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1. 发明授权

US06953763B2 Solid support stabilized Mn(III) and Mn(VII) and method of preparation 有权
标题翻译：固体支持体系稳定化Mn（III）和Mn（VII）及其制备方法
公开(公告)号：US06953763B2
公开(公告)日：2005-10-11
申请号：US10430500
申请日：2003-05-06
申请人： Rajan K. Vempati , David Y. Son
发明人： Rajan K. Vempati , David Y. Son
IPC分类号： B01D53/86 , B01J21/16 , B01J23/34 , B01J29/072 , B01J29/076 , B01J29/16 , B01J29/46 , B01J29/48 , B01J37/02 , C01G45/02 , C02F1/72 , B01J29/06
CPC分类号： B01J37/0203 , B01D53/8603 , B01D53/8665 , B01J21/16 , B01J23/34 , B01J29/072 , B01J29/076 , B01J29/163 , B01J29/46 , B01J29/48 , C01G45/02 , C01P2002/86 , C02F1/725 , C02F2303/02
摘要： The instant method produces Mn(III) and Mn(VII) in stabilized form. Stabilized Mn(II), Mn(III), Mn(IV), and Mn(VII) are also formed on solid supports. Solid supported Mn(VII) is prepared by first reacting an H-saturated support with Mn(II) in solution. Mn(III) substituted Fe oxide coated on natural zeolite (FMNZ) is prepared by reacting Mn(II) and Fe(III) to a natural zeolite equilibrated with 2 N NaoH. The resulting Mn(IV) and Mn(III) oxide is precipitated from solution and dried to give supported Mn(IV) or Mn(III). The Mn(IV) material is reacted with 1,4-phenylenediamine (PDA) to form supported Mn(VII). In another aspect of the invention, Mn(II) is synthesized by adding 1,2-phenylenediamine dihydrochloride to uncoated and clay and-zeolite coated MnO2. Mn(II) and Mn(III) are synthesized by adding 1,2-phenylenediamine dihydrochloride and 1,4-phenylenediamine dihydrochloride, respectively, to uncoated Mn containing clays, and clay and-zeolite coated MnO2.
摘要翻译：本方法产生稳定形式的Mn（III）和Mn（VII）。稳定的Mn（II），Mn（III），Mn（IV）和Mn（VII）也形成在固体载体上。通过首先使H饱和载体与溶液中的Mn（II）反应来制备固体负载的Mn（VII）。通过使Mn（II）和Fe（III）反应到用2N NaOH平衡的天然沸石中制备涂覆在天然沸石（FMNZ）上的Mn（III）取代的Fe氧化物。所得Mn（IV）和Mn（III）氧化物从溶液中沉淀并干燥，得到负载型Mn（IV）或Mn（III）。使Mn（IV）物质与1,4-苯二胺（PDA）反应形成负载型Mn（VII）。在本发明的另一方面，通过将1,2-苯二胺二盐酸盐加入到未涂覆的和粘土和沸石涂覆的MnO 2 N 2中来合成Mn（II）。通过将1,2-苯二胺二盐酸盐和1,4-苯二胺二盐酸盐分别加入到未包衣的含Mn粘土中，并将粘土和沸石涂覆的MnO 2 N 2合成Mn（II）和Mn（III）。

2. 发明授权

US06784270B1 Polymer containing borate and alkynyl groups 有权
标题翻译：含硼酸酯和炔基的聚合物
公开(公告)号：US06784270B1
公开(公告)日：2004-08-31
申请号：US10255050
申请日：2002-09-26
申请人： Teddy M. Keller , David Y. Son
发明人： Teddy M. Keller , David Y. Son
IPC分类号： C08G7908
CPC分类号： C08G79/08 , C08G77/56
摘要： A polymer has a repeating unit including at least one alkynyl group, at least one borate group, at least one silyl group and/or at least one siloxyl group. The polymer may be prepared by reacting a first compound having at least one alkynyl group and at least one siloxyl group and a second compound selected from boric acid, hydrocarbon borate, hydrocarbon boronic acid, and pyroboric acid. The polymer of the present invention possesses both the processability of an organic polymer and the thermal and oxidative stability of an inorganic polymer.
摘要翻译：聚合物具有包括至少一个炔基，至少一个硼酸酯基，至少一个甲硅烷基和/或至少一个硅氧烷基的重复单元。聚合物可以通过使具有至少一个炔基的第一化合物和至少一个siloxyl基团和选自硼酸，硼酸硼氢盐，烃硼酸和焦硼酸的第二化合物反应来制备。本发明的聚合物具有有机聚合物的加工性和无机聚合物的热和氧化稳定性。

