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1. 发明授权

US5236776A Thermoplastic thermoformable composite material and method of forming such material 失效
标题翻译：热塑性热成型复合材料及其形成方法
公开(公告)号：US5236776A
公开(公告)日：1993-08-17
申请号：US651957
申请日：1991-02-07
申请人： Douglas R. Fitchmun , Stuart E. Jenkins
发明人： Douglas R. Fitchmun , Stuart E. Jenkins
IPC分类号： B29C51/08 , B29C51/14 , B29C70/08 , B32B27/12 , B32B38/08
CPC分类号： B32B38/08 , B29C51/145 , B29C70/086 , B32B27/12 , B29C51/082 , Y10T442/3594 , Y10T442/3854
摘要： A thermoplastic thermoformable resin material defines a core of a thermoformable thermoplastic composite material. First and second layers of fabric material are disposed against opposite sides of the core. An additional layer of a fabric material is positioned on the first fabric layer to impart a particular color to the composite material. A resin envelopes and impregnates the different fabric layers and bonds these layers to the core. The fabric layers have a total thickness sufficient to impart strength and rigidity to the fabric material. The core is sufficiently thick to provide for a shaping of the composite material at an elevated temperature to any desired configuration without any rippling or buckling of the composite material. Additional layers of a thermoplastic thermoformable resin material may be disposed on the outer layers of the fabric material. They impregnate the fabric layers, provide a continuity with the core and provide a smooth external surface to the composite material. The core and the additional resin layers may be an acrylic. The two fabric layers may be made from carbon and may be woven or formed from discrete particles. The additional fabric layer may be woven from a warp and a woof. The warp may be made from a high strength fiber and the woof may be formed from a colored fiber. Another embodiment of the composite material may be formed from the core, one additional layer of the fabric material and the colored fabric. The invention also relates to methods of forming the composite material.
摘要翻译：热塑性热成型树脂材料限定了可热成形的热塑性复合材料的芯。第一和第二层织物材料被布置成抵靠芯的相对侧。将另外的织物材料层定位在第一织物层上以赋予复合材料特定的颜色。树脂包裹并浸渍不同的织物层并将这些层粘合到芯上。织物层具有足以赋予织物材料强度和刚度的总厚度。芯足够厚以提供将复合材料在升高的温度下成形为任何所需构型，而不会使复合材料发生波纹或弯曲。热塑性可热成型树脂材料的另外的层可以设置在织物材料的外层上。它们浸渍织物层，提供与芯的连续性并为复合材料提供光滑的外表面。芯和附加树脂层可以是丙烯酸。两个织物层可以由碳制成并且可以由离散的颗粒编织或形成。附加织物层可以由经纱和纬纱编织。经线可以由高强度纤维制成，并且纬纱可以由有色纤维形成。复合材料的另一个实施例可以由芯，织物材料的一个附加层和着色织物形成。本发明还涉及形成复合材料的方法。

2. 发明授权

US5538757A Method of making thermoplastic composite material 失效
标题翻译：制造热塑性复合材料的方法
公开(公告)号：US5538757A
公开(公告)日：1996-07-23
申请号：US361749
申请日：1994-12-22
申请人： Douglas R. Fitchmun , Niran Perera , Thomas W. Smith
发明人： Douglas R. Fitchmun , Niran Perera , Thomas W. Smith
IPC分类号： B32B27/12 , B05D1/00
CPC分类号： B32B27/12 , B32B37/0007 , B32B2305/18 , B32B2309/10
摘要： A thermoplastic composite material may be formed by supplying the thermoplastic material to the opposite surfaces of the fabric material and by then passing the resultant material through the spaces between progressive pairs of rollers. The rollers in each progressive pair have a decreased spacing relative to the rollers in the previous pair so as to squeeze the thermoplastic material into the interstices between the fabric threads without compressing the fabric material. The resultant material may also be moved in a tortuous path, such as formed by a pair of rollers defining an S-configuration relative to the resultant material, to engage the opposite surfaces of the resultant material and squeeze air from the resultant material without compressing the fabric.
摘要翻译：热塑性复合材料可以通过将热塑性材料供应到织物材料的相对表面，然后使得到的材料通过渐进的辊对之间的空间来形成。每个渐进对中的辊相对于前一对中的辊具有减小的间隔，以便将热塑性材料挤压到织物线之间的间隙中而不压缩织物材料。所得到的材料也可以在曲折的路径中移动，例如由相对于所得材料限定S形结构的一对辊形成，以使所得材料的相对表面接合并从所得材料挤压空气，而不压缩布。

