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    • 7. 发明授权
    • Recovery of hard acids and soft bases from decomposed coal
    • 从分解的煤中回收硬质酸和软碱
    • US5489376A
    • 1996-02-06
    • US289722
    • 1994-08-12
    • George M. KramerEdwin R. ErnstAndres M. Fraga
    • George M. KramerEdwin R. ErnstAndres M. Fraga
    • C10G1/00C10G1/04C10G1/08C10G1/06
    • C10G1/006C10G1/00C10G1/04C10G1/086
    • An improved process for recovering hard acids and soft bases used to decompose coal in which finely divided coal particles are contacted with a hard acid in the presence of a soft base at temperatures of from 0.degree. to 100.degree. C., said hard acid being characterized by a heat of reaction with dimethylsulfide of from 10 kcal/mol to 30 kcal/mol and said soft base being characterized by a heat of reaction with boron trifluoride of from 10 kcal/mol to 17 kcal/mol, followed by extracting the decomposed coal to remove said hard acid and soft base wherein the improvement comprises performing said extraction at a temperature of about 0.degree. to about 50.degree. C. using dimethylsulfide as the extraction solvent, and wherein following said dimethylcarbonate extraction, said decomposed coal is extracted with water at a temperature of from about 60.degree. to 275.degree. C.
    • 一种用于回收硬化酸和软碱的改进方法,其用于分解煤,其中细软的煤颗粒在软碱存在下在硬度为0至100℃的温度下与硬酸接触,所述硬酸被表征 通过与二甲硫醚反应的热量为10kcal / mol至30kcal / mol,所述软碱的特征在于与三氯化硼的反应热为10kcal / mol至17kcal / mol,随后提取分解的煤 去除所述硬酸和软碱,其中改进包括使用二甲基硫醚作为萃取溶剂在约0℃至约50℃的温度下进行所述萃取,并且其中在所述二甲基碳酸酯萃取之后,将所述分解的煤用水萃取 温度为约60℃至275℃