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1. 发明授权

US08313824B2 Decorative multilayer material impregnated with resin 有权
标题翻译：用树脂浸渍的装饰多层材料
公开(公告)号：US08313824B2
公开(公告)日：2012-11-20
申请号：US10581953
申请日：2004-12-17
申请人： Eiichiro Yokochi , Kenichi Tachihara
发明人： Eiichiro Yokochi , Kenichi Tachihara
IPC分类号： B41M5/00
CPC分类号： B44C5/0476 , B32B27/08 , B32B27/10 , B32B29/005 , B32B2260/028 , B32B2260/046 , B32B2307/554 , B32B2307/7265 , B32B2307/734 , B32B2451/00 , Y10T156/1002 , Y10T428/24479 , Y10T428/24802 , Y10T428/2481 , Y10T428/24818 , Y10T428/24876 , Y10T428/31551 , Y10T428/31663
摘要： A decorative material capable of achieving both surface endurance such as abrasion resistance, and internal endurance such as subsidence resistance, water resistance and oil resistance. The decorative material is produced by laminating an ionizing radiation curing resin coating paper onto a thermosetting resin impregnated paper, and heat pressing for the integration. A surface layer and a base material layer are laminated and integrated on the rear surface thereof. The surface layer has at least a surface resin layer made of a cured material of an ionizing radiation curing resin, a blocking layer for blocking the ooze out of the uncured material of the thermosetting resin, and an impregnated paper layer formed by a paper impregnated with a thermosetting resin and cured, laminated from the surface side. At least the uppermost surface of the base material layer has an impregnated paper layer formed by a paper impregnated with a thermosetting resin and cured.
摘要翻译：能够实现表面耐久性，例如耐磨性和内部耐久性如耐下降性，耐水性和耐油性的装饰材料。装饰材料通过将电离辐射固化树脂涂布纸层压到热固性树脂浸渍纸上并进行热压以一体化而制成。表面层和基材层在其后表面上层叠并整合。表面层至少具有由电离辐射固化树脂的固化材料制成的表面树脂层，用于阻断热固性树脂的未固化材料的渗出物的阻挡层和由浸渍了热固性树脂，并从表面侧层压。至少基材层的最上表面具有由浸渍有热固性树脂的纸形成的浸渍纸层并固化。

2. 发明授权

US07968174B2 Decorative material having low-gloss pattern ink layer formed on part of a substrate and a surface protective layer on the pattern in K layer, and decorative plate including such material 有权
标题翻译：在K层的图案的一部分上形成有低光图案油墨层和表面保护层的装饰材料，以及包含这种材料的装饰板
公开(公告)号：US07968174B2
公开(公告)日：2011-06-28
申请号：US11576155
申请日：2005-09-29
申请人： Toshitake Kobayashi , Eiichiro Yokochi
发明人： Toshitake Kobayashi , Eiichiro Yokochi
IPC分类号： B41M5/00
CPC分类号： B32B27/08 , B32B3/30 , B32B27/18 , B32B27/308 , B32B27/40 , B32B29/00 , B32B33/00 , B32B38/145 , B32B2307/4023 , B32B2307/406 , B32B2307/554 , B32B2375/00 , B32B2451/00 , B44C1/16 , B44F7/00 , Y10T156/1002 , Y10T428/24479 , Y10T428/24521 , Y10T428/24802 , Y10T428/2481 , Y10T428/24818 , Y10T428/31551
摘要： A decorative material having a pattern on a surface thereof and exhibiting a difference in gloss according to the pattern which is visually recognized as a concave portion, the decorative material further exhibiting not only a good surface strength such as abrasion resistance but also good marring resistance and oil resistance. The decorative material includes at least a substrate, a low-gloss pattern ink layer formed on part of the substrate, and a surface protective layer which is present on and contacted with the low-gloss pattern ink layer so as to cover a whole surface including both a region where the low-gloss pattern ink layer is formed and a region where no low-gloss pattern ink layer is formed.
摘要翻译：具有在其表面上具有图案并且根据视觉上被认为是凹形部分的图案呈现光泽差异的装饰材料，该装饰材料不仅表现出良好的表面强度如耐磨性，而且还具有良好的防结锈性，耐油性。所述装饰材料至少包括基板，形成在所述基板的一部分上的低光泽图案油墨层和存在于所述低光泽图案油墨层上并与所述低光泽图案油墨层接触的表面保护层，从而覆盖包括形成低光泽图案油墨层的区域和不形成低光泽图案油墨层的区域。

