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1. 发明授权

US07671165B2 Method of forming polycarbonate 有权
标题翻译：形成聚碳酸酯的方法
公开(公告)号：US07671165B2
公开(公告)日：2010-03-02
申请号：US12122234
申请日：2008-05-16
申请人： Hans-Peter Brack , Peter K. Davis , David Domingo Fuster , Jorge Garcia Agudo , Gerardo Hidalgo Llinas , Miguel Angel Salomon Cheliz , Ignacio Vic Fernandez , Laurus van der Wekke , Dennis James Patrick Maria Willemse
发明人： Hans-Peter Brack , Peter K. Davis , David Domingo Fuster , Jorge Garcia Agudo , Gerardo Hidalgo Llinas , Miguel Angel Salomon Cheliz , Ignacio Vic Fernandez , Laurus van der Wekke , Dennis James Patrick Maria Willemse
IPC分类号： C08G64/00 , B28B3/20
CPC分类号： C08G64/205 , B01J19/1862 , B01J19/20 , B01J2219/0004 , C08G64/307
摘要： A method of forming polycarbonate includes the steps of introducing a plurality of reaction components to a reactor operating under melt polymerization conditions and removing ester-substituted phenol from the reactor. The plurality of reaction components include a dihydroxy compound, an ester-substituted diaryl carbonate, and a melt transesterification catalyst. The reaction components are introduced in a plurality of reaction component streams. A first reaction component streams includes a melt transesterification catalyst dissolved or suspended in a liquid carrier containing an ester-substituted phenol. The composition of the first reaction component stream is selected such that ester-substituted phenol is not generated as a reaction product in the first reaction component stream.
摘要翻译：形成聚碳酸酯的方法包括以下步骤：将多个反应组分引入到在熔融聚合条件下操作的反应器中，并从反应器中除去酯取代的酚。多个反应组分包括二羟基化合物，酯取代的碳酸二芳基酯和熔融酯交换催化剂。将反应组分引入多个反应组分流中。第一反应组分流包括溶解或悬浮在含有酯取代的苯酚的液体载体中的熔融酯交换催化剂。选择第一反应组分流的组成，使得在第一反应组分流中不产生酯取代的酚作为反应产物。

2. 发明授权

US07645851B2 Polycarbonate with reduced color 有权
标题翻译：聚碳酸酯减少颜色
公开(公告)号：US07645851B2
公开(公告)日：2010-01-12
申请号：US11688551
申请日：2007-03-20
申请人： Sjef Berndsen , Hans Peter Brack , Bernd Jansen , Edward Kung , Daniel Lowery , Patrick Joseph McCloskey , Dennis Karlik , Gerardo Hidalgo Llinas
发明人： Sjef Berndsen , Hans Peter Brack , Bernd Jansen , Edward Kung , Daniel Lowery , Patrick Joseph McCloskey , Dennis Karlik , Gerardo Hidalgo Llinas
IPC分类号： C08G64/00 , C08G63/18
CPC分类号： C08K5/49 , C08L69/00
摘要： A method of making polycarbonate includes the steps of forming polycarbonate by a melt transesterification method using an activated diaryl carbonate, and compounding the polycarbonate with a phosphorus-containing compound that has an abstractable proton or hydrolyzable group. The phosphorus-containing compound is compounded with the polycarbonate in an amount sufficient to result in an improvement in the color properties of the polycarbonate as compared to pellets formed from the same polycarbonate without addition of the phosphorus-containing compound.
摘要翻译：制备聚碳酸酯的方法包括通过使用活化的碳酸二芳基酯的熔体酯交换法形成聚碳酸酯的步骤，并将聚碳酸酯与具有可抽提的质子或可水解基团的含磷化合物混合。含磷化合物与聚碳酸酯混合，其量足以导致与不加入含磷化合物相同的聚碳酸酯形成的粒料相比，聚碳酸酯的着色性能得到改善。

