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    • 3. 发明授权
    • Ultrahigh brightness calcined clay pigment, manufacture & use thereof
    • 超高亮度煅烧粘土颜料,制造及使用
    • US5624488A
    • 1997-04-29
    • US497241
    • 1995-06-30
    • Ellen S. ForbusPaul R. SuitchThomas Dombrowski
    • Ellen S. ForbusPaul R. SuitchThomas Dombrowski
    • C09C1/42C04B14/10
    • C09C1/42C01P2004/51C01P2004/61C01P2006/14C01P2006/16C01P2006/60C01P2006/62C01P2006/63C01P2006/64C01P2006/80C01P2006/90Y10T428/31993
    • A selected kaolin crude or crude fraction is purified by physical or physical/chemical means, such as froth flotation and/or selective flocculation, to remove discrete particles of TiO.sub.2 and in some cases, discrete iron minerals. The pure (or purified clay) must then be agitated in the presence of water with a particulate grinding media such as, for example, sand, alumina or zirconia beads, to increase the 2 micron content of the kaolin. An intermediate ground product that contains a substantial weight percentage of particles finer than 1 micron is generated as a result of grinding. The particles finer than 1 micron in the ground kaolin also include those particles in the previously pure or purified kaolin that were present in the naturally occurring clay. A pulp of the ground clay is then fractionated to remove particles larger than 2 microns, e.g., to remove at least 95%, preferably at 100% by weight, of the particles larger than 2 microns, while minimizing the removal of particles finer than 1 micron. The resulting fine particles size fraction is then treated by conventional series of steps, i.e., optional bleaching, drying, pulverization, calcination and repulverization to produce a low abrasion, ultrahigh brightness (typically 96%) calcined kaolin pigment.
    • 选择的高岭土原油或粗馏分通过物理或物理/化学方法如泡沫浮选和/或选择性絮凝来纯化,以去除离散的TiO 2颗粒,并且在一些情况下,分散的铁矿物质。 然后必须在水的存在下用颗粒研磨介质例如砂,氧化铝或氧化锆珠搅拌纯(或纯化的粘土),以增加高岭土的2微米含量。 作为研磨的结果产生了含有大于1微米的颗粒的重量百分数的中间磨碎产物。 研磨高岭土中微粒比1微米的颗粒还包括存在于天然粘土中的先前纯化或纯化的高岭土中的那些颗粒。 然后将研磨粘土的纸浆分馏以除去大于2微米的颗粒,例如,除去大于2微米的颗粒的至少95%,优选100重量%,同时最小化除去比1更细的颗粒 微米。 然后通过常规的一系列步骤,即任选的漂白,干燥,粉碎,煅烧和再造浆处理所得到的细粒度级分,以产生低磨损,超高亮度(通常为96%)的煅烧高岭土颜料。