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1. 发明申请

US20060112612A1 Preparation of additive mixtures for mineral oils and mineral oil distillates 审中-公开
标题翻译：矿物油和矿物油馏分添加剂混合物的制备
公开(公告)号：US20060112612A1
公开(公告)日：2006-06-01
申请号：US11331336
申请日：2006-01-12
申请人： Matthias Krull , Gerhard Bettermann , Curd-Werner Adams , Werner Reimann
发明人： Matthias Krull , Gerhard Bettermann , Curd-Werner Adams , Werner Reimann
IPC分类号： C10L1/10
CPC分类号： C08K3/00 , C10L1/146 , C10L1/1641 , C10L1/1955 , C10L1/1963 , C10L1/1966 , C10L1/1973 , C10L1/1981 , C10L1/1985
摘要： The present invention provides a continuous process for preparing additive mixtures for mineral oils and mineral oil distillates, comprising A) a cold flow improver for middle distillates, and at least one further component selected from B) and C): B) a further cold flow improver, C) an organic solvent, which comprises mixing cold flow improver and optionally solvent by means of a static mixer, the temperature of the additive mixture at the outlet of the static mixer being from 0° to 100° C.
摘要翻译：本发明提供了用于制备用于矿物油和矿物油馏出物的添加剂混合物的连续方法，其包括A）用于中间馏分的冷流改进剂和至少一种选自B）和C）的另外的组分：B）另外的冷流改进剂，C）有机溶剂，其包括通过静态混合器将冷流改进剂和任选的溶剂混合，静态混合器出口处的添加剂混合物的温度为0℃至100℃

2. 发明授权

US07014667B2 Preparation of additive mixtures for mineral oils and mineral oil distillates 有权
标题翻译：矿物油和矿物油馏分添加剂混合物的制备
公开(公告)号：US07014667B2
公开(公告)日：2006-03-21
申请号：US10676962
申请日：2003-10-01
申请人： Matthias Krull , Gerhard Bettermann , Curd-Werner Adams , Werner Reimann
发明人： Matthias Krull , Gerhard Bettermann , Curd-Werner Adams , Werner Reimann
IPC分类号： C10L1/14 , B01F15/00 , B01F17/00 , C08K3/00 , C08F210/02
CPC分类号： C08K3/00 , C10L1/146 , C10L1/1641 , C10L1/1955 , C10L1/1963 , C10L1/1966 , C10L1/1973 , C10L1/1981 , C10L1/1985
摘要： The present invention provides a continuous process for preparing additive mixtures for mineral oils and mineral oil distillates, comprising A) a cold flow improver for middle distillates, and at least one further component selected from B) and C): B) a further cold flow improver, C) an organic solvent, which comprises mixing cold flow improver and optionally solvent by means of a static mixer, the temperature of the additive mixture at the outlet of the static mixer being from 0° C. to 100° C.
摘要翻译：本发明提供了用于制备用于矿物油和矿物油馏出物的添加剂混合物的连续方法，其包括A）用于中间馏分的冷流改进剂和至少一种选自B）和C）的另外的组分：B）另外的冷流改进剂，C）有机溶剂，其包括通过静态混合器将冷流改进剂和任选溶剂混合，静态混合器出口处的添加剂混合物的温度为0℃至100℃

