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    • 1. 发明授权
    • Polypropylene having a high maleic anhydride content
    • 具有高马来酸酐含量的聚丙烯
    • US07183359B2
    • 2007-02-27
    • US11249070
    • 2005-10-12
    • Paul K. HannaDavid D. Truong
    • Paul K. HannaDavid D. Truong
    • C08F269/00C08L23/12
    • C08F255/02C08F8/46C08F2810/40C08F222/06C08F10/06
    • Polypropylene having high maleic anhydride content, between about 5 and about 45 wt %, may be prepared by first reacting a metallocene-prepared polypropylene having terminal unsaturation with one mole equivalent of maleic anhydride to give polypropylene having a single unsaturation and a terminal succinic anhydride moiety. This product is then reacted with additional maleic anhydride in the presence of a free radical initiator (such as a peroxide or UV radiation) to give a polypropylene with maleic anhydride moieties along the backbone. The polypropylene product does not suffer scission or crosslinking with subsequently undesirable increases in molecular weight or viscosity. The maleic anhydride moieties provide reactivity to the polypropylene and thus expand its uses and applications.
    • 具有约5至约45重量%的马来酸酐含量高的聚丙烯可以通过首先使具有不饱和键的茂金属制备的聚丙烯与1摩尔当量马来酸酐反应得到具有单一不饱和度和末端琥珀酸酐部分的聚丙烯 。 然后在自由基引发剂(例如过氧化物或UV辐射)的存在下,将该产物与另外的马来酸酐反应,得到沿着主链的具有马来酸酐部分的聚丙烯。 聚丙烯产品不会发生断裂或交联,随后不希望的分子量或粘度增加。 马来酸酐部分为聚丙烯提供反应性,从而扩大其用途和用途。