3. 发明授权

US5932335A Oxidation resistant fiber-reinforced composites with poly(carborane-siloxane/silane-acetylene) 失效
标题翻译：具有聚（碳硼烷 - 硅氧烷/硅烷 - 乙炔）的抗氧化纤维增强复合材料
公开(公告)号：US5932335A
公开(公告)日：1999-08-03
申请号：US775486
申请日：1996-12-31
申请人： Teddy M. Keller , David Y. Son
发明人： Teddy M. Keller , David Y. Son
IPC分类号： C08J5/06 , B32B5/28
CPC分类号： C08J5/06 , C08J2383/08 , C08J2383/14 , C08J2385/04 , Y10T428/249928 , Y10T428/24993 , Y10T428/249944 , Y10T428/249945 , Y10T428/249946 , Y10T428/30 , Y10T428/31663
摘要： An oxidation resistant fiber-reinforced composite is made by impregnating a fibrous material with a resin containing a linear polymer having a repeating unit with at least one carboranyl group, at least one silyl or siloxyl group and at least one acetylenic group. The linear polymer may then be cured to form a fiber-reinforced thermoset or may be pyrolyzed to form a fiber-reinforced ceramic. For additional protection of the fibrous material against oxidation, the fibrous material may be prewetted or coated, also with a linear polymer containing a linear polymer having a repeating unit with at least one carboranyl group, at least one silyl or siloxyl group and at least one acetylenic group, prior to being impregnated. The coating on the fibrous material may be cured to form a thermoset coating on the fibers or may be pyrolyzed to form a ceramic coating on the fibers.
摘要翻译：通过用包含具有至少一个碳硼烷基，至少一个甲硅烷基或硅氧烷基和至少一个炔基的重复单元的直链聚合物的树脂浸渍纤维材料来制备抗氧化纤维增强复合材料。然后可以将线性聚合物固化以形成纤维增强的热固性材料，或者可以被热解以形成纤维增强的陶瓷。为了进一步保护纤维材料免于氧化，纤维材料可以预先润湿或涂覆，还可以使用含有具有至少一个碳硼烷基的重复单元的直链聚合物，至少一个甲硅烷基或硅氧烷基和至少一个乙炔基，然后浸渍。纤维材料上的涂层可以固化以在纤维上形成热固性涂层，或者可以被热解以在纤维上形成陶瓷涂层。

4. 发明授权

US5874514A Siloxane unsaturated hydrocarbon based polymers 失效
标题翻译：硅氧烷不饱和烃基聚合物
公开(公告)号：US5874514A
公开(公告)日：1999-02-23
申请号：US437742
申请日：1995-05-09
申请人： Teddy M. Keller , David Y. Son
发明人： Teddy M. Keller , David Y. Son
IPC分类号： C08G77/442 , C08G77/50 , C08G77/06
CPC分类号： C08G77/442 , C08G77/50
摘要： This invention relates to a new class of novel linear inorganic-organic hybrid polymers of varying molecular weight that are useful for making high temperature, oxidatively stable thermosets, and these novel linear polymers are in themselves oxidatively stable at high temperatures between 600.degree.-1000.degree. C. These new materials have repeat units that contain at least one alkynyl group and at least one siloxanyl group within the backbone of these novel linear polymers. These novel linear polymers can be further polymerized to form thermosets and ceramics.
摘要翻译：本发明涉及可用于制备高温，氧化稳定的热固性材料的新型不同分子量的线性无机 - 有机杂化聚合物，这些新型线性聚合物本身在600-1000℃的高温下氧化稳定 C.这些新材料具有在这些新型线性聚合物的骨架内含有至少一个炔基和至少一个硅氧烷基的重复单元。这些新型线性聚合物可以进一步聚合以形成热固性材料和陶瓷。