3. 发明授权

US06969746B2 Process for the preparation of ethylene copolymers, and their use as additives to mineral oil and mineral oil distillates 失效
标题翻译：制备乙烯共聚物的方法及其作为矿物油和矿物油馏出物添加剂的用途
公开(公告)号：US06969746B2
公开(公告)日：2005-11-29
申请号：US10748011
申请日：2003-12-30
申请人： Matthias Krull , Werner Reimann , Wilhelm Zoller , Di Heinz Dieter Bühnen , Gerhard Bettermann
发明人： Matthias Krull , Werner Reimann , Wilhelm Zoller , Di Heinz Dieter Bühnen , Gerhard Bettermann
IPC分类号： C10L1/192 , B01J3/04 , B01J19/24 , C08F2/00 , C08F2/02 , C08F210/02 , C08F210/16 , C10L1/14 , C10L1/16 , C10L1/18 , C10L1/195 , C10L1/196 , C10L1/197 , C10L1/22
CPC分类号： B01J3/042 , B01J19/2415 , B01J2219/00168 , B01J2219/00184 , B01J2219/00186 , C08F210/02 , C08F210/16 , C10L1/143 , C10L1/1608 , C10L1/1616 , C10L1/1641 , C10L1/195 , C10L1/1955 , C10L1/1963 , C10L1/1966 , C10L1/1973 , C10L1/1985 , C10L1/221 , C10L1/224 , C10L1/2364 , C08F2/00 , C08F218/08 , C08F218/10 , C08F210/14
摘要： Process for the preparation of ethylene copolymers, and their use as additives to mineral oil and mineral oil distillates.The invention relates to a process for the preparation of terpolymers of ethylene and at least 2 further olefinically unsaturated compounds by polymerization in a tubular reactor fitted with at least one side branch, wherein the fresh monomer components, which are introduced into the tubular reactor via the reactor inlet (the primary stream) or via the side branch or side branches (secondary stream or secondary streams), in each of the streams contain ethylene and at most one further olefinically unsaturated compound.
摘要翻译：制备乙烯共聚物的方法及其作为矿物油和矿物油馏出物添加剂的用途。本发明涉及一种通过在装有至少一个侧枝的管式反应器中聚合制备乙烯和至少2种其它烯属不饱和化合物的三元共聚物的方法，其中新鲜单体组分通过反应器入口（主流）或经由侧分支或副分支（二级流或二级流）在每个流中含有乙烯和至多一种其它烯属不饱和化合物。

4. 发明授权

US5496482A Process for the preparation of alkali metal acetates 失效
标题翻译：碱金属乙酸盐的制备方法
公开(公告)号：US5496482A
公开(公告)日：1996-03-05
申请号：US984330
申请日：1992-12-02
申请人： Gerhard Bettermann , Gu/ nther Schimmel , Johannes Himmrich
发明人： Gerhard Bettermann , Gu/ nther Schimmel , Johannes Himmrich
IPC分类号： C09K3/18
CPC分类号： C09K3/18
摘要： To prepare a corrosion-inhibiting liquid de-icing agent based on alkali metal acetates, 30 to 50 percent strength by weight alkali metal hydroxide solution is introduced into a reaction container provided with a cooling device and a mixing device, and 85 to 100% strength acetic acid is metered into the reaction container until the ratio by weight of acetic acid to alkali metal hydroxide solution therein (0.30 to 0.45):1. A portion of this solution is transferred from the reaction container to a stirred dissolving tank and 0.03 to 1% by weight, relative to the batch, of benzotriazole and/or tolyltriazole and/or imidazole is dissolved therein. The resulting solution containing azole is introduced into the reaction container along with 0.01 to 0.2% by weight of phosphoric acid, relative to the batch. Acetic acid continues to be metered into the reaction container until the density of the solution in the reaction container is 1.07 to 1.39 g/cm.sup.3 at 20.degree. C. Small amounts of alkali metal hydroxide solution or acetic acid are then introduced into the reaction container until the pH of the solution therein is 9.2 to 9.8. Finally, this solution is withdrawn from the reaction container as a liquid de-icing agent.
摘要翻译：为了制备基于碱金属乙酸盐的腐蚀抑制液体除冰剂，将30-50％重量的碱金属氢氧化物溶液引入设置有冷却装置和混合装置的反应容器中，并将85至100％的强度将乙酸计量加入到反应容器中，直至乙酸与其中的碱金属氢氧化物溶液的重量比（0.30至0.45）：1。将该溶液的一部分从反应容器转移至搅拌溶解槽，相对于该批次为0.03〜1重量％的苯并三唑和/或甲苯基三唑和/或咪唑溶解于其中。将含有唑的所得溶液相对于批料与0.01至0.2重量％的磷酸一起引入反应容器中。乙酸继续计量加入到反应容器中，直到反应容器中的溶液的密度在20℃下为1.07至1.39g / cm 3。然后将少量碱金属氢氧化物溶液或乙酸引入反应容器中直到其溶液的pH值为9.2〜9.8。最后，将该溶液作为液体除冰剂从反应容器中取出。