3. 发明授权

US5824620A Heterogeneous metallocene catalysts and use thereof in olefin polymerization process 失效
标题翻译：非均相茂金属催化剂及其在烯烃聚合过程中的应用
公开(公告)号：US5824620A
公开(公告)日：1998-10-20
申请号：US958880
申请日：1997-10-27
申请人： Wilfried Michiels Vega , Pilar Lafuente Canas , Antonio Munoz-Escalona Lafuente , Gerardo Hidalgo Llinas , Jose Sancho Royo , Luis Mendez Llatas
发明人： Wilfried Michiels Vega , Pilar Lafuente Canas , Antonio Munoz-Escalona Lafuente , Gerardo Hidalgo Llinas , Jose Sancho Royo , Luis Mendez Llatas
IPC分类号： C07F17/00 , C08F4/02 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00
CPC分类号： C07F17/00 , C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/65922 , Y10S526/943
摘要： This invention is related to a method for the preparation of heterogeneous catalysts, useful for the production of poliolefins. The method is characterized because said catalysts are obtained by supporting onto solids soluble metallocenes possessing one or more functional groups. Said functional groups are characterized because they can react with other reactive groups on the surface of the solids. The reactive groups on the solids can be part of said solids or incorporated by means of chemical modification. These catalyst systems are especially appropiated for the polymerization of one or several 1-olefins having from 2 to 20 carbon atoms in their chain. Further, they are especially appropiated for the copolymerization of ethylene with 1-olefins having from 3 to 20 carbon atoms in their chains. These polymerization processes can be carried out in gas-phase slurry or solution, at high temperatures and pressures.
摘要翻译：本发明涉及制备用于生产聚烯烃的非均相催化剂的方法。所述方法的特征在于所述催化剂通过支持具有一个或多个官能团的固体可溶性金属茂获得。所述官能团的特征在于它们可以与固体表面上的其它反应性基团反应。固体上的反应性基团可以是所述固体的一部分或通过化学改性掺入。这些催化剂体系尤其适用于其链中具有2至20个碳原子的一种或多种1-烯烃的聚合。此外，它们特别适用于乙烯与其链中具有3至20个碳原子的1-烯烃的共聚。这些聚合方法可以在气相浆液或溶液中，在高温和高压下进行。

4. 发明授权

US08263729B2 Method for making polycarbonate 有权
标题翻译：制作聚碳酸酯的方法
公开(公告)号：US08263729B2
公开(公告)日：2012-09-11
申请号：US12974197
申请日：2010-12-21
申请人： Alfredo Lopez Carretero , David Domingo Fuster , Gerardo Hidalgo Llinas , Ignacio Vic Fernandez , Miguel Angel Salomon Cheliz
发明人： Alfredo Lopez Carretero , David Domingo Fuster , Gerardo Hidalgo Llinas , Ignacio Vic Fernandez , Miguel Angel Salomon Cheliz
IPC分类号： C08G64/00 , C08G63/02
CPC分类号： C08G64/307
摘要： A method of making polycarbonate comprises polymerizing, in a melt polymerization reaction, an aromatic dihydroxy compound and a diaryl carbonate in a presence of a polymerization catalyst and producing a by-product vapor stream comprising the dihydroxy compound, the diaryl carbonate and a diaryl carbonate by-product, adding a low vapor pressure compound to the by-product vapor stream to produce a modified by-product vapor stream, introducing the modified by-product vapor stream to a separation unit, removing the volatile diaryl carbonate by-product from the modified by-product vapor stream in the separation unit to form a treated by-product stream and returning the treated by-product stream to the polymerization reaction. Alternatively, the low vapor pressure compound can be added directly to the separation unit.
摘要翻译：一种制备聚碳酸酯的方法包括在熔融聚合反应中，在聚合催化剂存在下聚合芳族二羟基化合物和碳酸二芳基酯，并产生包含二羟基化合物，碳酸二芳基酯和碳酸二芳基酯的副产物蒸气流产物，向副产物蒸汽流中加入低蒸汽压化合物以产生改性副产物蒸气流，将改性副产物蒸汽流引入分离单元，从经修饰的蒸汽流中除去挥发性碳酸二芳酯副产物在分离单元中产生副产物蒸汽流以形成经处理的副产物流并将处理的副产物流返回到聚合反应中。或者，低蒸气压化合物可以直接添加到分离单元。

