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1. 发明申请

US20120123157A1 FORMIC ACID MANUFACTURING SYSTEM AND METHOD OF MANUFACTURING FORMIC ACID 审中-公开
标题翻译：制酸制剂及其制备方法
公开(公告)号：US20120123157A1
公开(公告)日：2012-05-17
申请号：US12944240
申请日：2010-11-11
申请人： Hsiao-Ping HUANG , Ming-Jer Lee , Hao-Yen Lee , Jyun-Hong Chen
发明人： Hsiao-Ping HUANG , Ming-Jer Lee , Hao-Yen Lee , Jyun-Hong Chen
IPC分类号： C07C51/12 , B01J19/00
CPC分类号： C07C51/09 , B01J8/20 , B01J19/0066 , B01J19/18 , B01J2219/00006 , B01J2219/00108 , C07C51/44 , C07C67/36 , Y02P20/127 , C07C53/02 , C07C69/06
摘要： Formic acid manufacturing system and method of manufacturing formic acid. The formic acid manufacturing system includes a reactor, a first separation device, a second separation device, a reactive distillation device and a third separation device. Methyl formate is produced in the reactor by processing a conbonylation reaction of external carbon monoxide and methanol. Water is added into the reactive distillation device externally, and formic acid and methanol is produced in the reactive distillation device by hydrolyzing methyl formate with water. A formic acid solution is obtained from an output of the third separation device.
摘要翻译：甲酸生产体系及甲酸生产方法。甲酸制造系统包括反应器，第一分离装置，第二分离装置，反应蒸馏装置和第三分离装置。通过加工外部一氧化碳和甲醇的共羰化反应，在反应器中生产甲酸甲酯。向外部向反应蒸馏装置中加入水，通过用水水解甲酸甲酯，在反应蒸馏装置中生成甲酸和甲醇。从第三分离装置的输出获得甲酸溶液。

2. 发明申请

US20110094787A1 PRINTED CIRCUIT BOARD AND MANUFACTURING METHOD THEREOF 审中-公开
标题翻译：印刷电路板及其制造方法
公开(公告)号：US20110094787A1
公开(公告)日：2011-04-28
申请号：US12647431
申请日：2009-12-25
申请人： YING-TSO LAI , CHUN-JEN CHEN , YU-CHANG PAI , PEI-CHUN LIN , CHIN-HUI CHEN , HSIAO-PING HUANG
发明人： YING-TSO LAI , CHUN-JEN CHEN , YU-CHANG PAI , PEI-CHUN LIN , CHIN-HUI CHEN , HSIAO-PING HUANG
IPC分类号： H05K1/11 , H05K3/10
CPC分类号： H05K1/116 , H05K1/0201 , H05K3/3447 , H05K2201/062 , H05K2201/09036 , H05K2201/093 , H05K2201/0969 , H05K2203/0242 , Y10T29/49155
摘要： A printed circuit board includes a layer. A layer of copper is covered on a surface of the layer. A through hole passes through the printed circuit board. A number of thermal engravings are defined in the layer around the through hole. Each thermal engraving is a groove defined in the surface of the layer, without covered with the layer of copper. The number of thermal engravings are not in contact with each other.
摘要翻译：印刷电路板包括一层。铜层被覆盖在该层的表面上。通孔穿过印刷电路板。在通孔周围的层中限定了许多热雕刻。每个热雕刻是在层的表面中限定的凹槽，而不被铜层覆盖。热雕刻的数量彼此不接触。

3. 发明申请

US20090264674A1 SYSTEM AND METHOD FOR PRODUCING DIESTER 审中-公开
标题翻译：用于生产柴油的系统和方法
公开(公告)号：US20090264674A1
公开(公告)日：2009-10-22
申请号：US12420449
申请日：2009-04-08
申请人： Hsiao-Ping HUANG , Cheng-Ching YU , Ming-Jer LEE , Shih-Bo HUNG , I-Kuan LAI
发明人： Hsiao-Ping HUANG , Cheng-Ching YU , Ming-Jer LEE , Shih-Bo HUNG , I-Kuan LAI
IPC分类号： C07C67/08 , B01J19/00
CPC分类号： C07C67/08 , Y02P20/127 , Y02P20/582 , C07C69/44 , C07C69/42
摘要： The system and method for producing diester are provided. The system includes a first distillation unit reacting a dicarboxylic acid with an alcohol to produce a first gaseous mixture, a first cooling unit connected to the first distillation unit and cooling the first gaseous mixture into a first liquid mixture, a second distillation unit connected to the first cooling unit and separating the first liquid mixture into a second gaseous mixture and a second liquid mixture, and a liquid-liquid extraction unit connected to the second distillation unit and separating the second liquid mixture into an aqueous-rich mixture and an organic-rich mixture from which the diester is obtained.
摘要翻译：提供了制备二酯的体系和方法。该系统包括使二羧酸与醇反应以产生第一气体混合物的第一蒸馏单元，连接到第一蒸馏单元并将第一气态混合物冷却成第一液体混合物的第一冷却单元，连接到第二蒸馏单元第一冷却单元并将第一液体混合物分离成第二气体混合物和第二液体混合物，以及连接到第二蒸馏单元的液 - 液萃取单元，并将第二液体混合物分离成富含水的混合物和富含有机物的混合物获得二酯的混合物。

