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1. 发明授权

US4352755A Production of maleic anhydride 失效
标题翻译：生产马来酸酐
公开(公告)号：US4352755A
公开(公告)日：1982-10-05
申请号：US204699
申请日：1980-11-06
申请人： Raymond Higgins , Graham J. Hutchings , Deborah A. Trebilco , Philip E. Starkey
发明人： Raymond Higgins , Graham J. Hutchings , Deborah A. Trebilco , Philip E. Starkey
IPC分类号： C07D307/60 , C07C51/25
CPC分类号： C07C51/252 , Y02P20/142
摘要： Maleic anhydride is produced by oxidizing a straight chain C.sub.4 hydrocarbon with oxygen in a stream comprising 25 to 60% by volume of the C.sub.4 hydrocarbon, 20 to 45% by volume of oxygen and optionally inert gases to produce a stream containing at least 21/2% by volume of maleic anhydride and condensing maleic anhydride substantially free from water from this stream.
摘要翻译：马来酸酐通过用包含25至60体积％的C 4烃，20至45体积％的氧气和任选的惰性气体的气流氧化直链C 4烃而产生，以产生含有至少21/2 马来酸酐的体积百分比并且从该流中基本上不含水的马来酸酐冷凝。

2. 发明授权

US4317777A Production of maleic acid and anhydride 失效
标题翻译：生产马来酸和酸酐
公开(公告)号：US4317777A
公开(公告)日：1982-03-02
申请号：US138318
申请日：1980-04-08
申请人： Raymond Higgins , Graham J. Hutchings
发明人： Raymond Higgins , Graham J. Hutchings
IPC分类号： C07D307/60 , B01J23/22 , B01J27/00 , B01J27/198 , B01J27/199 , B01J35/00 , C07B61/00 , C07C51/215 , C07C51/265 , C07D307/89
CPC分类号： C07C51/215 , B01J23/22 , B01J27/198 , B01J35/002 , B01J35/1014 , C07C51/265 , B01J2523/00
摘要： Hydrocarbons, particularly n-butane, are oxidized to acid anhydrides, especially maleic anhydride, by contacting them at concentrations above the flammable limit with oxygen in the presence of a vanadium/phosphorus mixed oxide catalyst having a surface area of at least 10 m.sup.2 /g. The concentration of inert gas is more than 70 molar percent and the oxygen concentration is greater than 13 molar percent.
摘要翻译：在具有至少10m 2 / g的表面积的钒/磷混合氧化物催化剂的存在下，通过使它们以高于易燃极限的浓度与氧接触将烃，特别是正丁烷氧化成酸酐，特别是马来酸酐。惰性气体的浓度大于70摩尔％，氧浓度大于13摩尔％。

3. 发明授权

US5268107A Modified clinoptilolite as an ion exchange material 失效
标题翻译：改性斜发沸石作为离子交换材料
公开(公告)号：US5268107A
公开(公告)日：1993-12-07
申请号：US815625
申请日：1991-12-30
申请人： Graham J. Hutchings , Themistoclis Themistocleous , Richard G. Copperthwaite
发明人： Graham J. Hutchings , Themistoclis Themistocleous , Richard G. Copperthwaite
IPC分类号： B01J39/14 , G21F9/12 , C02F1/42
CPC分类号： B01J39/14 , G21F9/12
摘要： An ion exchange material for the removal of radioisotope cations such as the cations of caesium and strontium from an aqueous environment containing the radioisotope cation comprises a modified clinoptilolite produced by treating a natural clinoptilolite with sodium hydroxide at a concentration of approximately 2M or with hydrochloric acid at a concentration of from 0.1 to 5M for a suitable treatment time and at a suitable treatment temperature. The modified clinoptilolite is especially effective in the removal of radioisotope cations from an aqueous environment.
摘要翻译：用于从含有放射性同位素阳离子的含水环境中去除放射性同位素阳离子如铯和锶的阳离子的离子交换材料包括通过用约2M浓度的氢氧化钠或盐酸处理天然斜发沸石而制备的改性斜发沸石在合适的处理时间和在合适的处理温度下，浓度为0.1至5M。修饰的斜发沸石在从水性环境中除去放射性同位素阳离子方面特别有效。

4. 发明授权

US5162598A Conversion of propane and butane 失效
标题翻译：丙烷和丁烷的转化
公开(公告)号：US5162598A
公开(公告)日：1992-11-10
申请号：US815627
申请日：1991-12-30
申请人： Graham J. Hutchings , Themistoclis Themistocleous , Richard G. Copperthwaite
发明人： Graham J. Hutchings , Themistoclis Themistocleous , Richard G. Copperthwaite
IPC分类号： B01J20060101 , B01J29/00 , B01J37/06 , C01B20060101 , C07C20060101 , C07C4/06 , C07C6/10
CPC分类号： B01J29/00 , B01J37/06 , C07C4/06 , C07C6/10 , C07C2529/70
摘要： A modified natural clinoptilolite, produced by treating a natural clinoptilolite with a suitable mineral acid or with a suitable alkali and then with a suitable mineral acid, is used as a catalyst in a process for the conversion of propane or butane to give a product containing at least 40% of ethene, propene or C.sub.4 hydrocarbons or a mixture thereof.
摘要翻译：在用于转化丙烷或丁烷的方法中使用通过用合适的无机酸或合适的碱处理天然斜发沸石，然后用合适的无机酸处理的改性天然斜发沸石作为催化剂，得到含有至少40％的乙烯，丙烯或C4烃或其混合物。