3. 发明授权

US5390430A Shoe sole constructed of composite thermoplastic material including a compliant layer 失效
标题翻译：鞋底由复合热塑性材料构成，包括柔顺层
公开(公告)号：US5390430A
公开(公告)日：1995-02-21
申请号：US267185
申请日：1994-06-28
申请人： Douglas R. Fitchmun , Niran Perera
发明人： Douglas R. Fitchmun , Niran Perera
IPC分类号： B32B27/12 , A43B13/18 , A43B13/12
CPC分类号： B32B27/12 , Y10T428/2495 , Y10T442/365 , Y10T442/67 , Y10T442/671
摘要： A thermoformable thermoplastic composite material has a core sufficiently thick to provide for a shaping of the composite material at an elevated temperature to any desired configuration. Layers of a fabric material disposed on opposite sides of the core may be formed of glass, carbon or aramid and from woven fibers, unidirectional or chopped fibers or random strand mats. The fabric layers are sufficiently thick to impart strength and rigidity to the composite material. Layers of a thermoplastic thermoformable resin material may be disposed on the fabric layers. The thermoplastic layers impregnate the fabric layers, bond the fabric layers to the core and provide a smooth external surface to the composite material. The core is preferably thinner than the combined thicknesses of the fabric layers and the thermoplastic layers. For example, the thickness of each fabric layer may be 0.008"-0.009", of each thermoplastic layer may be 0.0005"-0.002" and of the thermoplastic composite material may be 0.035"-0.060". A thermoplastic layer of an elastomer such as urethane is bonded to one of the thermoplastic layers with a thickness of approximately 0.010"-0.020" to impart abrasion resistance and high impact strength to the thermoplastic composite material. The composite material may illustratively be disposed externally in the sole of a shoe with the elastomer facing outwardly.
摘要翻译：可热成形的热塑性复合材料具有足够厚的芯以提供将复合材料在升高的温度下成形为任何所需的构型。设置在芯的相对侧上的织物材料的层可以由玻璃，碳或芳族聚酰胺和织造纤维，单向或短切的纤维或随机链条垫片形成。织物层足够厚以赋予复合材料强度和刚性。热塑性可热成型树脂材料的层可以设置在织物层上。热塑性层浸渍织物层，将织物层粘合到芯上，并为复合材料提供光滑的外表面。芯优选比织物层和热塑性层的组合厚度薄。例如，每个织物层的厚度可以为0.008“至0.009”，每个热塑性层的厚度可以为0.0005“-2.002”，热塑性复合材料的厚度可以为0.035“至0.060”。诸如氨基甲酸乙酯的弹性体的热塑性层被结合到热塑性层之一，其厚度约为0.010“至0.020”，以赋予热塑性复合材料耐磨性和高冲击强度。复合材料可以示例性地布置在鞋的鞋底中，弹性体面向外。

4. 发明授权

US4778717A Thermoplastic thermoformable composite material 失效
标题翻译：热塑性热成型复合材料
公开(公告)号：US4778717A
公开(公告)日：1988-10-18
申请号：US886543
申请日：1986-07-16
申请人： Douglas R. Fitchmun
发明人： Douglas R. Fitchmun
IPC分类号： A43B17/00 , B32B27/12 , B32B7/00
CPC分类号： A43B17/003 , B32B27/12 , Y10T442/365
摘要： A thermoplastic composite having a plurality of layers of material each having a particular total thickness and a particular total volume, including a first layer of thermoplastic resin materal forming a core. At least two layers of fabric material each disposed on an opposite side of the first layer and impregnated with the core material to define an outer skin on the core. Two layers of thermoplastic resin material each overlaying one of the at least two layers of fabric and each bonded to the thermoplastic material impregnated in the adjacent layer of fabric material to define an outer covering for protecting the layers of fabric and providing a covering for protecting the layers of fabric and providing a smooth exterior. The thickness of the core forming a substantial percentage of the total thickness of the composite and the fiber volume of the at least two layers of fabric material forming less than one third (1/3) of the total volume of the composite.
摘要翻译：一种热塑性复合材料，其具有多层材料，每层具有特定的总厚度和特定的总体积，包括形成芯的第一层热塑性树脂。至少两层织物材料各自设置在第一层的相对侧上，并浸渍有芯材料以在芯上限定外皮。两层热塑性树脂材料，各自覆盖至少两层织物中的一层，并且每层结合到浸渍在相邻层织物材料中的热塑性材料，以限定用于保护织物层的外覆层，并提供用于保护织物的覆盖物织物层，提供光滑的外观。芯的厚度形成复合材料的总厚度的相当大的百分比，并且至少两层织物材料的纤维体积小于复合材料总体积的三分之一（1/3）。