4. 发明授权

US07399881B1 Transesterification process of methyl acetate 有权
标题翻译：乙酸甲酯的酯交换过程
公开(公告)号：US07399881B1
公开(公告)日：2008-07-15
申请号：US11715776
申请日：2007-03-08
申请人： Hsiao-Ping Huang , Cheng-Ching Yu , Ming-Jer Lee , Jyun-Hong Chen , Jian-Kai Cheng
发明人： Hsiao-Ping Huang , Cheng-Ching Yu , Ming-Jer Lee , Jyun-Hong Chen , Jian-Kai Cheng
IPC分类号： C07C67/02
CPC分类号： C07C67/03 , C07C67/54 , Y02P20/127 , C07C69/003 , C07C69/14
摘要： A transesterification process of methyl acetate is provided. The process comprises: (a) performing a first reactive distillation of a methyl acetate solution and a first alcohol to generate a first ester and a first mixture; (b) performing a first distillation of a first part of the first mixture to generate a second mixture; and (c) performing a second reactive distillation of a first part of the second mixture and a second alcohol to generate a second ester; wherein the respective one of the first and second alcohols is a limiting reagent. The transesterification process provided in the present invention could highly reduce the investing production cost of the transesterification of the by-product, methyl acetate, in the conventional polyvinyl alcohol plants.
摘要翻译：提供乙酸甲酯的酯交换过程。该方法包括：（a）对乙酸甲酯溶液和第一醇进行第一反应蒸馏以产生第一酯和第一混合物; （b）对所述第一混合物的第一部分进行第一蒸馏以产生第二混合物; 和（c）对所述第二混合物的第一部分和第二醇进行第二反应蒸馏以产生第二酯; 其中所述第一和第二醇中的相应的一种是限制性试剂。本发明提供的酯交换方法可以大大降低常规聚乙烯醇装置中副产物乙酸甲酯的酯交换反应的投资生产成本。

5. 发明申请

US20080264772A1 Method and apparatus for esterification 有权
标题翻译：酯化方法和装置
公开(公告)号：US20080264772A1
公开(公告)日：2008-10-30
申请号：US11789880
申请日：2007-04-25
申请人： Hsiao-Ping Huang , Cheng-Ching Yu , Ming-Jer Lee , Shih-Bo Hung , I-Kuan Lai
发明人： Hsiao-Ping Huang , Cheng-Ching Yu , Ming-Jer Lee , Shih-Bo Hung , I-Kuan Lai
IPC分类号： B01D3/34
CPC分类号： B01D3/008 , C07C67/08 , C07C69/14
摘要： The method and apparatus for improving the esterification procedure, in particular for improving the esterification procedure to obtain an ester of low carbon number such as the ethyl acetate and the isopropyl acetate, are provided. By means of the provided method and apparatus, the conversion ratio of the esterification procedure is significantly increased and hence an ester product of a relatively high purity, up to the industrial specification, is obtained.
摘要翻译：提供了改进酯化方法的方法和装置，特别是用于改进酯化程序以获得低碳数的酯如乙酸乙酯和乙酸异丙酯。通过所提供的方法和装置，酯化程序的转化率显着增加，因此获得了直至工业规范的相对高纯度的酯产物。

