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    • 4. 发明授权
    • Solvent free die-attach compositions
    • 无溶剂的芯片附着组合物
    • US5447988A
    • 1995-09-05
    • US157665
    • 1993-11-23
    • Stephen M. DershemDennis B. PattersonDeborah L. Derfelt
    • Stephen M. DershemDennis B. PattersonDeborah L. Derfelt
    • C08G73/06C08K3/08H01B1/22H01B1/02
    • H01B1/22C08G73/0655C08K3/08
    • In accordance with the present invention, there is provided a novel composition for attaching a semiconductor device to a substrate. The invention composition comprises liquid polycyanate ester monomer, electrically conductive filler, and a curing catalyst, in the substantial absence of alkylphenol. The recognition that attach paste compositions are effective without the addition of alkylphenol has the benefit of reducing the cost of preparation, as well as the ease of preparation of die attach pastes containing electrically conductive filler and polycyanate ester monomer. The incorporation of alkylphenol into die-attach paste compositions has been found to be unnecessary, due to the presence of catalytically active species on the surface of filler flake employed in the preparation of such pastes. Indeed, it is desirable to eliminate alkylphenols from die-attach paste compositions because alkylphenols are acidic species that do not become incorporated into the final polymerized matrix of the cured attach paste. These acidic species can thus leach out, leaving voids in the cured composition and causing corrosion of sensitive electronic parts which come in contact therewith. Optional treatment of filler to render it free of catalytically active metal ions significantly extends the pot life of the composition.
    • 根据本发明,提供了一种用于将半导体器件附着到衬底上的新型组合物。 本发明组合物包含液态聚氰酸酯单体,导电填料和固化催化剂,基本上不存在烷基酚。 在不添加烷基酚的情况下附着糊剂组合物有效的认识有益于降低制备成本,以及容易制备含有导电填料和聚氰酸酯单体的管芯附着浆料。 已经发现,由于在制备这种糊料中使用的填料片表面上存在催化活性物质,因此已经发现将烷基酚引入到模具附着糊剂组合物中是不必要的。 实际上,由于烷基酚是不被引入固化的附着浆料的最终聚合基质中的酸性物质,因此期望从模头附着糊剂组合物中除去烷基酚。 这些酸性物质因此可能被浸出,在固化的组合物中留下空隙并导致与其接触的敏感电子部件的腐蚀。 填充剂的任选处理使其不含催化活性金属离子显着延长了组合物的适用期。