5. 发明授权

US5741744A Thermoplastic thermoformable composite material and method of forming such material 失效
标题翻译：热塑性热成型复合材料及其形成方法
公开(公告)号：US5741744A
公开(公告)日：1998-04-21
申请号：US749989
申请日：1996-11-15
申请人： Douglas R. Fitchmun
发明人： Douglas R. Fitchmun
IPC分类号： B29C70/08 , B29C70/50 , B32B5/28 , B32B27/04 , B32B5/18
CPC分类号： B29C70/502 , B29C70/086 , B32B27/04 , B32B5/28 , B29K2101/12 , B29K2105/0854 , Y10T428/2495 , Y10T442/126 , Y10T442/176 , Y10T442/2369 , Y10T442/2377 , Y10T442/2861 , Y10T442/3472 , Y10T442/3602 , Y10T442/659 , Y10T442/674
摘要： A thermoplastic thermoformable composite material for shaping and stretching into a desired form without voids and holes, including a core formed by at least one layer of chopped fibers enveloped and impregnated by thermoplastic material to form a fabric layer. Layers of thermoplastic material respectively positioned on opposite sides of the fabric layer core, and the layers of thermoplastic material provided with a sufficient thickness to flow into and heal any voids or holes formed in the core as the composite material is shaped and stretched into a desired form.
摘要翻译：一种热塑性可热成型复合材料，用于成形和拉伸成所需形状而没有空隙和孔，包括由至少一层短切纤维形成的芯，该芯由热塑性材料包裹并浸渍以形成织物层。分别位于织物层芯的相对侧上的热塑性材料层，以及具有足够厚度的热塑性材料层，以便当复合材料成型并拉伸成所需的时，流入并愈合在芯中形成的任何空隙或孔形成。

6. 发明授权

US5354604A Thermoplastic thermoformable composite material and method of forming such material 失效
标题翻译：热塑性热成型复合材料及其形成方法
公开(公告)号：US5354604A
公开(公告)日：1994-10-11
申请号：US731640
申请日：1991-07-17
申请人： David M. Blakeman , Douglas R. Fitchmun , Niran Perera
发明人： David M. Blakeman , Douglas R. Fitchmun , Niran Perera
IPC分类号： B32B27/12 , B32B5/18 , B32B5/28
CPC分类号： B32B27/12 , Y10T428/2495 , Y10T428/249953 , Y10T428/249992 , Y10T428/26 , Y10T428/269 , Y10T442/3594 , Y10T442/3642 , Y10T442/365 , Y10T442/3854 , Y10T442/387 , Y10T442/3911 , Y10T442/67 , Y10T442/671
摘要： A thermoplastic resin defines a core of a thermoformable thermoplastic composite material. The core is sufficiently thick to provide for a shaping of the composite material at an elevated temperature to any desired configuration. First and second layers of fabric material are disposed on opposite sides of the core. The fabric material may be formed of glass, carbon or aramid and may be formed from woven fibers, unidirectional or chopped fibers or random strand mats. The fabric layers have a thickness sufficient to impart strength and rigidity to the fabric material. Layers of a thermoplastic thermoformable resin material may be disposed on the layers of the fabric material. The thermoplastic layers impregnate the fabric layers, bond the fabric layers to the core and provide a smooth external surface to the composite material. The thermoplastic layers are of a sufficient thickness to maximize the flexural load strength of the composite material and to eliminate the formation of any rippling or buckling of the composite material. The core and the additional resin layers may be an acrylic, a polycarbonate or ABS. The core may be thicker than the combined thicknesses of the fabric layers and the thermoplastic layers. For example, each of the fabric layers may have a thickness in the order of eight mils (0.008" ) to nine mils (0.009" ). The thickness of each of the thermoplastic layers may be in the order of seven mils (0.007" ) to nine mils (0.009" ). The thickness of the thermoplastic composite material may be in the order of eighty five mils (0.085" ) to one hundred and twenty five mils (0.125" ).
摘要翻译：热塑性树脂限定可热成形的热塑性复合材料的芯。芯足够厚以提供复合材料在升高的温度下成形为任何所需的构型。第一和第二层织物材料设置在芯的相对侧上。织物材料可以由玻璃，碳或芳族聚酰胺形成，并且可由编织纤维，单向或短切纤维或随机链条垫形成。织物层具有足以赋予织物材料强度和刚性的厚度。热塑性可热成型树脂材料的层可以设置在织物材料的层上。热塑性层浸渍织物层，将织物层粘合到芯上，并为复合材料提供光滑的外表面。热塑性层具有足够的厚度以最大化复合材料的弯曲载荷强度并消除复合材料的任何起皱或翘曲的形成。芯和附加树脂层可以是丙烯酸，聚碳酸酯或ABS。芯可以比织物层和热塑性层的组合厚度厚。例如，每个织物层可以具有8密耳（0.008“）至9密耳（0.009”）的量级。每个热塑性层的厚度可以为7密耳（0.007“）至9密耳（0.009”）的数量级。热塑性复合材料的厚度可以是八十五密耳（0.085“）到十二点二五密耳（0.125”）的数量级。