5. 发明授权

US4209423A Production of acid anhydrides and catalysts therefor 失效
标题翻译：生产酸酐及其催化剂
公开(公告)号：US4209423A
公开(公告)日：1980-06-24
申请号：US906251
申请日：1978-05-15
申请人： Graham J. Hutchings , Raymond Higgins
发明人： Graham J. Hutchings , Raymond Higgins
IPC分类号： C07D307/60 , B01J23/22 , B01J27/18 , B01J27/198 , B01J35/00 , C01B25/37 , C07B61/00 , C07C51/215 , C07C51/265 , B01J27/14 , C07D307/14
CPC分类号： C07C51/215 , B01J23/22 , B01J27/198 , B01J35/002 , C07C51/265
摘要： Catalysts for the oxidation of hydrocarbons to acid anhydrides, for example maleic and phthalic anhydrides, are prepared from a vanadium/phosphorus mixed oxide precursor by conditioning it by contact with a strong acid of concentration at least 3 N and solvent extraction to remove unwanted phases. The treated precursor is converted to a catalytically active form by heating. Novel catalysts containing phase X are produced. The catalysts may contain rare earth metal promoters.
摘要翻译：用于将烃氧化成酸酐（例如马来酸酐和邻苯二甲酸酐）的催化剂由钒/磷混合氧化物前体通过与浓度至少为3N的强酸接触进行调理并进行溶剂萃取以除去不需要的相来制备。经处理的前体通过加热转化为催化活性形式。制备含有相X的新型催化剂。催化剂可以含有稀土金属助催化剂。

6. 发明授权

US5264644A Preparation of conjugated dienes 失效
标题翻译：共轭二烯的制备
公开(公告)号：US5264644A
公开(公告)日：1993-11-23
申请号：US14058
申请日：1993-02-05
申请人： Ian D. Hudson , Graham J. Hutchings
发明人： Ian D. Hudson , Graham J. Hutchings
IPC分类号： B01J23/16 , C07C1/207 , C07C1/24
CPC分类号： C07C1/24 , B01J23/16 , C07C1/207 , C07C2527/167
摘要： The invention relates to a process for the preparation of a conjugated diene from the corresponding carbonyl compound having the same number of carbon atoms by dehydration at a temperature of 300.degree. to 450.degree. C. using a catalyst comprising aluminium phosphate having the cristobalite structure. This catalyst is superior to aluminium phosphate having the tridymite structure in the dehydration of carbonyl compounds and has advantages over boron phosphate catalysts. Using the process, isoprene may be prepared from 2-methyl butanal and/or methyl isopropyl ketone in high yields. Unexpectedly aluminium phosphate having the cristobalite structure is markedly superior to boron phosphate in converting methyl isopropyl ketone, which is an intermediate product formed in appreciable amounts in the dehydration of 2-methyl butanal to isoprene. This superiority significantly improves the process economics of the conversion reaction of 2-methyl butanal to isoprene.
摘要翻译：本发明涉及一种通过使用含有方石英结构的磷酸铝的催化剂，在300-450℃的温度下通过脱水从具有相同碳原子数的相应羰基化合物制备共轭二烯的方法。该催化剂优于羰基化合物脱水中具有鳞石英结构的磷酸铝，并且具有优于硼酸盐催化剂的优点。使用该方法，异戊二烯可以以高产率从2-甲基丁醛和/或甲基异丙基酮制备。出乎意料的是，在转化甲基异丙基酮时，具有方英石结构的磷酸铝显着优于磷酸氢盐，甲基异丙基酮是在2-甲基丁醛脱水至异戊二烯中以合理的量形成的中间产物。这种优势显着提高了2-甲基丁醛与异戊二烯的转化反应的工艺经济性。

7. 发明授权

US4983560A Modified zeolite catalysts 失效
标题翻译：改性沸石催化剂
公开(公告)号：US4983560A
公开(公告)日：1991-01-08
申请号：US242903
申请日：1988-09-12
申请人： Richard G. Copperthwaite , Themistoclis Themistocleous , Graham J. Hutchings
发明人： Richard G. Copperthwaite , Themistoclis Themistocleous , Graham J. Hutchings
IPC分类号： B01J29/70 , C10G11/05
CPC分类号： C10G11/05 , B01J29/70
摘要： There is disclosed a method for the modification of a natural clinoptilolite by acid treatment using a mineral acid at a suitable temperature and for a suitable period of time, followed by calcination, to produce a modified clinoptilolite which may be used as a catalyst in a reaction for the preparation of or transformation of hydrocarbons, e.g. the cracking of hydrocarbon products. There is also disclosed a method of regenerating the deactivated modified catalyst after use by treatment in the presence of nitrous oxide.