6. 发明申请

US20100125145A1 Trans-Esterification Reaction System And Method Thereof 审中-公开
标题翻译：反酯化反应体系及其方法
公开(公告)号：US20100125145A1
公开(公告)日：2010-05-20
申请号：US12465596
申请日：2009-05-13
申请人： Cheng-Ching Yu , Hsiao-Ping Huang , Ming-Jer Lee , Yin-Heng Shen , Jian-Kai Cheng
发明人： Cheng-Ching Yu , Hsiao-Ping Huang , Ming-Jer Lee , Yin-Heng Shen , Jian-Kai Cheng
IPC分类号： C11C3/04 , B01J8/04
CPC分类号： C11C3/04 , C11B3/00 , Y02E50/13
摘要： The trans-esterification system for trans-esterifying a triglyceride includes a reaction tank, a separation tank, a first pipe and a second pipe. The reaction tank is inputted with the triglyceride and a monohydric alcohol for undergoing a trans-esterification reaction to produce a mixture. The separation tank is inputted with the mixture for a phase separation to generate an ester phase solution and a glycerol phase solution having a first part and a second part. The first pipe connects the reaction tank and the separation tank, and transports the mixture from the reaction tank to the separation tank. The second pipe connects the reaction tank and the separation tank, and transports the first part of the glycerol phase solution from the separation tank to the reaction tank for undergoing the trans-esterification reaction.
摘要翻译：用于酯交换甘油三酸酯的酯交换体系包括反应槽，分离槽，第一管和第二管。输入反应槽中的甘油三酯和一元醇进行酯交换反应以产生混合物。向分离槽输入混合物进行相分离以产生具有第一部分和第二部分的酯相溶液和甘油相溶液。第一管连接反应罐和分离罐，并将混合物从反应罐输送到分离罐。第二管连接反应罐和分离罐，并将第一部分甘油相溶液从分离罐输送到反应罐进行酯交换反应。

7. 发明申请

US20080128262A1 Separation process for methyl acetate hydrolysis and apparatus thereof 有权
标题翻译：乙酸甲酯水解分离方法及其设备
公开(公告)号：US20080128262A1
公开(公告)日：2008-06-05
申请号：US11699849
申请日：2007-01-30
申请人： Hsiao-Ping Huang , Cheng-Ching Yu , Ming-Jer Lee , Yu-De Lin , Jian-Kai Cheng
发明人： Hsiao-Ping Huang , Cheng-Ching Yu , Ming-Jer Lee , Yu-De Lin , Jian-Kai Cheng
IPC分类号： B01D3/40 , B01D3/34 , B01D3/42
CPC分类号： B01D3/009 , B01D3/146 , C07C51/09 , C07C51/44 , Y02P20/127 , Y10S203/06 , C07C53/08
摘要： A separation system for a methyl acetate hydrolysis is provided. The separation system comprises a reactive distillation system, a reflux system, a first separation system and a second separation. The reactive distillation system allows the hydrolysis of a methyl acetate solution to generate a first mixture and a second mixture. The reflux system is packed with a heterogeneous catalyst and coupled to the reactive distillation system, which refluxes the first mixture to the reactive distillation system. The first separation system is coupled to the reactive distillation system, which directs the second mixture thereinto so as to isolate an acetic acid and a third mixture therefrom. The second separation system is coupled to the first separation system, which directs the third mixture thereintio so as to separate a methanol therefrom. The methyl acetate feeding system is coupled to, one of the reactive distillation system and the reflux system, which feeds the methyl acetate solution thereinto.
摘要翻译：提供了一种用于乙酸甲酯水解的分离系统。分离系统包括反应蒸馏系统，回流系统，第一分离系统和第二分离。反应蒸馏系统允许水解乙酸甲酯溶液以产生第一混合物和第二混合物。回流系统装有非均相催化剂并与反应蒸馏系统偶联，反应蒸馏系统使第一混合物回流到反应蒸馏系统。第一分离系统耦合到反应蒸馏系统，其将第二混合物引导到其中以从其中分离乙酸和第三混合物。第二分离系统耦合到第一分离系统，其将第三混合物引导到其中以从其分离甲醇。将乙酸甲酯进料系统与反应蒸馏系统和回流系统中的一个反应，将乙酸甲酯溶液加入其中。

8. 发明授权

US06440047B1 Exercising device for simulating hula-hoop rotations 失效
标题翻译：用于模拟呼啦圈旋转的运动装置
公开(公告)号：US06440047B1
公开(公告)日：2002-08-27
申请号：US09835646
申请日：2001-04-12
申请人： Hsiao-Ping Huang
发明人： Hsiao-Ping Huang
IPC分类号： A63B7100
CPC分类号： A63B19/00 , A63B21/0608 , A63B23/00 , A63B71/0686 , A63B2071/063 , A63B2071/0661 , A63B2207/02 , A63B2209/08 , A63B2220/17 , A63B2220/801
摘要： An exercising device for simulating hula-hoop rotations includes: a housing having at least a track annularly formed in the housing, at least a ball rolling or rotably moving in the track upon a hula-hoop rotation by a user who wears the housing of the exercising device, and an audio and visual device provided on the housing to indicate or display the whirling movements audiovisually.
摘要翻译：用于模拟呼啦圈旋转的锻炼装置包括：壳体，其至少具有环形地形成在所述壳体中的轨道，至少一个滚珠或可旋转地在轨道上移动的滚珠，所述滚珠在穿过所述壳体的使用者的呼吸圈旋转时运动装置，以及设置在外壳上的音频和视频装置，以便在视听中指示或显示旋转运动。