7. 发明授权

US5604020A Thermoplastic thermoformable composite material and method of forming such material 失效
标题翻译：热塑性热成型复合材料及其形成方法
公开(公告)号：US5604020A
公开(公告)日：1997-02-18
申请号：US390533
申请日：1995-02-16
申请人： Douglas R. Fitchmun
发明人： Douglas R. Fitchmun
IPC分类号： B29C70/08 , B29C70/50 , B32B5/28 , B32B27/04 , B32B5/18
CPC分类号： B29C70/502 , B29C70/086 , B32B27/04 , B32B5/28 , B29K2101/12 , B29K2105/0854 , Y10T428/2495 , Y10T442/126 , Y10T442/176 , Y10T442/2369 , Y10T442/2377 , Y10T442/2861 , Y10T442/3472 , Y10T442/3602 , Y10T442/659 , Y10T442/674
摘要： A thermoplastic thermoformable composite material for shaping and stretching into a desired form without voids and holes, including a core formed by at least one layer of chopped fibers enveloped and impregnated by thermoplastic material to form a fabric layer. Layers of thermoplastic material respectively positioned on opposite sides of the fabric layer core, and the layers of thermoplastic material provided with a sufficient thickness to flow into and heal any voids or holes formed in the core as the composite material is shaped and stretched into a desired form.
摘要翻译：一种热塑性可热成型复合材料，用于成形和拉伸成所需形状而没有空隙和孔，包括由至少一层短切纤维形成的芯，该芯由热塑性材料包裹并浸渍以形成织物层。分别位于织物层芯的相对侧上的热塑性材料层，以及具有足够厚度的热塑性材料层，以便当复合材料成型并拉伸成所需的时，流入并愈合在芯中形成的任何空隙或孔形成。