3. 发明授权

US07931954B2 Decorating material 有权
标题翻译：装饰材料
公开(公告)号：US07931954B2
公开(公告)日：2011-04-26
申请号：US10574173
申请日：2004-09-30
申请人： Toshitake Kobayashi , Kazuhiro Abe , Kenichi Tachihara , Eiichiro Yokochi
发明人： Toshitake Kobayashi , Kazuhiro Abe , Kenichi Tachihara , Eiichiro Yokochi
IPC分类号： B41M5/00
CPC分类号： B44F1/02 , B41M7/0045 , B44C5/04 , B44F9/02 , C09D11/102 , Y10T156/1002 , Y10T428/24479 , Y10T428/24612 , Y10T428/24802 , Y10T428/2481 , Y10T428/24818 , Y10T428/31551
摘要： There is provided a decorative material comprising at least a substrate, a low-luster pattern ink layer partially formed on the substrate, and a surface protective layer which is present on and contacted with the low-luster pattern ink layer so as to cover a whole surface including both a region where the low-luster pattern ink layer is formed and a region where no low-luster pattern ink layer is formed, wherein the surface protective layer is formed by crosslinking and curing an ionizing radiation-curable resin composition, and provided therein with a low-gloss region which is located in a portion just above the low-luster pattern ink layer and in the vicinity of the portion and visually recognized as a concave portion. The decorative material is provided on a surface thereof with a pattern, and exhibits a difference in gloss according to the pattern which is visually recognized as a concave portion, thereby imparting a good convexo-concave feeling to a surface thereof.
摘要翻译：提供一种装饰材料，其至少包括基板，部分地形成在基板上的低光泽图案油墨层和存在于低光泽图案油墨层上并与低光泽图案油墨层接触的表面保护层，以覆盖整个其中表面保护层是通过电离辐射固化树脂组合物的交联和固化而形成的，并且提供了形成低光泽图案油墨层的区域和形成低光泽图案油墨层的区域其中具有低光泽区域，其位于刚好在低光泽图案油墨层上方的部分中并且在该部分附近并且被视觉识别为凹部。装饰材料在其表面上设置有图案，并且根据视觉上被认为是凹部的图案呈现出光泽差异，从而赋予其表面良好的凹凸感。

4. 发明申请

US20050129970A1 Decorative sheet 有权
标题翻译：装饰板
公开(公告)号：US20050129970A1
公开(公告)日：2005-06-16
申请号：US10508023
申请日：2003-03-19
申请人： Eiichiro Yokochi
发明人： Eiichiro Yokochi
IPC分类号： B32B29/00 , B44C5/04 , B32B9/04 , A47G35/00
CPC分类号： B44C5/0476 , B32B29/00 , Y10T428/31511 , Y10T428/31786 , Y10T428/31855 , Y10T428/31895 , Y10T428/31909 , Y10T428/31938 , Y10T428/31993
摘要： The present invention improves a surface protective layer in the resistance to marring to the extent not achieved even if the surface protective layer is made of a crosslinked cured product of an ionizing radiation-curable resin and added with silica. When forming a layer comprising the crosslinked cured product of the ionizing radiation-curable resin as a surface protective layer (2) on a substrate sheet (1) made of paper or the like, fired kaolin is contained as a filler in the surface protective layer. The fired kaolin is preferably surface-treated with a silane coupling agent. On the substrate sheet (1), a wholly solid layer (3) and a pattern layer (4) are generally provided. A primer layer may be optionally provided between the substrate sheet and the surface protective layer.
摘要翻译：即使表面保护层由电离辐射固化树脂的交联固化物制成并加入二氧化硅，本发明改善了抗损伤性的表面保护层。当在由纸等制成的基片（1）上形成包含电离辐射固化树脂的交联固化物作为表面保护层（2）的层时，在表面保护层中含有烧成的高岭土作为填料。烧成的高岭土优选用硅烷偶联剂进行表面处理。在基片（1）上，通常设置完整的固体层（3）和图形层（4）。底漆层可以任选地设置在基片和表面保护层之间。