5. 发明授权

US5238592A Liquid de-icing agent based on acetates and process for melting snow and ice on traffic surfaces with the aid of this agent 失效
标题翻译：基于乙酸的液体清除剂和用于在该助剂的助催化剂下，将雪和冰与交联表面熔融的方法
公开(公告)号：US5238592A
公开(公告)日：1993-08-24
申请号：US787370
申请日：1991-11-04
申请人： Achim Stankowiak , Josef Kapfinger , Gerhard Bettermann
发明人： Achim Stankowiak , Josef Kapfinger , Gerhard Bettermann
IPC分类号： C09K3/18 , E01H10/00
CPC分类号： C09K3/185 , C09K3/18
摘要： The de-icing agent described comprises an aqueous solution of at least one alkali metal acetate or at least one alkaline earth metal acetate or a mixture of the two and water as the main components, and 0.01 to 1% by weight of at least one water-soluble triazole compound or at least one water-soluble imidazole compound or a mixture of the two and, if appropriate, 0.01 to 0.5% by weight of at least one alkali metal phosphate as inhibitors. The process described for melting snow and ice on traffic surfaces comprises application of an effective amount of the novel de-icing agent to the ice- and/or snow-covered surfaces to be treated.
摘要翻译：所描述的除冰剂包括至少一种碱金属乙酸盐或至少一种碱土金属乙酸盐或两者和水的混合物作为主要组分的水溶液，和0.01至1重量％的至少一种水可溶性三唑化合物或至少一种水溶性咪唑化合物或两者的混合物，如果合适的话，以0.01至0.5重量％的至少一种碱金属磷酸盐作为抑制剂。描述用于在交通工具表面上融化雪和冰的过程包括将有效量的新颖除冰剂施加到待处理的冰和/或积雪的表面上。

6. 发明授权

US07872061B2 Preparation of additive mixtures for mineral oils and mineral oil distillates 有权
标题翻译：矿物油和矿物油馏分添加剂混合物的制备
公开(公告)号：US07872061B2
公开(公告)日：2011-01-18
申请号：US12247520
申请日：2008-10-08
申请人： Matthias Krull , Gerhard Bettermann , Curd-Werner Adams , Werner Reimann
发明人： Matthias Krull , Gerhard Bettermann , Curd-Werner Adams , Werner Reimann
IPC分类号： C08K3/00 , C08F210/02
CPC分类号： C08K3/00 , C10L1/146 , C10L1/1641 , C10L1/1955 , C10L1/1963 , C10L1/1966 , C10L1/1973 , C10L1/1981 , C10L1/1985
摘要： The present invention provides a continuous process for preparing additive mixtures for mineral oils and mineral oil distillates, comprising A) a cold flow improver for middle distillates, and at least one further component selected from B) and C): B) a further cold flow improver, C) an organic solvent, which comprises mixing cold flow improver and optionally solvent by means of a static mixer, the temperature of the additive mixture at the outlet of the static mixer being from 0° C. to 100° C.
摘要翻译：本发明提供了用于制备用于矿物油和矿物油馏出物的添加剂混合物的连续方法，其包括A）用于中间馏分的冷流改进剂和至少一种选自B）和C）的另外的组分：B）另外的冷流改进剂，C）有机溶剂，其包括通过静态混合器将冷流改进剂和任选溶剂混合，静态混合器出口处的添加剂混合物的温度为0℃至100℃

