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1. 发明申请

US20120064390A1 LITHIUM ION BATTERY ELECTROLYTE AND LITHIUM BATTERY HAVING THE SAME 审中-公开
标题翻译：锂离子电池电解液和锂电池
公开(公告)号：US20120064390A1
公开(公告)日：2012-03-15
申请号：US13229412
申请日：2011-09-09
申请人： Huiying Wang , Guishu Zhou
发明人： Huiying Wang , Guishu Zhou
IPC分类号： H01M10/056 , H01M2/02
CPC分类号： H01M10/0568 , H01M10/0567 , H01M10/0569
摘要： Electrolytes of lithium ion batteries of the present disclosure comprise: a lithium salt, a non-aqueous solvent, and an additive. The additive further comprises a first and second compound. The first compound is a 4 X1, 5 R1 [1,3]dioxolan-2-one, wherein X1 is selected from the group consisting of: F, Cl, and Br and R1 is selected from the group consisting of hydrogen and linear alkyl compounds having between 1 and 3 carbon atoms. The second compound has a molecular formula of: F(CF2CF2)x—CH2CH2—(CH2CH2O)yH, wherein x is any integer ranging from 1 to 7, and y is any integer ranging from 1 to 15.
摘要翻译：本公开的锂离子电池的电解质包括：锂盐，非水溶剂和添加剂。添加剂还包含第一和第二化合物。第一化合物是4X1，5R1 [1,3]二氧戊环-2-酮，其中X 1选自：F，Cl和Br，R 1选自氢和直链烷基具有1至3个碳原子的化合物。第二化合物具有分子式：F（CF 2 CF 2）x -CH 2 CH 2 - （CH 2 CH 2 O）y H，其中x是1至7的整数，y是1至15的整数。

2. 发明申请

US20100028771A1 ELECTROLYTE FOR LITHIUM BATTERIES 有权
标题翻译：电解液用于锂离子电池
公开(公告)号：US20100028771A1
公开(公告)日：2010-02-04
申请号：US12482690
申请日：2009-06-11
申请人： GuiShu ZHOU , Lei SI , Yong WANG , YiWei FAN
发明人： GuiShu ZHOU , Lei SI , Yong WANG , YiWei FAN
IPC分类号： H01M2/02 , H01M6/04 , H01M6/16 , H01M4/82
CPC分类号： H01M10/052 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M2300/0025 , H01M2300/0031 , H01M2300/0034 , Y02E60/122 , Y10T29/4911
摘要： Electrolyte and lithium secondary batteries containing the same are disclosed. In one instance, the electrolyte includes a lithium salt, a solvent and an additive. In some examples, the additive includes substances A, B and C, wherein substance A is vinylene carbonate, substance B includes at least one of fluorinated or chlorinated ethylene carbonate or diethylene carbonate, and substance C includes at least one of ethylene sulfite, 1,3-propanesultone and propenyl sulfite.
摘要翻译：公开了含有它们的电解质和锂二次电池。在一种情况下，电解质包括锂盐，溶剂和添加剂。在一些实例中，添加剂包括物质A，B和C，其中物质A是碳酸亚乙烯酯，物质B包括氟化或氯化碳酸亚乙酯或二亚乙基碳酸酯中的至少一种，物质C包括亚硫酸亚乙酯， 3-丙磺酸内酯和亚硫酸丙烯酯。

3. 发明授权

US07790322B2 Additive mixture for electrolyte of lithium ion secondary battery and electrolyte of lithium ion secondary battery comprising the same 有权
标题翻译：锂离子二次电池用电解质的添加剂和包含该锂离子二次电池的锂离子二次电池的电解质
公开(公告)号：US07790322B2
公开(公告)日：2010-09-07
申请号：US12090728
申请日：2006-10-17
申请人： Feng Xiao , Mingxia Wang , Guishu Zhou , Huaying You
发明人： Feng Xiao , Mingxia Wang , Guishu Zhou , Huaying You
IPC分类号： H01M6/18
CPC分类号： H01M10/0567 , H01M10/0525 , H01M10/4235 , H01M2300/0025 , H01M2300/0042
摘要： Disclosed herewith are an additive mixture for the electrolyte of lithium ion secondary batteries and electrolyte of lithium ion secondary batteries comprising the said additive mixture. The additive mixture comprises biphenyl based compound 0.5-95.4 wt %, cyclohexyl benzene based compound 0.1-93.8 wt %, vinylene carbonate 0.4-93.2 wt %, t-alkyl benzene based compound 0.5-96.5 wt %, and phenyl vinyl sulfone 0.5-95.8% based on total weight of the additive mixture.
摘要翻译：本发明公开了一种用于锂离子二次电池的电解质和包含所述添加剂混合物的锂离子二次电池的电解质的添加剂混合物。添加剂混合物包含联苯基化合物0.5-95.4重量％，环己基苯基化合物0.1-93.8重量％，碳酸亚乙烯酯0.4-93.2重量％，t-烷基苯基化合物0.5-96.5重量％和苯基乙烯基砜0.5-95.8 基于添加剂混合物的总重量的％。

