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1. 发明申请

US20150210784A1 Catalyst on silica clad alumina support 有权
标题翻译：二氧化硅包覆氧化铝载体上的催化剂
公开(公告)号：US20150210784A1
公开(公告)日：2015-07-30
申请号：US13999217
申请日：2014-01-30
申请人： Stephen R. Schmidt , David M. Chapman , Manoj M. Koranne , Michael D. Jensen
发明人： Stephen R. Schmidt , David M. Chapman , Manoj M. Koranne , Michael D. Jensen
IPC分类号： C08F4/18 , C08F4/22
CPC分类号： C08F110/02 , C08F4/69 , C08F4/025
摘要： The invention concerns catalysts comprising (i) a clad catalyst support comprising (a) a core which comprises alumina particles and (b) about 1 to about 40 weight percent silica cladding, based on the weight of the clad catalyst support, on the surface of the core; the catalyst support having a BET surface area of greater than 20 m2/g and a porosity of at least about 0.2 cc/g; and (ii) 0.1 to 10 weight percent, based on the weight of the catalyst, of catalytically active transition metal on the surface of the clad catalyst support; wherein the catalyst support has a normalized sulfur uptake (NSU) of up to 25 μg/m2. The invention also concerns the production and use of such catalyst.
摘要翻译：本发明涉及催化剂，其包括（i）包覆催化剂载体，其包含（a）包含氧化铝颗粒的芯，和（b）约1至约40重量％的二氧化硅包层，基于包覆催化剂载体的重量，核心; 所述催化剂载体具有大于20m 2 / g的BET表面积和至少约0.2cc / g的孔隙率; 和（ii）基于催化剂重量的0.1至10重量％的催化活性过渡金属在包覆催化剂载体的表面上; 其中催化剂载体具有高达25μg/ m 2的归一化硫吸收（NSU）。本发明还涉及这种催化剂的生产和使用。

2. 发明授权

US08545796B2 Silica-stabilized ultrafine anatase titania, vanadia catalysts, and methods of production thereof 有权
标题翻译：二氧化硅稳定的超细锐钛矿型二氧化钛，氧钒催化剂及其制造方法
公开(公告)号：US08545796B2
公开(公告)日：2013-10-01
申请号：US12533414
申请日：2009-07-31
申请人： David M. Chapman
发明人： David M. Chapman
IPC分类号： B01J21/00 , B01J21/06 , B01J21/08 , B01J23/00 , C01B33/12 , C01G23/047 , B01D53/56 , B01D53/94
CPC分类号： B01J21/08 , B01D53/9418 , B01D53/9477 , B01D2251/2067 , B01D2255/20707 , B01D2255/20723 , B01D2255/20776 , B01D2255/30 , B01D2258/012 , B01J21/063 , B01J23/22 , B01J23/30 , B01J35/0013 , B01J35/006 , B01J35/1014 , B01J35/1038 , B01J37/0209 , B01J37/035 , B01J37/04 , B01J37/08
摘要： The invention is directed to compositions and processes for the production of silica-stabilized ultrafine anatase titanias and which may further comprise tungsten and vanadia. The surface stabilization may be by treatment of the TiO2 particles with a low molecular weight and/or small nanoparticle form of silica such as, in preferred embodiments, a tetra(alkyl)ammonium silicate or silicic acid, which serves to efficiently maintain the anatase phase and prevent crystal growth under severe thermal and hydrothermal conditions, even in the presence of vanadia. The vanadia catalysts produced from the novel titanias have equal or improved catalytic activity for selective catalytic reduction of NOx compared to conventional vanadia supported silica-titania based catalysts. The invention is further directed to diesel emission catalytic devices comprising the novel titania-based catalyst compositions.
摘要翻译：本发明涉及用于生产二氧化硅稳定的超细锐钛矿钛的组合物和方法，并且其还可以包含钨和钒。表面稳定化可以通过用低分子量和/或二氧化硅的小纳米颗粒形式的TiO 2颗粒进行处理，例如在优选的实施方案中为四（烷基）硅酸铵或硅酸，其用于有效地保持锐钛矿相并且在严重的热和水热条件下，即使在存在氧化钒的情况下也能防止晶体生长。与常规的支持二氧化钛 - 二氧化钛的催化剂相比，从新型钛合金制备的氧钒催化剂与NOx的选择性催化还原具有相同或改善的催化活性。本发明还涉及包含新型二氧化钛基催化剂组合物的柴油发射催化装置。

