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    • 3. 发明申请
    • PROCESS FOR SEPARATING LIQUID MIXTURES
    • 分离液体混合物的方法
    • US20110266219A1
    • 2011-11-03
    • US13056760
    • 2009-08-19
    • Erik Everhardus Bernardus MeulemanPeter GeerdinkEarl Lawrence Vincent GoetheerEva Sanchez Fernandez
    • Erik Everhardus Bernardus MeulemanPeter GeerdinkEarl Lawrence Vincent GoetheerEva Sanchez Fernandez
    • B01D61/36B01D63/00
    • B01D61/362B01D61/364B01D63/02B01D63/082B01D2313/146B01D2313/22C02F1/447C02F1/448
    • The invention is directed to a process for separating liquid mixtures and an apparatus for separating liquid mixtures. The process of the invention comprises: passing a liquid stream of the liquid mixture over a permeable non-porous selective membrane, said membrane being selective for at least one of said first and second compounds, whereby at least part of the liquid stream passes through said membrane leaving the other side of said membrane as a vapor, with the remainder of the liquid stream forming a retentate stream, and condensing said vapor on a condenser surface having a lower temperature than the liquid stream to give a distillate stream, said condenser surface forming a non-permeable heat conducting separation wall between said distillate stream and a cooling stream which cooling stream is a) said feed stream, in case the feed stream has a sufficiently low temperature to serve as a suitable cooling medium for the condensation of the permeate vapor, or b) said retentate stream, in case the feed stream has such a high temperature that would make it unsuitable as a cooling medium for the condensation of the permeate vapor, so that heat can be transferred between the vapor and the cooling stream, wherein the distance between said membrane and said condenser surface is smaller than 10 mm, and wherein the vapor pressure of said distillate stream is lower than the vapor pressure of the compounds in the liquid stream for which the permeable non-porous selective membrane is selective, resulting in sufficient driving force for the separation to occur.
    • 本发明涉及一种用于分离液体混合物的方法和用于分离液体混合物的装置。 本发明的方法包括:将液体混合物的液体流通过可渗透的无孔选择性膜,所述膜对于所述第一和第二化合物中的至少一种是选择性的,由此至少部分液体流通过所述 膜离开所述膜的另一侧为蒸汽,其余液体流形成滞留物流,并将所述蒸气冷凝在具有比液体流低的温度的冷凝器表面上,得到馏出物流,所述冷凝器表面形成 在所述馏出物流和冷却流之间的不可渗透的导热分离壁,冷却流是a)所述进料流,在进料流具有足够低的温度以用作合适的冷却介质以冷凝渗透气体 ,或b)所述滞留物流,在进料流具有如此高的温度使其不适合作为冷凝剂的冷却介质的情况下 使得热量可以在蒸气和冷却流之间传递,其中所述膜和所述冷凝器表面之间的距离小于10mm,并且其中所述馏出物流的蒸气压低于蒸气 在可渗透的非多孔选择性膜是选择性的液体流中的化合物的压力,导致足够的驱动力进行分离。