5. 发明申请

US20090220800A1 HIGH-GLOSS DECORATIVE SHEET 有权
标题翻译：高档装饰片
公开(公告)号：US20090220800A1
公开(公告)日：2009-09-03
申请号：US11817417
申请日：2006-02-28
申请人： Eiichiro Yokochi
发明人： Eiichiro Yokochi
IPC分类号： B32B27/30 , C08F130/08
CPC分类号： B44C1/165 , C08F222/1006 , C08F230/08 , C09D4/00 , Y10T428/24802 , Y10T428/24868 , Y10T428/24876 , Y10T428/31551 , Y10T428/31663 , Y10T428/31938
摘要： This invention provides a decorative sheet having a high glossy impression, comprising a surface protective layer formed of an ionizing radiation curing resin, which is excellent in surface specularity and marker ink erasing capability and has suppressed slipperiness as a decorative sheet, and a decorative plate comprising the sheet and a substrate jointed to each other. In the decorative sheet, a silicone having a high lifting effect (the effect of lifting on the surface) and a silicone having high compatibility with the ionizing radiation curing resin are incorporated, either separately from each other or simultaneously, into an ionizing radiation curing resin for forming the surface protective layer. According to this constitution, properties, which are generally likely to be offset by each other, that is, excellent contamination resistance, marker ink erasing capability, and cellophane tape resistance, high leveling properties, surface smoothness, and transparency, and suppressed slipperiness, can be maintained on a high level.
摘要翻译：本发明提供一种具有高光泽印象的装饰片，其特征在于，包括由离子化辐射固化树脂形成的表面保护层，其具有优异的表面镜面反应性和标记墨水擦除能力，并且抑制了作为装饰片材的滑爽性，以及装饰板，片材和彼此接合的基底。在装饰片中，将与电离辐射固化树脂具有高相容性的高提升效果（提升表面的效果）的硅树脂和与电离辐射固化树脂具有高相容性的硅氧烷彼此分开或同时地并入电离辐射固化树脂用于形成表面保护层。根据这种结构，通常可能彼此抵消的性质，即优异的耐污染性，标记油墨擦除能力和玻璃纸胶带耐性，高流平性，表面平滑性和透明性以及抑制滑爽性。保持在高水平。

6. 发明申请

US20070116933A1 Decorating material 有权
标题翻译：装饰材料
公开(公告)号：US20070116933A1
公开(公告)日：2007-05-24
申请号：US10574173
申请日：2004-09-30
申请人： Toshitake Kobayashi , Kazuhiro Abe , Kenichi Tachihara , Eiichiro Yokochi
发明人： Toshitake Kobayashi , Kazuhiro Abe , Kenichi Tachihara , Eiichiro Yokochi
IPC分类号： B32B3/00
CPC分类号： B44F1/02 , B41M7/0045 , B44C5/04 , B44F9/02 , C09D11/102 , Y10T156/1002 , Y10T428/24479 , Y10T428/24612 , Y10T428/24802 , Y10T428/2481 , Y10T428/24818 , Y10T428/31551
摘要： There is provided a decorative material comprising at least a substrate, a low-luster pattern ink layer partially formed on the substrate, and a surface protective layer which is present on and contacted with the low-luster pattern ink layer so as to cover a whole surface including both a region where the low-luster pattern ink layer is formed and a region where no low-luster pattern ink layer is formed, wherein the surface protective layer is formed by crosslinking and curing an ionizing radiation-curable resin composition, and provided therein with a low-gloss region which is located in a portion just above the low-luster pattern ink layer and in the vicinity of the portion and visually recognized as a concave portion. The decorative material is provided on a surface thereof with a pattern, and exhibits a difference in gloss according to the pattern which is visually recognized as a concave portion, thereby imparting a good convexo-concave feeling to a surface thereof.
摘要翻译：提供一种装饰材料，其至少包括基板，部分地形成在基板上的低光泽图案油墨层和存在于低光泽图案油墨层上并与低光泽图案油墨层接触的表面保护层，以覆盖整个其中表面保护层是通过电离辐射固化树脂组合物的交联和固化而形成的，并且提供了形成低光泽图案油墨层的区域和形成低光泽图案油墨层的区域其中具有低光泽区域，其位于刚好在低光泽图案油墨层上方的部分中并且在该部分附近并且被视觉识别为凹部。装饰材料在其表面上设置有图案，并且根据视觉上被认为是凹部的图案呈现出光泽差异，从而赋予其表面良好的凹凸感。