3. 发明授权

US5236880A Catalyst for cracking of paraffinic feedstocks 失效
标题翻译：用于裂化石蜡原料的催化剂
公开(公告)号：US5236880A
公开(公告)日：1993-08-17
申请号：US846989
申请日：1992-03-09
申请人： David M. Chapman
发明人： David M. Chapman
IPC分类号： B01J29/46 , B01J29/76 , C10G11/05
CPC分类号： C10G11/05 , B01J29/46 , B01J2229/40
摘要： A zeolite catalyst with improved hydrocarbon conversion comprising a crystalline aluminosilicate having a SiO.sub.2 /Al.sub.2 O.sub.3 ratio greater than 5 and preferably a MFI or MEL zeolite. The zeolite contains a Group VIIIA metal, preferably nickel, and it has been subjected to severe thermal or hydrothermal treatments under controlled conditions of temperature, time or steam partial pressure so as to effect an increase in the relative surface concentrations of Group VIIIA metal and aluminum. The catalyst can be used in a process for the conversion of paraffinic feedstocks to improve paraffin cracking activity, to increase the aromatic fraction in the C5 to C12 gasoline range products, to improve the calculated octane numbers of the C5 to C12 gasoline range product, and/or to improve the yield of the C5 to C12 gasoline range products.
摘要翻译：具有改进的烃转化率的沸石催化剂，其包含SiO 2 / Al 2 O 3比率大于5，优选MFI或MEL沸石的结晶硅铝酸盐。沸石含有ⅦA族金属，优选镍，并且在温度，时间或蒸汽分压的受控条件下进行严格的热或水热处理，以使ⅦA族金属和铝的相对表面浓度增加。该催化剂可用于转化石蜡原料以提高石蜡裂化活性的方法，以增加C5至C12汽油范围产物中的芳族馏分，以改善C5至C12汽油范围产物的计算辛烷值，以及 /或提高C5至C12汽油范围产品的产量。

4. 发明授权

US5157183A Aromatization process using an improved catalyst 失效
标题翻译：使用改进的催化剂的芳构化方法
公开(公告)号：US5157183A
公开(公告)日：1992-10-20
申请号：US625272
申请日：1990-12-10
申请人： Ronald L. Cotterman , David M. Chapman
发明人： Ronald L. Cotterman , David M. Chapman
IPC分类号： B01J29/072 , C07C2/00 , C07C2/76
CPC分类号： C07C2/00 , B01J29/072 , C07C2/76 , C07C2529/70
摘要： A catalytic process for converting low molecular weight non-aromatic compounds into higher molecular weight aromatic compounds utilizes a unique zeolite catalyst with improved hydrocarbon conversion. The catalyst is a crystalline aluminosilicate having a SiO.sub.2 /Al.sub.2 O.sub.3 ratio greater than 5 and preferably a MFI or MEL zeolite. The zeolite contains a Group VIIIA metal, preferably nickel, and is subjected to thermal or hydrothermal treatments under controlled conditions of temperature, time or steam partial pressure so as to effect a decrease in the amount of carbon deposited as the zeolite catalyst. The catalyst can be used in a process for the conversion of light hydrocarbon feedstocks to improve aromatization activity.
摘要翻译：将低分子量非芳族化合物转化为更高分子量芳族化合物的催化方法利用具有改进的烃转化率的独特的沸石催化剂。催化剂是SiO 2 / Al 2 O 3比率大于5，优选MFI或MEL沸石的结晶硅铝酸盐。沸石含有ⅦA族金属，优选为镍，并且在温度，时间或蒸汽分压的受控条件下进行热或水热处理，以便降低作为沸石催化剂沉积的碳的量。催化剂可用于轻烃原料转化以改善芳构化活性的方法。