8. 发明授权

US4288372A Production of maleic anhydride 失效
标题翻译：生产马来酸酐
公开(公告)号：US4288372A
公开(公告)日：1981-09-08
申请号：US100141
申请日：1979-12-04
申请人： Graham J. Hutchings , Raymond Higgins
发明人： Graham J. Hutchings , Raymond Higgins
IPC分类号： C07D307/60 , B01J23/22 , B01J27/18 , B01J27/198 , B01J35/00 , C01B25/37 , C07B61/00 , C07C51/215 , C07C51/265
CPC分类号： C07C51/215 , B01J23/22 , B01J27/198 , B01J35/002 , C07C51/265
摘要： Catalysts for the oxidation of hydrocarbons to acid anhydrides, for example maleic and phthalic anhydrides, are prepared from a vanadium/phosphorus mixed oxide precursor by conditioning it by contact with a strong acid of concentration at least 3N and solvent extraction to remove unwanted phases. The treated precursor is converted to a catalytically active form by heating. Novel catalysts containing phase X are produced. The catalysts may contain rare earth metal promoters.
摘要翻译：用于将烃氧化成酸酐（例如马来酸酐和邻苯二甲酸酐）的催化剂由钒/磷混合氧化物前体制备，通过与浓度至少为3N的强酸接触进行调理并进行溶剂萃取以除去不期望的相。经处理的前体通过加热转化为催化活性形式。制备含有相X的新型催化剂。催化剂可以含有稀土金属助催化剂。

9. 发明授权

US4222945A Production of maleic anhydride 失效
标题翻译：生产马来酸酐
公开(公告)号：US4222945A
公开(公告)日：1980-09-16
申请号：US6554
申请日：1979-01-25
申请人： Raymond Higgins , Graham J. Hutchings
发明人： Raymond Higgins , Graham J. Hutchings
IPC分类号： B01J23/22 , B01J27/198 , B01J35/00 , C07C51/215 , C07C51/265 , C07D307/60
CPC分类号： C07C51/215 , B01J23/22 , B01J27/198 , B01J35/002 , B01J35/1014 , C07C51/265
摘要： Hydrocarbons, particularly n-butane, are oxidized to acid anhydrides, especially maleic anhydride, by contacting them at concentrations above the flammable limit with oxygen in the presence of a vanadium/phosphorus mixed oxide catalyst having a surface area of at least 10 m.sup.2 /g. The oxygen concentration is greater than 13 molar percent and/or the concentration of inert gas is less than 70 molar percent.
摘要翻译：在具有至少10m 2 / g的表面积的钒/磷混合氧化物催化剂的存在下，通过使它们以高于易燃极限的浓度与氧接触将烃，特别是正丁烷氧化成酸酐，特别是马来酸酐。氧浓度大于13摩尔％，和/或惰性气体的浓度小于70摩尔％。

10. 发明申请

US20130172625A1 METHODS FOR USING ALLYLIC OXIDATION CATALYSTS TO PERFORM OXIDATION REACTIONS 审中-公开
标题翻译：使用多种氧化催化剂进行氧化反应的方法
公开(公告)号：US20130172625A1
公开(公告)日：2013-07-04
申请号：US13581068
申请日：2011-02-10
申请人： Brian Tarbit , Graham J. Hutchings , Jennifer K. Edwards , Peter Miedziak
发明人： Brian Tarbit , Graham J. Hutchings , Jennifer K. Edwards , Peter Miedziak
IPC分类号： C07C45/34
CPC分类号： C07C45/34 , B01J21/063 , B01J21/18 , B01J23/44 , B01J23/52 , B01J23/63 , B01J23/8906 , B01J37/0201 , C07C49/627 , C07C49/653 , C07C49/603
摘要： Methods for using ailylic oxidation catalysts to perform oxidation reactions. In an exemplary method for catalyzing an ailylic oxidation reaction of the present disclosure, the method comprises the step of catalyzing an oxidation of an ailylic compound using an ailylic oxidation catalyst. In at least one embodiment, the ailylic oxidation catalyst comprises palladium, gold, and titanium, In an exemplary embodiment, the ailylic oxidation catalyst comprises 2.5% Aυ÷2.5% Pd/TiO2.
摘要翻译：使用二氧化硅氧化催化剂进行氧化反应的方法。在本公开的催化甲酰氧化反应的示例性方法中，所述方法包括使用芳族氧化催化剂催化芳族化合物的氧化的步骤。在至少一个实施方案中，所述芳族氧化催化剂包括钯，金和钛。在一个示例性实施方案中，所述芳族氧化催化剂包含2.5％的铕2.5％的Pd / TiO 2。

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