4. 发明申请

US20090305130A1 TYPE OF NON-AQUEOUS ELECTROLYTE 审中-公开
标题翻译：非水溶性电解质
公开(公告)号：US20090305130A1
公开(公告)日：2009-12-10
申请号：US12091271
申请日：2006-11-09
申请人： Feng Xiao , Mingxia Wang , Guishu Zhou , Huaying You
发明人： Feng Xiao , Mingxia Wang , Guishu Zhou , Huaying You
IPC分类号： H01M10/26
CPC分类号： H01M10/0567
摘要： This invention relates to non-aqueous electrolytes, in particular, a non-aqueous electrolyte for lithium-ion secondary batteries. The electrolyte comprises regular organic solvents and electrolyte saline. The special characteristics are: the electrolyte also comprises mixed additives, said mixed additives comprising at least one of those of compound group A, at least one of those of compound group B, and one of those of compound group C wherein: compound group A are selected from inorganic saline including Li2CO3, Li2SO4, Li2 SO3, LiNO3; compound group B are selected from vinylene carbonate, propylene carbonate; and compound group C are selected from ES, PS, DMS, DES, DMSO. The weight ratio can be (Group I).
摘要翻译：本发明涉及非水电解质，特别是涉及锂离子二次电池的非水电解质。电解质包含常规有机溶剂和电解质盐水。其特征是电解质还包含混合添加剂，所述混合添加剂包括化合物A，化合物B中的至少一种和化合物C中的至少一种，其中化合物基团A为选自包括Li 2 CO 3，Li 2 SO 4，Li 2 SO 3，LiNO 3的无机盐水; 化合物B选自碳酸亚乙烯酯，碳酸亚丙酯; 和化合物C选自ES，PS，DMS，DES，DMSO。重量比可以是（组I）。

5. 发明授权

US08883356B2 Electrolyte for lithium batteries 有权
标题翻译：锂电池电解液
公开(公告)号：US08883356B2
公开(公告)日：2014-11-11
申请号：US12482690
申请日：2009-06-11
申请人： GuiShu Zhou , Lei Si , Yong Wang , YiWei Fan
发明人： GuiShu Zhou , Lei Si , Yong Wang , YiWei Fan
IPC分类号： H01M6/18 , H01M10/052 , H01M10/0567 , H01M10/0568 , H01M10/0569
CPC分类号： H01M10/052 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M2300/0025 , H01M2300/0031 , H01M2300/0034 , Y02E60/122 , Y10T29/4911
摘要： Electrolyte and lithium secondary batteries containing the same are disclosed. In one instance, the electrolyte includes a lithium salt, a solvent and an additive. In some examples, the additive includes substances A, B and C, wherein substance A is vinylene carbonate, substance B includes at least one of fluorinated or chlorinated ethylene carbonate or diethylene carbonate, and substance C includes at least one of ethylene sulfite, 1,3-propanesultone and propenyl sulfite.
摘要翻译：公开了含有它们的电解质和锂二次电池。在一种情况下，电解质包括锂盐，溶剂和添加剂。在一些实例中，添加剂包括物质A，B和C，其中物质A是碳酸亚乙烯酯，物质B包括氟化或氯化碳酸亚乙酯或二亚乙基碳酸酯中的至少一种，物质C包括亚硫酸亚乙酯， 3-丙磺酸内酯和亚硫酸丙烯酯。

6. 发明授权

US07732093B2 Type of non-aqueous electrolyte 有权
标题翻译：非水电解质的类型
公开(公告)号：US07732093B2
公开(公告)日：2010-06-08
申请号：US11595218
申请日：2006-11-09
申请人： Feng Xiao , Mingxia Wang , Guishu Zhou , Huaying You
发明人： Feng Xiao , Mingxia Wang , Guishu Zhou , Huaying You
IPC分类号： H01M6/14
CPC分类号： H01M10/0567
摘要： This invention relates to non-aqueous electrolytes, in particular, a non-aqueous electrolyte for lithium-ion secondary batteries. The electrolyte comprises regular organic solvents and electrolyte saline. The special characteristics are: the electrolyte also comprises mixed additives, said mixed additives comprising at least one of those of compound group A, at least one of those of compound group B, and one of those of compound group C wherein: compound group A are selected from inorganic saline including Li2CO3, Li2SO4, Li2SO3, LiNO3; compound group B are selected from vinylene carbonate, propylene carbonate; and compound group C are selected from ES, PS, DMS, DES, DMSO. The weight ratio can be A:B:C=0.1%-3.0%:0.5%-4.0%:1.0%-5.0%.
摘要翻译：本发明涉及非水电解质，特别是涉及锂离子二次电池的非水电解质。电解质包含常规有机溶剂和电解质盐水。其特征是电解质还包含混合添加剂，所述混合添加剂包括化合物A，化合物B中的至少一种和化合物C中的至少一种，其中化合物基团A为选自无机盐水，包括Li2CO3，Li2SO4，Li2SO3，LiNO3; 化合物B选自碳酸亚乙烯酯，碳酸亚丙酯; 和化合物C选自ES，PS，DMS，DES，DMSO。重量比可以是A：B：C = 0.1％-3.0％:0.5％-4.0％：1.0％-5.0％。