7. 发明授权

US06762253B2 Process for the preparation of ethylene copolymers, and their use as additives to mineral oil and mineral oil distillates 有权
标题翻译：制备乙烯共聚物的方法及其作为矿物油和矿物油馏出物添加剂的用途
公开(公告)号：US06762253B2
公开(公告)日：2004-07-13
申请号：US09956544
申请日：2001-09-18
申请人： Matthias Krull , Werner Reimann , Wilhelm Zoller , Heinz Dieter Bühnen , Gerhard Bettermann
发明人： Matthias Krull , Werner Reimann , Wilhelm Zoller , Heinz Dieter Bühnen , Gerhard Bettermann
IPC分类号： C08F200
CPC分类号： B01J3/042 , B01J19/2415 , B01J2219/00168 , B01J2219/00184 , B01J2219/00186 , C08F210/02 , C08F210/16 , C10L1/143 , C10L1/1608 , C10L1/1616 , C10L1/1641 , C10L1/195 , C10L1/1955 , C10L1/1963 , C10L1/1966 , C10L1/1973 , C10L1/1985 , C10L1/221 , C10L1/224 , C10L1/2364 , C08F2/00 , C08F218/08 , C08F218/10 , C08F210/14
摘要： The invention relates to a process for the preparation of terpolymers of ethylene and at least 2 further olefinically unsaturated compounds by polymerization in a tubular reactor fitted with at least one side branch, wherein the fresh monomer components, which are introduced into the tubular reactor via the reactor inlet (the primary stream) or via the side branch or side branches (secondary stream or secondary streams), in each of the streams contain ethylene and at most one further olefinically unsaturated compound.
摘要翻译：本发明涉及一种通过在装有至少一个侧枝的管式反应器中聚合制备乙烯和至少2种其它烯属不饱和化合物的三元共聚物的方法，其中新鲜单体组分通过反应器入口（主流）或经由侧分支或副分支（二级流或二级流）在每个流中含有乙烯和至多一种其它烯属不饱和化合物。

8. 发明授权

US4906445A Continuous process for complete removal or organic impurities from and complete decolorization of prepurified wet-process phosphoric acid 失效
标题翻译：用于完全去除或有机杂质的连续方法和完全脱湿的湿法磷酸完全脱色
公开(公告)号：US4906445A
公开(公告)日：1990-03-06
申请号：US311640
申请日：1989-02-16
申请人： Gunther Schimmel , Gerhard Bettermann , Gero Heymer , Friedrich Kolkmann
发明人： Gunther Schimmel , Gerhard Bettermann , Gero Heymer , Friedrich Kolkmann
IPC分类号： C01B25/234 , C01B25/235 , C01B25/46
CPC分类号： C01B25/461 , C01B25/235
摘要： A continuous process is indicated for complete removal of organic impurities from and complete decolorization of pre-purified wet-process phosphoric acid which has been purified by an extractive method using an organic solvent, freed from residual hydrofluoric acid by steam stripping and treated with hydrogen peroxide at elevated temperature, which comprises mixing the pre-purified wet-process phosphoric acid and the hydrogen peroxide in a mixing zone at a temperature of from 100.degree. to 200.degree. C., preferably 140.degree. to 160.degree. C., and allowing them to react at this temperature for a further 1 to 4 hours, cooling to from 85.degree. to 90.degree. C. the pre-purified wet-process phosphoric acid treated in this way and pumping it at this temperature with exclusion of air firstly through an activated charcoal bed which has been prepared on the basis of peat and has been steam-activated and has a BET surface area of from 800 to 1000 m.sup.2 /g, and subsequently through a silicon carbide and/or graphite bed while maintaining a pumping rate of less than 0.5 m.sup.3 /h of wet-process phosphoric acid per m.sup.3 of activated charcoal bed.
摘要翻译：指示完全除去有机杂质并完全脱色预纯化的湿法磷酸的连续方法，其通过萃取方法使用有机溶剂纯化，通过汽提除去残留的氢氟酸并用过氧化氢处理在高温下，其包括在预先纯化的湿法磷酸和过氧化氢的混合区中在100至200℃，优选140至160℃的温度下混合，并使它们在该温度下再反应1至4小时，冷却至85℃至90℃，预纯化的湿法磷酸以此方式处理并在该温度下泵送，首先通过活性炭排除空气基于泥炭制备并已蒸汽活化并具有800至1000m2 / g的BET表面积的床，随后通过碳化硅和/或石墨b 同时保持每立方米活性炭床的湿法磷酸的泵送速率小于0.5m 3 / h。