7. 发明授权

US08053061B2 High-gloss decorative sheet 有权
标题翻译：高光泽装饰板
公开(公告)号：US08053061B2
公开(公告)日：2011-11-08
申请号：US11817417
申请日：2006-02-28
申请人： Eiichiro Yokochi
发明人： Eiichiro Yokochi
IPC分类号： B32B3/00
CPC分类号： B44C1/165 , C08F222/1006 , C08F230/08 , C09D4/00 , Y10T428/24802 , Y10T428/24868 , Y10T428/24876 , Y10T428/31551 , Y10T428/31663 , Y10T428/31938
摘要： This invention provides a decorative sheet having a high glossy impression, comprising a surface protective layer formed of an ionizing radiation curing resin, which is excellent in surface specularity and marker ink erasing capability and has suppressed slipperiness as a decorative sheet, and a decorative plate comprising the sheet and a substrate jointed to each other. In the decorative sheet, a silicone having a high lifting effect (the effect of lifting on the surface) and a silicone having high compatibility with the ionizing radiation curing resin are incorporated, either separately from each other or simultaneously, into an ionizing radiation curing resin for forming the surface protective layer. According to this constitution, properties, which are generally likely to be offset by each other, that is, excellent contamination resistance, marker ink erasing capability, and cellophane tape resistance, high leveling properties, surface smoothness, and transparency, and suppressed slipperiness, can be maintained on a high level.
摘要翻译：本发明提供一种具有高光泽印象的装饰片，其特征在于，包括由离子化辐射固化树脂形成的表面保护层，其具有优异的表面镜面反应性和标记墨水擦除能力，并且抑制了作为装饰片材的滑爽性，以及装饰板，片材和彼此接合的基底。在装饰片中，将与电离辐射固化树脂具有高相容性的高提升效果（提升表面的效果）的硅树脂和与电离辐射固化树脂具有高相容性的硅氧烷彼此分开或同时并入电离辐射固化树脂用于形成表面保护层。根据这种结构，通常可能彼此抵消的性质，即优异的耐污染性，标记油墨擦除能力和玻璃纸胶带耐性，高流平性，表面平滑性和透明性以及抑制滑爽性。保持在高水平。

8. 发明授权

US07674527B2 Coated paper 有权
标题翻译：铜版纸
公开(公告)号：US07674527B2
公开(公告)日：2010-03-09
申请号：US10571431
申请日：2004-09-21
申请人： Eiichiro Yokochi
发明人： Eiichiro Yokochi
IPC分类号： B32B9/06
CPC分类号： D21H19/82 , D21H19/40 , D21H19/62 , Y10T428/31504 , Y10T428/31551 , Y10T428/31573 , Y10T428/31975 , Y10T428/31993
摘要： A coated paper having the oil resistance and the marring resistance which cannot be obtained by the addition of the silica particles is provided. The coated paper 10 has a configuration with at least a surface protection layer 2 of a cross-linking cured material of an ionizing radiation curing resin laminated on a fiber substrate 1, wherein the ionizing radiation curing resin of the surface protection layer contains an ethylene oxide modified polymerizable compound, and preferably, the surface protection layer contains baked kaolin particle. By increasing the hydrophilic property with the ethylene oxide modified polymerizable compound, the oil resistance is provided for the surface protection layer itself, and with the baked kaolin particle, the marring resistance can be provided. Moreover, it is preferable to laminate successively a solid colored layer 3A and a primer layer 4 before laminating the surface protection layer on the fiber substrate in terms of the adhesion property and the design property. Moreover, it is preferable to form these layers as a cured material of an urethane resin resulting from a reaction of an acrylic polyol and an isocyanate in terms of the adhesion property and the oil resistance.
摘要翻译：提供了通过添加二氧化硅颗粒而不能获得的具有耐油性和耐污损性的涂布纸。涂布纸10具有至少层叠在纤维基材1上的电离辐射固化树脂的交联固化物的表面保护层2的结构，其中表面保护层的电离辐射固化树脂含有环氧乙烷改性的可聚合化合物，并且优选地，表面保护层含有焙烧高岭土颗粒。通过用环氧乙烷改性的可聚合化合物增加亲水性，为表面保护层本身提供了耐油性，并且对于焙烧高岭土颗粒，可以提供耐磨损性。此外，就粘合性和设计性而言，在将表面保护层层压在纤维基材上之前，优选依次层压固色层3A和底漆层4。此外，从粘合性和耐油性的角度出发，优选将这些层形成为由丙烯酸多元醇与异氰酸酯反应得到的聚氨酯树脂的固化物。