8. 发明授权

US5571607A Thermoplastic thermoformable composite material and method of forming such material 失效
标题翻译：热塑性热成型复合材料及其形成方法
公开(公告)号：US5571607A
公开(公告)日：1996-11-05
申请号：US285062
申请日：1994-08-03
申请人： David M. Blakeman , Douglas R. Fitchmun , Niran Perera
发明人： David M. Blakeman , Douglas R. Fitchmun , Niran Perera
IPC分类号： B32B27/12 , B32B27/04 , B32B7/00
CPC分类号： B32B27/12 , Y10T428/2495 , Y10T428/249953 , Y10T428/249992 , Y10T428/26 , Y10T428/269 , Y10T442/3594 , Y10T442/3642 , Y10T442/365 , Y10T442/3854 , Y10T442/387 , Y10T442/3911 , Y10T442/67 , Y10T442/671
摘要： A thermoplastic resin defines a core of a thermoformable thermoplastic composite material. The core is sufficiently thick to provide for a shaping of the composite material at an elevated temperature to any desired configuration. First and second layers of fabric material are disposed on opposite sides of the core. The fabric material may be formed of glass, carbon or aramid and may be formed from woven fibers, unidirectional or chopped fibers or random strand mats. The fabric layers have a thickness sufficient to impart strength and rigidity to the fabric material. Layers of a thermoplastic thermoformable resin material may be disposed on the layers of the fabric material. The thermoplastic layers impregnate the fabric layers, bond the fabric layers to the core and provide a smooth external surface to the composite material. The thermoplastic layers are of a sufficient thickness to maximize the flexural load strength of the composite material and to eliminate the formation of any rippling or buckling of the composite material. The core and the additional resin layers may be an acrylic, a polycarbonate or ABS. The core may be thicker than the combined thicknesses of the fabric layers and the thermoplastic layers. For example, each of the fabric layers may have a thickness in the order of eight mils (0,008") to nine mils (0,009"). The thickness of each of the thermoplastic layers may be in the order of seven mils (0,007") to nine mils (0.009"). The thickness of the thermoplastic composite material may be in the order of eighty five mils (0.085") to one hundred and twenty five mils (0. 125") .
摘要翻译：热塑性树脂限定可热成形的热塑性复合材料的芯。芯足够厚以提供复合材料在升高的温度下成形为任何所需的构型。第一和第二层织物材料设置在芯的相对侧上。织物材料可以由玻璃，碳或芳族聚酰胺形成，并且可由编织纤维，单向或短切纤维或随机链条垫形成。织物层具有足以赋予织物材料强度和刚性的厚度。热塑性可热成型树脂材料的层可以设置在织物材料的层上。热塑性层浸渍织物层，将织物层粘合到芯上，并为复合材料提供光滑的外表面。热塑性层具有足够的厚度以最大化复合材料的弯曲载荷强度并消除复合材料的任何起皱或翘曲的形成。芯和附加树脂层可以是丙烯酸，聚碳酸酯或ABS。芯可以比织物层和热塑性层的组合厚度厚。例如，每个织物层可具有8密耳（0,008“）至9密耳（009”）的量级。每个热塑性层的厚度可以为7密耳（0.007“）至9密耳（0.009”）的量级。热塑性复合材料的厚度可以为八十五密耳（0.085“）至一百二十五密耳（0.125”）的数量级。

9. 发明授权

US5525412A Thermoplastic thermoformable composite material and method of forming such material 失效
标题翻译：热塑性热成型复合材料及其形成方法
公开(公告)号：US5525412A
公开(公告)日：1996-06-11
申请号：US285061
申请日：1994-08-03
申请人： David M. Blakeman , Douglas R. Fitchmun , Niran Perera
发明人： David M. Blakeman , Douglas R. Fitchmun , Niran Perera
IPC分类号： B32B27/12 , B32B27/04 , B32B7/00
CPC分类号： B32B27/12 , Y10T428/2495 , Y10T428/249953 , Y10T428/249992 , Y10T428/26 , Y10T428/269 , Y10T442/3594 , Y10T442/3642 , Y10T442/365 , Y10T442/3854 , Y10T442/387 , Y10T442/3911 , Y10T442/67 , Y10T442/671
摘要： A thermoplastic resin defines a core of a thermoformable thermoplastic composite material. The core is sufficiently thick to provide for a shaping of the composite material at an elevated temperature to any desired configuration. First and second layers of fabric material are disposed on opposite sides of the core. The fabric material may be formed of glass, carbon or aramid and may be formed from woven fibers, unidirectional or chopped fibers or random strand mats. The fabric layers have a thickness sufficient to impart strength and rigidity to the fabric material. Layers of a thermoplastic thermoformable resin material may be disposed on the layers of the fabric material. The thermoplastic layers impregnate the fabric layers, bond the fabric layers to the core and provide a smooth external surface to the composite material. The thermoplastic layers are of a sufficient thickness to maximize the flexural load strength of the composite material and to eliminate the formation of any rippling or buckling of the composite material. The core and the additional resin layers may be an acrylic, a polycarbonate or ABS. The core may be thicker than the combined thicknesses of the fabric layers and the thermoplastic layers. For example, each of the fabric layers may have a thickness in the order of eight mils (0.008") to nine mils (0.009"). The thickness of each of the thermoplastic layers may be in the order of seven mils (0.007") to nine mils (0.009"). The thickness of the thermoplastic composite material may be in the order of eighty five mils (0.085") to one hundred and twenty five mils (0.125").
摘要翻译：热塑性树脂限定可热成形的热塑性复合材料的芯。芯足够厚以提供复合材料在升高的温度下成形为任何所需的构型。第一和第二层织物材料设置在芯的相对侧上。织物材料可以由玻璃，碳或芳族聚酰胺形成，并且可由编织纤维，单向或短切纤维或随机链条垫形成。织物层具有足以赋予织物材料强度和刚性的厚度。热塑性可热成型树脂材料的层可以设置在织物材料的层上。热塑性层浸渍织物层，将织物层粘合到芯上，并为复合材料提供光滑的外表面。热塑性层具有足够的厚度以最大化复合材料的弯曲载荷强度并消除复合材料的任何起皱或翘曲的形成。芯和附加树脂层可以是丙烯酸，聚碳酸酯或ABS。芯可以比织物层和热塑性层的组合厚度厚。例如，每个织物层可以具有8密耳（0.008“）至9密耳（0.009”）的量级。每个热塑性层的厚度可以为7密耳（0.007“）至9密耳（0.009”）的数量级。热塑性复合材料的厚度可以是八十五密耳（0.085“）到十二点二五密耳（0.125”）的数量级。