5. 发明授权

US06265336B1 High temperature ceramics derived from linear carborane-(siloxane or silane)-acetylene copolymers 有权
标题翻译：衍生自线性碳硼烷 - （硅氧烷或硅烷） - 乙炔共聚物的高温陶瓷
公开(公告)号：US06265336B1
公开(公告)日：2001-07-24
申请号：US09618103
申请日：2000-07-17
申请人： Teddy M. Keller , David Y. Son
发明人： Teddy M. Keller , David Y. Son
IPC分类号： C04B35571
CPC分类号： C04B35/563 , C04B35/571 , C04B35/58085
摘要： This invention relates to a new class of novel inorganic-organic hybrid ceramics that are formed from novel linear polymers of varying molecular weight and varying carborane content.
摘要翻译：本发明涉及一类新的无机 - 有机杂化陶瓷，其由具有不同分子量和不同碳硼烷含量的新型线性聚合物形成。

6. 发明授权

US5563181A Siloxane unsaturated hydrocarbon based thermosetting polymers 失效
标题翻译：硅氧烷不饱和烃基热固性聚合物
公开(公告)号：US5563181A
公开(公告)日：1996-10-08
申请号：US437763
申请日：1995-05-09
申请人： Teddy M. Keller , David Y. Son
发明人： Teddy M. Keller , David Y. Son
IPC分类号： C08F2/46 , C08G77/442 , C08G77/50
CPC分类号： C08G77/442 , C08G77/50
摘要： This invention relates to a new class of novel inorganic-organic hybrid thermoset polymers that are formed from linear inorganic-organic hybrid polymers of varying molecular weight. These new high temperature oxidatively stable thermosetting polymers are formed from linear polymeric materials having repeat units that contain at least one alkynyl group for cross-linking purposes and at least one siloxanyl group. These novel thermoset polymers contain an unsaturated cross-linked hydrocarbon moiety.
摘要翻译：本发明涉及由具有不同分子量的线性无机 - 有机杂化聚合物形成的一类新型无机 - 有机杂化的热固性聚合物。这些新的高温氧化稳定的热固性聚合物由含有至少一个用于交联目的的炔基和至少一个硅氧烷基的重复单元的直链聚合物形成。这些新型热固性聚合物含有不饱和的交联烃部分。

7. 发明授权

US5483017A High temperature thermosets and ceramics derived from linear carborane-(siloxane or silane)-acetylene copolymers 失效
标题翻译：衍生自直链碳硼烷 - （硅氧烷或硅烷） - 乙炔共聚物的高温热固性材料和陶瓷
公开(公告)号：US5483017A
公开(公告)日：1996-01-09
申请号：US337013
申请日：1994-11-07
申请人： Teddy M. Keller , David Y. Son
发明人： Teddy M. Keller , David Y. Son
IPC分类号： C04B35/571 , C08G77/56 , C08G77/60
CPC分类号： C04B35/571 , C08G77/56 , C08G77/60
摘要： This invention relates to a new class of novel inorganic-organic hybrid thermosetting polymers and ceramics that are formed from novel linear polymers of varying molecular weight and varying carborane content. These novel organoboron thermoset polymers and ceramics contain an unsaturated cross-linked moiety.
摘要翻译：本发明涉及一类新的无机 - 有机杂化的热固性聚合物和陶瓷，它们是由不同分子量和不同碳硼烷含量的新型线性聚合物形成的。这些新型有机硼热固性聚合物和陶瓷含有不饱和交联部分。