9. 发明授权

US07291400B2 Decorative sheet 有权
标题翻译：装饰板
公开(公告)号：US07291400B2
公开(公告)日：2007-11-06
申请号：US10508023
申请日：2003-03-19
申请人： Eiichiro Yokochi
发明人： Eiichiro Yokochi
IPC分类号： B32B29/04
CPC分类号： B44C5/0476 , B32B29/00 , Y10T428/31511 , Y10T428/31786 , Y10T428/31855 , Y10T428/31895 , Y10T428/31909 , Y10T428/31938 , Y10T428/31993
摘要： The present invention improves a surface protective layer in the resistance to marring to the extent not achieved even if the surface protective layer is made of a crosslinked cured product of an ionizing radiation-curable resin and added with silica. When forming a layer comprising the crosslinked cured product of the ionizing radiation-curable resin as a surface protective layer (2) on a substrate sheet (1) made of paper or the like, fired kaolin is contained as a filler in the surface protective layer. The fired kaolin is preferably surface-treated with a silane coupling agent. On the substrate sheet (1), a wholly solid layer (3) and a pattern layer (4) are generally provided. A primer layer may be optionally provided between the substrate sheet and the surface protective layer.
摘要翻译：即使表面保护层由电离辐射固化树脂的交联固化物制成并加入二氧化硅，本发明改善了抗损伤性的表面保护层。当在由纸等制成的基片（1）上形成包含电离辐射固化树脂的交联固化物作为表面保护层（2）的层时，在表面保护层中含有烧成的高岭土作为填料。烧成的高岭土优选用硅烷偶联剂进行表面处理。在基片（1）上，通常设置完整的固体层（3）和图形层（4）。底漆层可以任选地设置在基片和表面保护层之间。

10. 发明申请

US20070054145A1 Coated paper 有权
标题翻译：铜版纸
公开(公告)号：US20070054145A1
公开(公告)日：2007-03-08
申请号：US10571431
申请日：2004-09-21
申请人： Eiichiro Yokochi
发明人： Eiichiro Yokochi
IPC分类号： B32B29/00
CPC分类号： D21H19/82 , D21H19/40 , D21H19/62 , Y10T428/31504 , Y10T428/31551 , Y10T428/31573 , Y10T428/31975 , Y10T428/31993
摘要： A coated paper having not only oil resistance but marring resistance, which has not been attained even by the addition of silica particles. The coated paper (10) has a structure comprising a fibrous base (1) and superposed thereover at least a surface-protective layer (2) made of a resin obtained by crosslinking and curing a resin curable with an ionizing radiation, wherein the resin curable with an ionizing radiation contains an ethylene oxide-modified polymerizable compound. Preferably, the surface-protective layer contains burned kaolin particles. The ethylene oxide-modified polymerizable compound enhances hydrophilicity and imparts oil resistance to the surface-protective layer itself. The burned kaolin particles impart marring resistance. It is preferable to successively superpose a solid colored layer (3A) and a primer layer (4) before the superposition of the surface-protective layer over the fibrous base from the standpoints of adhesion and appearance. These layers preferably are constituted of a cured urethane resin obtained from an acrylic polyol and an isocyanate from the standpoints of adhesion and oil resistance.
摘要翻译：不仅具有耐油性，而且抗结块性的涂布纸，即使加入二氧化硅颗粒也未获得。涂布纸（10）具有包括纤维基材（1）的结构，并且至少包含由通过交联和固化用电离辐射固化的树脂而获得的树脂制成的表面保护层（2），其中树脂可固化电离辐射含有环氧乙烷改性的可聚合化合物。优选地，表面保护层含有烧成的高岭土颗粒。环氧乙烷改性的可聚合化合物增强亲水性，并赋予表面保护层本身耐油性。烧成的高岭土颗粒赋予耐腐蚀性。从附着力和外观的观点出发，优选在将表面保护层叠置在纤维基材上之前，依次层叠固色层（3A）和底漆层（4）。从粘合性和耐油性的观点出发，优选由丙烯酸多元醇和异氰酸酯得到的固化的聚氨酯树脂构成。

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