5. 发明申请

US20090286952A1 METHOD OF FORMING POLYCARBONATE 有权
标题翻译：形成聚碳酸酯的方法
公开(公告)号：US20090286952A1
公开(公告)日：2009-11-19
申请号：US12122234
申请日：2008-05-16
申请人： Hans-Peter Brack , Peter K. Davis , David Domingo Fuster , Jorge Garcia Agudo , Gerardo Hidalgo Llinas , Miguel Angel Salomon Cheliz , Ignacio Vic Fernandez , Laurus van der Wekke , Dennis James Willemse
发明人： Hans-Peter Brack , Peter K. Davis , David Domingo Fuster , Jorge Garcia Agudo , Gerardo Hidalgo Llinas , Miguel Angel Salomon Cheliz , Ignacio Vic Fernandez , Laurus van der Wekke , Dennis James Willemse
IPC分类号： C08G64/30
CPC分类号： C08G64/205 , B01J19/1862 , B01J19/20 , B01J2219/0004 , C08G64/307
摘要： A method of forming polycarbonate includes the steps of introducing a plurality of reaction components to a reactor operating under melt polymerization conditions and removing ester-substituted phenol from the reactor. The plurality of reaction components include a dihydroxy compound, an ester-substituted diaryl carbonate, and a melt transesterification catalyst. The reaction components are introduced in a plurality of reaction component streams. A first reaction component streams includes a melt transesterification catalyst dissolved or suspended in a liquid carrier containing an ester-substituted phenol. The composition of the first reaction component stream is selected such that ester-substituted phenol is not generated as a reaction product in the first reaction component stream.
摘要翻译：形成聚碳酸酯的方法包括以下步骤：将多个反应组分引入到在熔融聚合条件下操作的反应器中，并从反应器中除去酯取代的酚。多个反应组分包括二羟基化合物，酯取代的碳酸二芳基酯和熔融酯交换催化剂。将反应组分引入多个反应组分流中。第一反应组分流包括溶解或悬浮在含有酯取代的苯酚的液体载体中的熔融酯交换催化剂。选择第一反应组分流的组成，使得在第一反应组分流中不产生酯取代的酚作为反应产物。

6. 发明授权

US06388029B1 Process for obtaining polyolefins 失效
标题翻译：获得聚烯烃的方法
公开(公告)号：US06388029B1
公开(公告)日：2002-05-14
申请号：US09584518
申请日：2000-05-31
申请人： Gerardo Hidalgo Llinas , Bego{overscore (n)}a Pe{overscore (n)}a Garcia , Antonio Mu{overscore (n)}oz-Escalona , Jose Sancho Royo
发明人： Gerardo Hidalgo Llinas , Bego{overscore (n)}a Pe{overscore (n)}a Garcia , Antonio Mu{overscore (n)}oz-Escalona , Jose Sancho Royo
IPC分类号： C08F442
CPC分类号： C08F10/00 , C08F4/61912 , C08F4/61916 , C08F4/61922 , Y10S526/943
摘要： Catalytic systems particularly suitable for the polymerization of &agr;-olefins containing from two to 20 carbon atoms, as well as for the copolymerization of ethylene with &agr;-olefins containing from three to 20 carbon atoms, dienes, and cycloalkenes in processes wherein the catalyst is suspended in a solvent, in processes in gas phase, as well as in mass polymerization processes at high temperatures and pressures, are disclosed. The catalytic system is a mixture of a catalyst component A and a co-catalyst component B. The catalyst component A is formed by a functionalized inorganic porous oxide, by an organoaluminium compound and by an organometallic compound of a metal of the groups 3, 4, 5, or 6 of the periodic table. Functionalization of the inorganic oxide is by introduction of functional groups to be used to strongly fix the organoaluminium compound and the organometallic compound. The co-catalyst component B, which is used for the activation of the catalyst, is formed of organoaluminium compounds, perfluorinated derivatives of boron, or a mixture thereof.
摘要翻译：在催化剂悬浮的方法中，特别适用于含有2至20个碳原子的α-烯烃的聚合以及乙烯与含有3至20个碳原子的α-烯烃的二烯和环烯烃的共聚反应的催化体系在溶剂中，在气相的方法中以及在高温和高压下的大量聚合方法中都有公开。催化剂体系是催化剂组分A和助催化剂组分B的混合物。催化剂组分A由官能化的无机多孔氧化物，有机铝化合物和第3,4族金属的有机金属化合物形成，5或6。无机氧化物的官能化是通过引入用于强力固定有机铝化合物和有机金属化合物的官能团。用于活化催化剂的助催化剂组分B由有机铝化合物，硼的全氟化衍生物或其混合物形成。