8. 发明授权

US08084662B2 Method for degrading chemical warfare agents using Mn(VII) oxide with-and-without solid support 有权
标题翻译：使用不含固体载体的Mn（VII）氧化物降解化学战剂的方法
公开(公告)号：US08084662B2
公开(公告)日：2011-12-27
申请号：US11124742
申请日：2005-05-09
申请人： Rajan K. Vempati , Edward R. Biehl , Ramesh S. Hegde , David Y. Son
发明人： Rajan K. Vempati , Edward R. Biehl , Ramesh S. Hegde , David Y. Son
IPC分类号： A62D3/37
CPC分类号： A62D3/36 , A62D2101/02
摘要： The invention provides a novel method of detoxifying highly toxic chemicals, and treating surfaces contaminated, or potentially contaminated, with toxic chemical agents such as chemical warfare agents and/or industrial toxins. The methods utilizes a novel sorbent compound which comprises Mn(VII) mineral which can be either solid supported or non-solid supported. The Mn(VII) mineral can be provided in a number of different forms including creams, lotions, powders, liquids, slurries and aerosols.
摘要翻译：本发明提供了一种解毒高毒性化学品的新方法，以及用有毒化学试剂如化学战剂和/或工业毒素处理被污染或可能被污染的表面。该方法利用了一种新型的吸附剂化合物，它包括可以是固体支持的或非固体的Mn（VII）矿物。 Mn（VII）矿物可以以许多不同的形式提供，包括霜剂，洗剂，粉剂，液体，浆液和气溶胶。

9. 发明授权

US06767981B1 Thermoset and ceramic containing silicon and boron 有权
标题翻译：含硅和硼的热固性陶瓷和陶瓷
公开(公告)号：US06767981B1
公开(公告)日：2004-07-27
申请号：US10254938
申请日：2002-09-26
申请人： Teddy M. Keller , David Y. Son
发明人： Teddy M. Keller , David Y. Son
IPC分类号： C08G7908
CPC分类号： C08G79/08
摘要： A thermoset polymer has a repeating unit comprising at least one crosslinking group having at least one unsaturated carbon-carbon bond and at least two crosslinking bonds, at least one borate group, at least one silyl group and/or at least one siloxyl group. The thermoset polymer of the present invention may be prepared by reacting a first compound having at least one alkynyl group, and at least one group selected from silyl groups and siloxyl groups, with a second compound selected from boric acid, hydrocarbon boronic acid, hydrocarbon borate, and pyroboric acid under reaction conditions sufficient to crosslink a sufficient number of alkyne bonds to form the thermoset polymer. The thermoset polymer of the present invention possesses both the processability of an organic polymer and the thermal and oxidative stability of an inorganic polymer. The thermoset polymer of the present invention may be further processed into a ceramic material by pyrolysis.
摘要翻译：热固性聚合物具有包含至少一个具有至少一个不饱和碳 - 碳键和至少两个交联键，至少一个硼酸酯基，至少一个甲硅烷基和/或至少一个硅氧烷基的交联基团的重复单元。本发明的热固性聚合物可以通过使具有至少一个炔基的第一化合物和至少一种选自甲硅烷基和硅氧烷基的基团与选自硼酸，烃硼酸，硼酸氢硼酸的第二化合物反应来制备和焦硼酸在足以交联足够数量的炔键以形成热固性聚合物的反应条件下进行。本发明的热固性聚合物具有有机聚合物的加工性和无机聚合物的热和氧化稳定性。本发明的热固性聚合物可以通过热解进一步加工成陶瓷材料。

10. 发明授权

US06187703B1 High temperature ceramics derived from linear carborane-(siloxane or silane)-acetylene copolymers 失效
公开(公告)号：US06187703B1
公开(公告)日：2001-02-13
申请号：US08540148
申请日：1995-10-06
申请人： Teddy M. Keller , David Y. Son
发明人： Teddy M. Keller , David Y. Son
IPC分类号： C04B35571
CPC分类号： C04B35/563 , C04B35/571 , C04B35/58085
摘要： This invention relates to a new class of novel inorganic-organic hybrid ceramics that are formed from novel linear polymers of varying molecular weight and varying carborane content.

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