Roell , Annette Reinmuth , Elke Barsties
发明人： Bernhard Rieger , Hans Brintzinger , Werner Roell , Annette Reinmuth , Elke Barsties
IPC分类号： C07F17/00 , C08F4/60 , C08F4/626 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/642 , C08F4/646 , C08F4/6592 , C08F4/68 , C08F10/00 , C08F10/06 , C08F110/06
CPC分类号： C08F10/00 , C08F10/06 , C08F110/06 , C08F4/63912 , C08F4/63927 , Y10S526/943
摘要： The present invention relates to soluble catalyst systems for the polymerization of C.sub.2 - to C.sub.10 -alk-l-enes, containing, as active constituents,a) a metallocene complex of the general formula I ##STR1## where R.sup.1 and R.sup.2 are branched C.sub.4 - to C.sub.10 -alkyl, 5- to 7-membered cycloalkyl, which may itself be substituted by C.sub.1 - to C.sub.6 -alkyl, or are C.sub.6 - to C.sub.15 -aryl or aralkyl;R.sup.3 to R.sup.6 are C.sub.1 - to C.sub.8 -alkyl,M is titanium, zirconium, hafnium or vanadium,Y is silicon or germanium, andX is halogen or C.sub.1 - to C.sub.8 -alkyl,b) and an open-chain or cyclic aluminoxane compound of the general formula II or III ##STR2## where R.sup.7 is C.sub.1 -C.sub.4 -alkyl, and m is from 5 to 30. These catalyst systems are particularly suitable for the preparation of polypropylene and copolymers of propylene with lesser amounts of other C.sub.2 - to C.sub.10 -alky-l-enes.
摘要翻译：本发明涉及用于聚合C2-至C10-烷-1-烯的可溶性催化剂体系，其含有作为活性成分的a）通式I（I）的茂金属络合物，其中R 1和R 2是支链C4至C10烷基，5-至7-元环烷基，其本身可被C 1至C 6 - 烷基取代，或为C 6至C 15 - 芳基或芳烷基; R3至R6为C1-至C8-烷基，M为钛，锆，铪或钒，Y为硅或锗，X为卤素或C1-至C8-烷基，b）和开链或环状铝氧烷化合物通式II或III其中R 7为C 1 -C 4 - 烷基，m为5至30的通式II或III。这些催化剂体系特别适用于制备丙烯和丙烯与较少量的其它C2-至 C10-烷-1-烯。

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