5. 发明申请

US20110118109A1 STABLE SUB-MICRON TITANIA SOLS 有权
标题翻译：稳定的亚微米TITANIA SOLS
公开(公告)号：US20110118109A1
公开(公告)日：2011-05-19
申请号：US12618484
申请日：2009-11-13
申请人： David M. Chapman
发明人： David M. Chapman
IPC分类号： B01J31/02 , B01J21/08 , B01J23/10 , B01J23/30 , B01J23/34 , B01J23/745 , B01J23/72 , B01J21/06 , B01J21/04
CPC分类号： B01J21/063 , B01D53/885 , B01D53/9418 , B01D2255/20707 , B01D2259/804 , B01J23/22 , B01J23/30 , B01J35/002 , B01J35/004 , B01J35/023 , C01G23/047 , C01G23/0532 , C01P2004/04 , C01P2004/51 , C01P2004/62 , C01P2006/12 , C01P2006/14 , C01P2006/22 , C09C1/3669
摘要： The present invention is directed to compositions and processes for the production of stable, alkaline, high solids, low viscosity, low surface tension, low flammability, sub-micron titania sols that have minimal offensive odor and methods of their use. Compositions of the present invention include, for example, mixtures of strong and weak organic bases used as dispersants to stabilize the titania sols. The dispersant mixtures have been found to result in relatively high titania solids content, low surface tension, low viscosity suspensions that are low in flammability. Sols produced according to the present invention can be used, for example, in catalytic applications such as catalyst supports for diesel emission control, or in pollutant photocatalyst applications in which it is desirable to have the titania in sol form.
摘要翻译：本发明涉及用于生产稳定，碱性，高固体，低粘度，低表面张力，低可燃性，亚微米级二氧化钛溶胶的组合物和方法，其具有最小的令人反感的气味及其使用方法。本发明的组合物包括例如用作分散剂的强和弱有机碱的混合物以稳定二氧化钛溶胶。已经发现分散剂混合物导致相对高的二氧化钛固体含量，低表面张力，低粘度悬浮液，其易燃性低。根据本发明生产的硫醇可用于例如催化应用，例如用于柴油机排放控制的催化剂载体，或者其中希望具有溶胶形式的二氧化钛的污染光催化剂应用中。

6. 发明申请

US20110027154A1 SILICA-STABILIZED ULTRAFINE ANATASE TITANIA, VANADIA CATALYSTS, AND METHODS OF PRODUCTION THEREOF 有权
标题翻译：二氧化硅稳定超细钛铁矿，VANADIA催化剂及其生产方法
公开(公告)号：US20110027154A1
公开(公告)日：2011-02-03
申请号：US12533414
申请日：2009-07-31
申请人： David M. Chapman
发明人： David M. Chapman
IPC分类号： B01D53/94 , B01J32/00 , B01J23/22 , F01N3/10
CPC分类号： B01J21/08 , B01D53/9418 , B01D53/9477 , B01D2251/2067 , B01D2255/20707 , B01D2255/20723 , B01D2255/20776 , B01D2255/30 , B01D2258/012 , B01J21/063 , B01J23/22 , B01J23/30 , B01J35/0013 , B01J35/006 , B01J35/1014 , B01J35/1038 , B01J37/0209 , B01J37/035 , B01J37/04 , B01J37/08
摘要： The invention is directed to compositions and processes for the production of silica-stabilized ultrafine anatase titanias and which may further comprise tungsten and vanadia. The surface stabilization may be by treatment of the TiO2 particles with a low molecular weight and/or small nanoparticle form of silica such as, in preferred embodiments, a tetra(alkyl)ammonium silicate or silicic acid, which serves to efficiently maintain the anatase phase and prevent crystal growth under severe thermal and hydrothermal conditions, even in the presence of vanadia. The vanadia catalysts produced from the novel titanias have equal or improved catalytic activity for selective catalytic reduction of NOx compared to conventional vanadia supported silica-titania based catalysts. The invention is further directed to diesel emission catalytic devices comprising the novel titania-based catalyst compositions.
摘要翻译：本发明涉及用于生产二氧化硅稳定的超细锐钛矿钛的组合物和方法，并且其还可以包含钨和钒。表面稳定化可以通过用低分子量和/或二氧化硅的小纳米颗粒形式的TiO 2颗粒进行处理，例如在优选的实施方案中为四（烷基）硅酸铵或硅酸，其用于有效地保持锐钛矿相并且在严重的热和水热条件下，即使在存在氧化钒的情况下也能防止晶体生长。与常规的支持二氧化钛 - 二氧化钛的催化剂相比，从新型钛合金制备的氧钒催化剂与NOx的选择性催化还原具有相同或改善的催化活性。本发明还涉及包含新型二氧化钛基催化剂组合物的柴油发射催化装置。