7. 发明申请

US20070105021A1 Type of mixed additives and electrolyte for lithium-ion secondary batteries using such mixed additives 有权
标题翻译：使用这种混合添加剂的锂离子二次电池的混合添加剂和电解质的种类
公开(公告)号：US20070105021A1
公开(公告)日：2007-05-10
申请号：US11583486
申请日：2006-10-18
申请人： Feng Xiao , Mingxia Wang , Guishu Zhou , Huaying You
发明人： Feng Xiao , Mingxia Wang , Guishu Zhou , Huaying You
IPC分类号： H01M10/40 , C23G5/00
CPC分类号： H01M10/0567 , H01M10/0525 , H01M10/4235 , H01M2300/0025 , H01M2300/0042
摘要： This invention discloses a type of mixed additives for electrolyte of lithium-ion secondary batteries, having the following characteristics: in weight percentage: biphenyl series: 0.5%˜95.4%; cyclohexylbenzene series: 1.1%˜93.8%; vinylene carbonate: 0.4%˜93.2%; phenyl vinyl sulfone: 0.5%˜96.5%; ethenyl sulfonyl benzene: 0.5%˜95.8%. This invention also discloses an electrolyte for lithium-ion secondary batteries comprising organic solvents and lithium saline, wherein the special characteristic is that it comprises 2%˜20% weight percentage of said mixed additives. The distinctive advantage of the mixed additives for lithium-ion secondary batteries of this invention is to effectively enhance the overcharging, low-temperature, and cycle properties of lithium-ion batteries. A lithium-ion battery having the mixed additives of this invention remains explosion-free, ignition-free and reliably safe when the lithium-ion secondary battery is overcharging. A battery of this invention's exemplary embodiment, when discharging at temperatures of −10° C. and −20° C., has high capacity, high medium voltage and low terminal inner resistance.
摘要翻译：本发明公开了一种锂离子二次电池用电解质混合添加剂，具有以下特征：重量百分比：联苯系列：0.5％〜95.4％环己基苯系列：1.1％〜93.8％; 碳酸亚乙烯酯：0.4％〜93.2％; 苯基乙烯基砜：0.5％〜96.5％; 乙烯基磺酰苯：0.5％〜95.8％。本发明还公开了一种包含有机溶剂和锂盐水的锂离子二次电池用电解质，其特征在于其占所述混合添加剂的2％〜20％重量百分比。本发明的锂离子二次电池用混合添加剂的显着优点在于有效地提高了锂离子电池的过充电，低温和循环性能。具有本发明的混合添加剂的锂离子电池在锂离子二次电池过充电时保持无爆炸，无点燃和可靠的安全。本发明示例性实施例的电池当在-10℃和-20℃的温度下放电时，具有高容量，高中等电压和低端子内阻。

8. 发明授权

US07700242B2 Type of mixed additives and electrolyte for lithium-ion secondary batteries using such mixed additives 有权
标题翻译：使用这种混合添加剂的锂离子二次电池的混合添加剂和电解质的种类
公开(公告)号：US07700242B2
公开(公告)日：2010-04-20
申请号：US11583486
申请日：2006-10-18
申请人： Feng Xiao , Mingxia Wang , Guishu Zhou , Huaying You
发明人： Feng Xiao , Mingxia Wang , Guishu Zhou , Huaying You
IPC分类号： H01M6/18
CPC分类号： H01M10/0567 , H01M10/0525 , H01M10/4235 , H01M2300/0025 , H01M2300/0042
摘要： This invention discloses a type of mixed additives for electrolyte of lithium-ion secondary batteries, having the following characteristics: in weight percentage: biphenyl series: 0.5% to 95.4%; cyclohexylbenzene series: 1.1% to 93.8%; vinylene carbonate: 0.4% to 93.2%; phenyl vinyl sulfone: 0.5% to 96.5%; ethenyl sulfonyl benzene: 0.5% to 95.8%. This invention also discloses an electrolyte for lithium-ion secondary batteries comprising organic solvents and lithium saline, wherein the special characteristic is that it comprises 2% to 20% weight percentage of said mixed additives. The distinctive advantage of the mixed additives for lithium-ion secondary batteries of this invention is to effectively enhance the overcharging, low-temperature, and cycle properties of lithium-ion batteries. A lithium-ion battery having the mixed additives of this invention remains explosion-free, ignition-free and reliably safe when the lithium-ion secondary battery is overcharging. A battery of this invention's exemplary embodiment, when discharging at temperatures of −10° C. and −20° C., has high capacity, high medium voltage and low terminal inner resistance.
摘要翻译：本发明公开了一种锂离子二次电池用电解质混合添加剂，具有以下特征：重量百分比：联苯系列：0.5〜95.4％环己基苯系列：1.1％〜93.8％; 碳酸亚乙烯酯：0.4％〜93.2％苯基乙烯基砜：0.5〜96.5％; 乙烯基磺酰苯：0.5％〜95.8％。本发明还公开了一种包含有机溶剂和锂盐的锂离子二次电池的电解质，其特征在于它包含2％至20％重量的所述混合添加剂。本发明的锂离子二次电池用混合添加剂的显着优点在于有效地提高了锂离子电池的过充电，低温和循环性能。具有本发明的混合添加剂的锂离子电池在锂离子二次电池过充电时保持无爆炸，无点燃和可靠的安全。本发明示例性实施例的电池当在-10℃和-20℃的温度下放电时，具有高容量，高中等电压和低端子内阻。

