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    • 1. 发明授权
    • High strain electrostrictive polymer
    • 高应变电致伸缩聚合物
    • US07078101B1
    • 2006-07-18
    • US10719852
    • 2003-11-21
    • Thomas S. RamotowskiGeorge J. KavarnosQiming Zhang
    • Thomas S. RamotowskiGeorge J. KavarnosQiming Zhang
    • B32B27/30
    • C08F214/22Y10T428/3154
    • The present invention is a new class of terpolymers for use as high strain electrostrictive polymer films. More particularly, the invention is a class of electrostrictive terpolymers comprising vinylidene fluoride (VDF), trifluoroethylene (TrFE) and at least one monomer having at least one halogen atom side group. The monomer is preferably an ethylene-based monomer and preferably selected to favor gauche-type linkage along the polymer backbone. The halogen atom side group is preferably large enough to move or cause adjacent polymer chains to be farther apart from or away from each other than in the absence of such side group, but not so large that it would inhibit polymer crystallites from forming. The monomer is preferably a chloro-monomer such as chlorofluoroethylene (CFE). The chlorofluoroethylene (CFE) is preferably 1-chloro-2-fluoroethylene or 1-chloro-1-fluoroethylene. The chlorofluoroethylene (CFE) favors gauche-type linkage which favors high electrostrictive strains.
    • 本发明是用作高应变电致伸缩聚合物膜的新型三元共聚物。 更具体地,本发明是一类包含偏二氟乙烯(VDF),三氟乙烯(TrFE)和至少一种具有至少一个卤素原子侧基的单体的电致伸缩三元共聚物。 单体优选为基于乙烯的单体,并且优选选择为有利于沿着聚合物主链的高密度连接。 卤素原子侧基优选足够大以使相邻的聚合物链远离或远离彼此而不是不存在这样的侧基,但不大于其将抑制聚合物微晶形成。 单体优选为氯代单体如氯氟乙烯(CFE)。 氯氟乙烯(CFE)优选为1-氯-2-氟乙烯或1-氯-1-氟乙烯。 氯氟乙烯(CFE)有利于高电导菌株的高密度连锁。