7. 发明授权

US6114555A Functionalized metallocene compounds, synthesis process and use thereof 失效
标题翻译：官能化茂金属化合物，合成方法及其应用
公开(公告)号：US6114555A
公开(公告)日：2000-09-05
申请号：US300301
申请日：1999-04-27
申请人： Gerardo Hidalgo Llinas , Antonio Munoz-Escalona Lafuente
发明人： Gerardo Hidalgo Llinas , Antonio Munoz-Escalona Lafuente
IPC分类号： C07F17/00 , C07F17/02 , C08F4/64 , C08F4/6592 , C08F10/00 , C07F7/00
CPC分类号： C07F17/00 , C08F10/00 , C08F4/65927 , Y02P20/55 , Y10S526/943
摘要： The present invention relates to nietallocene compounds characterized by the following formulas:(LR.sub.k).sub.z [LR.sub.k-f (R.sup.I OH).sub.f ].sub.x MX.sub.yI ##STR1## wherein: L, equal to or different from each other, is selected from the group comprising: cyclopentadienyl, indenyl, tetrahydroindenyl, fluorenyl, octahydrofluorenyl or benzoindenyl; each R is independently selected from hydrogen, C.sub.1 -C.sub.20 alkyl, C.sub.3 -C.sub.20 cycloalkyl, C.sub.6 -C.sub.20 aryl, C.sub.3 -C.sub.20 alkenyl C.sub.7 -C.sub.20 arylalkyl, C.sub.7 -C.sub.20 alkylaryl, C.sub.8 -C.sub.20 arylalkenyl, linear or branched, optionally substituted by 1 to 10 halogen atoms, or a group SiR.sup.II.sub.3 ; each R.sup.I equal to or different from each other, is a group SiR.sup.II.sub.2, or a divalent aliphatic or aromatic hydrocarbon group containing from 1 to 20 carbon atoms, optionally containing from 1 to 5 heteroatoms of groups 14 to 16 of the periodic table of the elements and boron; each Q is independently selected from B, C, Si, Ge, Sn; M is a metal of group 3, 4 or 10 of the Periodic Table, Laitlanide or Actinide; each X is independently selected from: hydrogen, chlorine, bromine, OR.sup.II, NR.sup.II.sub.2, C.sub.1 -C.sub.20 alkyl or C.sub.6 -C.sub.20 aryl; each R.sup.II is independently selected from C.sub.1 -C.sub.20 alkyl, C.sub.3 -C.sub.20 cycloalkyl, C.sub.6 -C.sub.20 aryl, C.sub.3 -C.sub.20 alkenyl, C.sub.7 -C.sub.20 arylalkyl, C.sub.7 -C.sub.20 arylalkenyl or alkylaryl, linear or branched; R.sup.II is methyl, ethyl, isopropyl; L' is N or O.
摘要翻译：本发明涉及以下列化学式表征的新戊烯化合物：（LRk）z [LRk-f（RIOH）f] xMXyI其中L，彼此相同或不同，选自：环戊二烯基，茚基，四氢茚基，芴基，八氢芴基或苯并茚基; 每个R独立地选自氢，C 1 -C 20烷基，C 3 -C 20环烷基，C 6 -C 20芳基，C 3 -C 20烯基C 7 -C 20芳基烷基，C 7 -C 20烷基芳基，直链或支链的C 8 -C 20芳基烯基，任选被1 至10个卤素原子，或SiRII 3基团; 每个RI彼此相同或不同，是SiRII2族或含有1至20个碳原子的任选含有1至5个元素周期表第14至16族的杂原子的二价脂族或芳族烃基和硼; 每个Q独立地选自B，C，Si，Ge，Sn; M是元素周期表中第3,4或10族的金属，Laitlanide或锕系元素; 每个X独立地选自：氢，氯，溴，ORII，NRII2，C 1 -C 20烷基或C 6 -C 20芳基; 每个RII独立地选自直链或支链的C 1 -C 20烷基，C 3 -C 20环烷基，C 6 -C 20芳基，C 3 -C 20烯基，C 7 -C 20芳基烷基，C 7 -C 20芳基烯基或烷基芳基; RII是甲基，乙基，异丙基; L'是N或O.