9. 发明申请

US20090042103A1 ADDITIVE MIXTURE FOR ELECTROLYTE OF LITHIUM ION SECONDARY BATTERY AND ELECTROLYTE OF LITHIUM ION SECONDARY BATTERY COMPRISING THE SAME 有权
标题翻译：锂离子二次电池电解质的添加剂和锂离子二次电池的电解质
公开(公告)号：US20090042103A1
公开(公告)日：2009-02-12
申请号：US12090728
申请日：2006-10-17
申请人： Feng Xiao , Mingxia Wang , Guishu Zhou , Huaying You
发明人： Feng Xiao , Mingxia Wang , Guishu Zhou , Huaying You
IPC分类号： H01M10/40
CPC分类号： H01M10/0567 , H01M10/0525 , H01M10/4235 , H01M2300/0025 , H01M2300/0042
摘要： An additive mixture of the electrolyte of lithium ion secondary batteries and the electrolyte of lithium ion secondary batteries including the said additive mixture, characterizing in that the additive mixture includes 0.5-95.4 wt % biphenyl based compound, 0.1-93.8 wt % cyclohexylbenzene based compound, 0.4-93.2 wt % vinylene carbonate, 0.5-96.5 wt % t-alkyl benzene based compound and 0.5-95.8 wt % ethenyl sulfonyl benzene, based on the whole weight of the additive mixture.
摘要翻译：锂离子二次电池的电解质和包括所述添加剂混合物的锂离子二次电池的电解质的添加混合物，其特征在于，所述添加剂混合物包含0.5-95.4重量％的联苯基化合物，0.1-93.8重量％的环己基苯基化合物， 0.4-93.2wt％碳酸亚乙烯酯，0.5-96.5wt％t-烷基苯基化合物和0.5-95.8wt％乙烯基磺酰苯，基于添加剂混合物的总重量。

10. 发明申请

US20080286646A1 Electrolytes for Lithium Ion Batteries and Their Fabrication Methods 审中-公开
标题翻译：锂离子电池用电解质及其制作方法
公开(公告)号：US20080286646A1
公开(公告)日：2008-11-20
申请号：US12093397
申请日：2006-11-23
申请人： Feng Xiao , Mingxia Wang , Guishu Zhou , Huaying You
发明人： Feng Xiao , Mingxia Wang , Guishu Zhou , Huaying You
IPC分类号： H01M10/26 , H01M10/24 , H01M2/14 , H01M10/28
CPC分类号： H01M10/0564 , H01M10/0567 , H01M10/058 , Y10T29/49108 , Y10T29/4911
摘要： Electrolytes for lithium ion batteries are provided. The electrolytes include lithium salts, organic solvents and additives. In particular, the additives include halogeno-benzene and/or its homologs, the S═O bond compounds, biphenyl and/or its homologs, phenylcyclohexane and/or its homologs, teraklylbenzenes, and di-cycladipate and/or its homologs. Lithium ion batteries using said electrolytes exhibit improved overcharging safety properties, high temperature storage stability properties and cycle life properties simultaneously.
摘要翻译：提供锂离子电池用电解液。电解质包括锂盐，有机溶剂和添加剂。特别地，添加剂包括卤代苯和/或其同系物，S-O键化合物，联苯和/或其同系物，苯基环己烷和/或其同系物，萜烯基苯和二环己二酸酯和/或其同系物。使用所述电解质的锂离子电池同时显示出改善的过充电安全性能，高温储存稳定性和循环寿命特性。

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