10. 发明授权

US5338600A Composite thermoplastic material including a compliant layer 失效
标题翻译：复合热塑性材料包括柔顺层
公开(公告)号：US5338600A
公开(公告)日：1994-08-16
申请号：US746740
申请日：1991-08-19
申请人： Douglas R. Fitchmun , Niran Perera
发明人： Douglas R. Fitchmun , Niran Perera
IPC分类号： B32B27/12 , B32B7/02 , B32B27/00 , D03D3/00
CPC分类号： B32B27/12 , Y10T428/2495 , Y10T442/365 , Y10T442/67 , Y10T442/671
摘要： A thermoformable thermoplastic composite material has a core sufficiently thick to provide for a shaping of the composite material at an elevated temperature to any desired configuration. Layers of a fabric material disposed on opposite sides of the core may be formed of glass, carbon or aramid and from woven fibers, unidirectional or chopped fibers or random strand mats. The fabric layers are sufficiently thick to impart strength and rigidity to the composite material. Layers of a thermoplastic thermoformable resin material may be disposed on the fabric layers. The thermoplastic layers impregnate the fabric layers, bond the fabric layers to the core and provide a smooth external surface to the composite material. The core is preferably thinner than the combined thicknesses of the fabric layers and the thermoplastic layers. For example, the thickness of each fabric layer may be 0.008"-0.009" of each thermoplastic layer may be 0.0005"-0.002" and of the thermoplastic composite material may be 0.035"-0.060". A thermoplastic layer of an elastomer such as urethane is bonded to one of the thermoplastic layers with a thickness of approximately 0.010"-0.020" to impart abrasion resistance and high impact strength to the thermoplastic composite material. The composite material may illustratively be disposed externally in the sole of a shoe with the elastomer facing outwardly.
摘要翻译：可热成形的热塑性复合材料具有足够厚的芯以提供将复合材料在升高的温度下成形为任何所需的构型。设置在芯的相对侧上的织物材料的层可以由玻璃，碳或芳族聚酰胺和织造纤维，单向或短切的纤维或随机链条垫片形成。织物层足够厚以赋予复合材料强度和刚性。热塑性可热成型树脂材料的层可以设置在织物层上。热塑性层浸渍织物层，将织物层粘合到芯上，并为复合材料提供光滑的外表面。芯优选比织物层和热塑性层的组合厚度薄。例如，每个织物层的厚度可以为每个热塑性层的0.008“ - 0.009”，可以为0.0005“ - 0.002”，热塑性复合材料的厚度可以为0.035“-0.060”。诸如氨基甲酸乙酯的弹性体的热塑性层被结合到热塑性层之一，其厚度约为0.010“至0.020”，以赋予热塑性复合材料耐磨性和高冲击强度。复合材料可以示例性地布置在鞋的鞋底中，弹性体面向外。

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