7. 发明授权

US08481453B2 Capture of volatilized vanadium and tungsten compounds in a selective catalytic reduction system 有权
标题翻译：在选择性催化还原体系中捕获挥发的钒和钨化合物
公开(公告)号：US08481453B2
公开(公告)日：2013-07-09
申请号：US13249919
申请日：2011-09-30
申请人： David M. Chapman
发明人： David M. Chapman
IPC分类号： B01J23/00
CPC分类号： B01J23/22 , B01D53/64 , B01D53/9418 , B01D53/9463 , B01D53/9477 , B01D2251/2062 , B01D2251/2067 , B01D2253/104 , B01D2253/108 , B01D2253/1124 , B01D2253/116 , B01D2255/2063 , B01D2255/2065 , B01D2255/20707 , B01D2255/20723 , B01D2255/2073 , B01D2255/20738 , B01D2255/20761 , B01D2255/20769 , B01D2255/20776 , B01D2257/60 , B01D2258/012 , B01J21/063 , B01J23/002 , B01J23/30 , B01J2523/00 , F01N3/2066 , Y02T10/24 , B01J2523/3712 , B01J2523/47 , B01J2523/69
摘要： An apparatus and method for treating diesel exhaust gases are described. The system consists of two functionalities, the first being a selective catalytic reduction (SCR) catalyst system and the second being a capture material for capturing catalyst components such as vanadia that have appreciable volatility under extreme exposure conditions. The SCR catalyst component is typically based on a majority phase of titania, with added minority-phase catalyst components comprising of one or more of the oxides of vanadium, silicon, tungsten, molybdenum, iron, cerium, phosphorous, copper and/or manganese vanadia. The capture material typically comprises a majority phase of high surface area oxides such as silica-stabilized titania, alumina, or stabilized alumina, for example.
摘要翻译：描述了一种用于处理柴油机废气的设备和方法。该系统由两个功能组成，第一个是选择性催化还原（SCR）催化剂体系，第二个是用于捕获在极端暴露条件下具有明显挥发性的催化剂组分如氧钒的捕获材料。 SCR催化剂组分通常基于二氧化钛的大部分相，其中添加的少数阶段催化剂组分包含一种或多种钒，硅，钨，钼，铁，铈，磷，铜和/或锰氧化钒的氧化物。捕获材料通常包括例如高表面积氧化物的多数相，例如二氧化硅稳定的二氧化钛，氧化铝或稳定的氧化铝。

8. 发明授权

US08481452B2 Capture of volatilized vanadium and tungsten compounds in a selective catalytic reduction system 有权
标题翻译：在选择性催化还原体系中捕获挥发的钒和钨化合物
公开(公告)号：US08481452B2
公开(公告)日：2013-07-09
申请号：US12638166
申请日：2009-12-15
申请人： David M. Chapman
发明人： David M. Chapman
IPC分类号： B01J23/00
CPC分类号： B01J23/22 , B01D53/64 , B01D53/9418 , B01D53/9463 , B01D53/9477 , B01D2251/2062 , B01D2251/2067 , B01D2253/104 , B01D2253/108 , B01D2253/1124 , B01D2253/116 , B01D2255/2063 , B01D2255/2065 , B01D2255/20707 , B01D2255/20723 , B01D2255/2073 , B01D2255/20738 , B01D2255/20761 , B01D2255/20769 , B01D2255/20776 , B01D2257/60 , B01D2258/012 , B01J21/063 , B01J23/002 , B01J23/30 , B01J2523/00 , F01N3/2066 , Y02T10/24 , B01J2523/3712 , B01J2523/47 , B01J2523/69
摘要： An apparatus and method for treating diesel exhaust gases are described. The system consists of two functionalities, the first being a selective catalytic reduction (SCR) catalyst system and the second being a capture material for capturing catalyst components that have appreciable volatility under extreme exposure conditions. The SCR catalyst component is typically based on a majority phase of titania, with added minority-phase catalyst components comprising of one or more of the oxides of vanadium, silicon, tungsten, molybdenum, iron, cerium, phosphorous, copper and/or manganese vanadia. The capture material typically comprises a majority phase of high surface area oxides such as silica-stabilized titania, alumina, or stabilized alumina, for example, wherein the capture material maintains a low total fractional monolayer coverage of minority phase oxides for the duration of the extreme exposure. The method involves treatment of hot exhaust streams by both the catalyst material and capture material, wherein the capture material can be in a mixture with the catalyst material, or can be located downstream thereof, or both, but still be maintained at the extreme temperatures. Volatile catalyst components such as vanadia are thus removed from the vapor phase of the exhaust gas.
摘要翻译：描述了一种用于处理柴油机废气的设备和方法。该系统由两个功能组成，第一个是选择性催化还原（SCR）催化剂体系，第二个是用于捕获在极端暴露条件下具有明显挥发性的催化剂组分的捕获材料。 SCR催化剂组分通常基于二氧化钛的大部分相，其中添加的少数阶段催化剂组分包含一种或多种钒，硅，钨，钼，铁，铈，磷，铜和/或锰氧化钒的氧化物。捕获材料通常包括高表面积氧化物的大多数相，例如二氧化硅稳定的二氧化钛，氧化铝或稳定的氧化铝，其中捕获材料在极端的持续时间内维持少量相氧化物的低总分数单层覆盖曝光。该方法包括通过催化剂材料和捕获材料二者处理热排气流，其中捕获材料可以与催化剂材料混合，或者可以位于其下游或两者，但是仍然保持在极端温度。因此，挥发性催化剂组分如氧钒从废气的气相中除去。