9. 发明授权

US08314266B2 Method for manufacturing esters from acid and alcohol and system thereof 有权
标题翻译：从酸和醇制备酯的方法及其制备方法
公开(公告)号：US08314266B2
公开(公告)日：2012-11-20
申请号：US12220940
申请日：2008-07-30
申请人： Cheng-Ching Yu , Hsiao-Ping Huang , Ming-Jer Lee , Ruei-Chiang Tsai , Jian-Kai Cheng
发明人： Cheng-Ching Yu , Hsiao-Ping Huang , Ming-Jer Lee , Ruei-Chiang Tsai , Jian-Kai Cheng
IPC分类号： C07C67/08
CPC分类号： C07C67/08 , B01D3/009 , Y02P20/127 , C07C69/14
摘要： A process for manufacturing esters from acid and alcohol and a system thereof are provided, wherein the system includes a reactive distillation column, a sidestream reactor packed with catalyst, and a decanter for conducting the method. The method is carried out by (a) extracting a first mixture of acid and alcohol from the reactive distillation column, for then feeding the first mixture to at least one sidestream reactor packed with catalyst to obtain a reaction product; (b) feeding the reaction product from the sidestream reactor to the reactive distillation column, allowing a second mixture of alcohol, ester and water to be separated from a top end of the reactive distillation column; (c) feeding the second mixture into the decanter to separate an organic phase from an aqueous phase; and (d) separating esters from the organic phase. The method and system allow the esters to be extracted without using a plurality of recovering columns and decanters, and are capable of improving packing/changing catalyst in a single reactive distillation column.
摘要翻译：提供了一种由酸和醇制备酯的方法及其制备方法，其中该体系包括反应蒸馏塔，装有催化剂的侧流反应器和用于进行该方法的滗析器。该方法通过以下步骤进行：（a）从反应蒸馏塔中提取酸和醇的第一混合物，然后将第一混合物进料至填充有催化剂的至少一个侧流反应器以获得反应产物; （b）将来自侧流反应器的反应产物进料到反应蒸馏塔，使醇，酯和水的第二混合物与反应蒸馏塔的顶端分离; （c）将第二混合物进料到滗析器中以将有机相与水相分离; 和（d）从有机相分离酯。该方法和系统允许在不使用多个回收塔和滗析器的情况下提取酯，并且能够改进单个反应蒸馏塔中的填料/改变催化剂。

10. 发明申请

US20120083621A1 METHOD AND APPARATUS FOR PREPARING MULTIPLE ESTERS 审中-公开
标题翻译：用于制备多个酯的方法和装置
公开(公告)号：US20120083621A1
公开(公告)日：2012-04-05
申请号：US12938251
申请日：2010-11-02
申请人： HSIAO-PING HUANG , I-LUNG CHIEN , MING-JER LEE , I-KUAN LAI
发明人： HSIAO-PING HUANG , I-LUNG CHIEN , MING-JER LEE , I-KUAN LAI
IPC分类号： C07C67/08 , B01J19/00
CPC分类号： C07C67/08 , B01D3/009 , B01D3/143 , B01J2219/00006 , C07C67/54 , Y02P20/127 , Y02P20/57 , C07C69/14
摘要： Disclosed is a method and an apparatus for manufacturing at least two esters. The method includes steps of: (a) reacting an acid and an alcohol mixture in a reactive distillation (RD) column to generate an alcohol-ester-water azeotrope, wherein the alcohol mixture includes at least two alcohols; (b) separating the alcohol-ester-water azeotrope as the organic mixture and water in a decanter; (c) purifying the organic mixture to generate the ester mixture in a stripper; and (d) performing the ester-ester separation on the ester mixture to generate at least two esters in a distillation column, wherein the number of at least two esters is the same with that of at least two alcohols. The unpurified ester mixture carrying heat can be refluxed into stripper for saving energy and enhancing the efficiency of purification.
摘要翻译：公开了用于制造至少两种酯的方法和装置。该方法包括以下步骤：（a）使反应性蒸馏（RD）塔中的酸和醇混合物反应以产生醇 - 酯 - 水共沸物，其中醇混合物包括至少两种醇; （b）将滗析器中的有机混合物和水的醇 - 酯 - 水共沸物分离; （c）纯化有机混合物以在汽提塔中产生酯混合物; 和（d）在酯混合物上进行酯 - 酯分离，以在蒸馏塔中产生至少两种酯，其中至少两种酯的数量与至少两种醇的数量相同。携带热量的未纯化的酯混合物可以回流到汽提器中，以节省能量并提高净化效率。

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