9. 发明申请

US20090184285A1 Preparation of Additive Mixtures For Mineral Oils and Mineral Oil Distillates 有权
标题翻译：矿物油和矿物油馏分添加剂混合物的制备
公开(公告)号：US20090184285A1
公开(公告)日：2009-07-23
申请号：US12247520
申请日：2008-10-08
申请人： Matthias KRULL , Gerhard BETTERMANN , Curd-Werner ADAMS , Werner REIMANN
发明人： Matthias KRULL , Gerhard BETTERMANN , Curd-Werner ADAMS , Werner REIMANN
IPC分类号： C09K5/10
CPC分类号： C08K3/00 , C10L1/146 , C10L1/1641 , C10L1/1955 , C10L1/1963 , C10L1/1966 , C10L1/1973 , C10L1/1981 , C10L1/1985
摘要： The present invention provides a continuous process for preparing additive mixtures for mineral oils and mineral oil distillates, comprisingA) a cold flow improver for middle distillates, and at least one further component selected from B) and C):B) a further cold flow improver,C) an organic solvent,which comprises mixing cold flow improver and optionally solvent by means of a static mixer, the temperature of the additive mixture at the outlet of the static mixer being from 0° C. to 100° C.
摘要翻译：本发明提供了用于制备用于矿物油和矿物油馏出物的添加剂混合物的连续方法，其包括A）用于中间馏分的冷流改进剂和至少一种选自B）和C）的另外的组分：B）另外的冷流改进剂，C）有机溶剂，其包括通过静态混合器将冷流改进剂和任选溶剂混合，静态混合器出口处的添加剂混合物的温度为0℃至100℃

10. 发明授权

US06509424B1 Process for the preparation of ethylene copolymers, and their use as additives to mineral oil and mineral oil distillates 失效
标题翻译：制备乙烯共聚物的方法及其作为矿物油和矿物油馏出物添加剂的用途
公开(公告)号：US06509424B1
公开(公告)日：2003-01-21
申请号：US09207219
申请日：1998-12-08
申请人： Matthias Krull , Werner Reimann , Wilhelm Zoller , Heinz Dieter Bühnen , Gerhard Bettermann
发明人： Matthias Krull , Werner Reimann , Wilhelm Zoller , Heinz Dieter Bühnen , Gerhard Bettermann
IPC分类号： C08F202
CPC分类号： B01J3/042 , B01J19/2415 , B01J2219/00168 , B01J2219/00184 , B01J2219/00186 , C08F210/02 , C08F210/16 , C10L1/143 , C10L1/1608 , C10L1/1616 , C10L1/1641 , C10L1/195 , C10L1/1955 , C10L1/1963 , C10L1/1966 , C10L1/1973 , C10L1/1985 , C10L1/221 , C10L1/224 , C10L1/2364 , C08F2/00 , C08F218/08 , C08F218/10 , C08F210/14
摘要： The invention relates to a process for the preparation of terpolymers of ethylene and at least 2 further olefinically unsaturated compounds by polymerization in a tubular reactor fitted with at least one side branch, wherein the fresh monomer components, which are introduced into the tubular reactor via the reactor inlet (the primary stream) or via the side branch or side branches (secondary stream or secondary streams), in each of the streams contain ethylene and at most one further olefinically unsaturated compound.
摘要翻译：本发明涉及一种通过在装有至少一个侧枝的管式反应器中聚合制备乙烯和至少2种其它烯属不饱和化合物的三元共聚物的方法，其中新鲜单体组分通过反应器入口（主流）或经由侧分支或副分支（二级流或二级流）在每个流中含有乙烯和至多一种其它烯属不饱和化合物。

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