9. 发明申请

US20120283092A1 Stable Sub-Micron Titania Sols 有权
标题翻译：稳定的亚微米级二氧化钛溶液
公开(公告)号：US20120283092A1
公开(公告)日：2012-11-08
申请号：US13550954
申请日：2012-07-17
申请人： David M. Chapman
发明人： David M. Chapman
IPC分类号： B01J21/06 , B01J21/08
CPC分类号： B01J21/063 , B01D53/885 , B01D53/9418 , B01D2255/20707 , B01D2259/804 , B01J23/22 , B01J23/30 , B01J35/002 , B01J35/004 , B01J35/023 , C01G23/047 , C01G23/0532 , C01P2004/04 , C01P2004/51 , C01P2004/62 , C01P2006/12 , C01P2006/14 , C01P2006/22 , C09C1/3669
摘要： The present invention is directed to compositions and processes for the production of stable, alkaline, high solids, low viscosity, low surface tension, low flammability, sub-micron titania sols that have minimal offensive odor and methods of their use. Compositions of the present invention include, for example, mixtures of strong and weak organic bases used as dispersants to stabilize the titania sols. The dispersant mixtures have been found to result in relatively high titania solids content, low surface tension, low viscosity suspensions that are low in flammability. Sols produced according to the present invention can be used, for example, in catalytic applications such as catalyst supports for diesel emission control, or in pollutant photocatalyst applications in which it is desirable to have the titania in sol form.
摘要翻译：本发明涉及用于生产稳定，碱性，高固体，低粘度，低表面张力，低可燃性，亚微米级二氧化钛溶胶的组合物和方法，其具有最小的令人反感的气味及其使用方法。本发明的组合物包括例如用作分散剂的强和弱有机碱的混合物以稳定二氧化钛溶胶。已经发现分散剂混合物导致相对高的二氧化钛固体含量，低表面张力，低粘度悬浮液，其易燃性低。根据本发明生产的硫醇可用于例如催化应用，例如用于柴油机排放控制的催化剂载体，或者其中希望具有溶胶形式的二氧化钛的污染光催化剂应用中。

10. 发明授权

US08247343B2 Stable sub-micron titania sols 有权
标题翻译：稳定的亚微米级二氧化钛溶胶
公开(公告)号：US08247343B2
公开(公告)日：2012-08-21
申请号：US12618484
申请日：2009-11-13
申请人： David M. Chapman
发明人： David M. Chapman
IPC分类号： B01J31/02 , B01J21/08 , B01J23/10 , B23B5/16 , C01G23/053 , C01G23/08
CPC分类号： B01J21/063 , B01D53/885 , B01D53/9418 , B01D2255/20707 , B01D2259/804 , B01J23/22 , B01J23/30 , B01J35/002 , B01J35/004 , B01J35/023 , C01G23/047 , C01G23/0532 , C01P2004/04 , C01P2004/51 , C01P2004/62 , C01P2006/12 , C01P2006/14 , C01P2006/22 , C09C1/3669
摘要： The present invention is directed to compositions and processes for the production of stable, alkaline, high solids, low viscosity, low surface tension, low flammability, sub-micron titania sols that have minimal offensive odor and methods of their use. Compositions of the present invention include, for example, mixtures of strong and weak organic bases used as dispersants to stabilize the titania sols. The dispersant mixtures have been found to result in relatively high titania solids content, low surface tension, low viscosity suspensions that are low in flammability. Sols produced according to the present invention can be used, for example, in catalytic applications such as catalyst supports for diesel emission control, or in pollutant photocatalyst applications in which it is desirable to have the titania in sol form.
摘要翻译：本发明涉及用于生产稳定，碱性，高固体，低粘度，低表面张力，低可燃性，亚微米级二氧化钛溶胶的组合物和方法，其具有最小的令人反感的气味及其使用方法。本发明的组合物包括例如用作分散剂的强和弱有机碱的混合物以稳定二氧化钛溶胶。已经发现分散剂混合物导致相对高的二氧化钛固体含量，低表面张力，低粘度悬浮液，其易燃性低。根据本发明生产的硫醇可用于例如催化应用，例如用于柴油机排放控制的催化剂载体，或者其中希望具有溶胶形式的二氧化钛的污染光催化剂应用中。

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