8. 发明申请

US20110274838A1 SYSTEM AND PROCESS FOR THE CONTINUOUS VACUUM COATING OF A MATERIAL IN WEB FORM 审中-公开
标题翻译：网页形式的材料的连续真空涂料的系统和工艺
公开(公告)号：US20110274838A1
公开(公告)日：2011-11-10
申请号：US12674233
申请日：2008-08-05
申请人： Francisco Villuendas Yuste , Rafael Alonso Esteban , Inigo Salinas Ariz , Gerardo Hidalgo Llinas
发明人： Francisco Villuendas Yuste , Rafael Alonso Esteban , Inigo Salinas Ariz , Gerardo Hidalgo Llinas
IPC分类号： C23C16/54 , C23C16/50 , C23C16/02 , C23C14/35 , C23C16/52 , C23C16/44 , C23C16/06 , C23C14/34 , C23C16/458 , C23C16/56
CPC分类号： C23C14/562 , C23C16/545
摘要： The system (1) for the continuous vacuum coating of a continuously suppliable material in web form (2) provided with feed means; at least one inlet chamber (4), wherein the transition between the inlet atmospheric pressure and the vacuum pressure of a coating chamber (5) incorporating at least one vacuum deposition module (6) for depositing metallic and/or dielectric components on the material in web form is carried out; at least one outlet chamber (7); and collecting means (8) which collect the coated material in web form. The system further comprises drive and support means (9), on which the material in web form is fixed for its transport and by one of its faces, which material follows a preferably straight path at least through the coating chamber.
摘要翻译：用于连续提供真空涂料的系统（1），所述系统包括具有进料装置的网状（2）的连续供应材料; 至少一个入口室（4），其中入口大气压力和涂覆室（5）的真空压力之间的过渡结合有至少一个用于在所述材料上沉积金属和/或电介质成分的真空沉积模块（6）网页形式进行; 至少一个出口室（7）; 以及收集装置（8），其收集网状的涂覆材料。该系统还包括驱动和支撑装置（9），在其上以网状形式的材料被固定以便运输，并且通过其一个表面，该材料至少穿过涂覆室遵循优选的直线路径。

9. 发明申请

US20070299241A1 Manufacture of polycarbonates 有权
标题翻译：聚碳酸酯的制造
公开(公告)号：US20070299241A1
公开(公告)日：2007-12-27
申请号：US11426467
申请日：2006-06-26
申请人： David Domingo , Ignacio Vic Fernandez , Jorge Garcia Agudo , Gerardo Hidalgo-Llinas , Alfredo Lopez-Carretero , Miguel Angel Salomon
发明人： David Domingo , Ignacio Vic Fernandez , Jorge Garcia Agudo , Gerardo Hidalgo-Llinas , Alfredo Lopez-Carretero , Miguel Angel Salomon
IPC分类号： C08G64/00
CPC分类号： C08G64/00 , C08G64/307
摘要： A method of producing a polycarbonate is provided. In an embodiment of the present invention the method includes the steps of: (i) introducing to a melt polymerization reactor system a reaction mixture having a first dihydroxy compound and an acid stabilizer, a carbonate source, and a polymerization catalyst system containing K2HPO4; and (ii) allowing the reaction mixture to polymerize thereby forming polycarbonate.
摘要翻译：提供了制造聚碳酸酯的方法。在本发明的一个实施方案中，该方法包括以下步骤：（i）向熔体聚合反应器系统引入具有第一二羟基化合物和酸稳定剂，碳酸酯源和含有K 2 HPO 4; 和（ii）使反应混合物聚合，由此形成聚碳酸酯。

10. 发明申请

US20060094854A1 METHOD FOR MAKING POLYCARBONATE 有权
标题翻译：制备聚碳酸酯的方法
公开(公告)号：US20060094854A1
公开(公告)日：2006-05-04
申请号：US10979479
申请日：2004-11-01
申请人： Gerardo Hidalgo , Patrick McCloskey , Alberto Nisoli , Lina Prada
发明人： Gerardo Hidalgo , Patrick McCloskey , Alberto Nisoli , Lina Prada
IPC分类号： C08G64/00 , B01J19/00
CPC分类号： B01D3/146 , B01J2219/00038 , B01J2219/0004 , C08G64/307 , Y02P20/582
摘要： A method of making polycarbonate comprises melt-polymerizing an aromatic dihydroxy compound and a carbonic acid diester in a presence of a polymerization catalyst in a reactor system producing a byproduct stream, wherein the polymerization catalyst comprises a quaternary phosphonium compound; and purifying the byproduct stream to separate the carbonic acid diester, wherein the separated carbonic acid diester has a phosphorous concentration of less than or equal to about 30 parts per million.
摘要翻译：制备聚碳酸酯的方法包括在聚合催化剂存在下在产生副产物流的反应器系统中使芳族二羟基化合物和碳酸二酯熔融聚合，其中聚合催化剂包含季鏻化合物; 并纯化副产物流以分离碳酸二酯，其中分离的碳酸二酯的磷浓度小于或等于约30ppm。

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