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    • 9. 发明申请
    • Process for incorporating metal nanoparticles in a polymeric article
    • 将金属纳米粒子掺入聚合物制品中的方法
    • US20090297830A1
    • 2009-12-03
    • US12156521
    • 2008-06-02
    • Robert A. PylesRonald C. HeddenDaniel Lentz
    • Robert A. PylesRonald C. HeddenDaniel Lentz
    • B05D3/10B32B5/16
    • H01B1/22B82Y30/00C08J5/005C23C18/1658C23C18/206C23C18/44Y10T428/254
    • A process of incorporating metal in the form of nanoparticles into the surface layer of a polymeric article is disclosed. The process includes bringing at least a part of the surface of said article in contact with a solvent mixture that contains (a) water, (b) a carrier conforming to R1—[—O—(CH2)n]mOR2 where R1 and R2 independently one from the other denote a radical selected from the group consisting of linear and branched C1-18 alkyl, benzyl, benzoyl, phenyl and H, n is 2 or 3, and m is 1-35, (c) a metal precursor, and optionally (d) a leveling agent, for a time sufficient to enable infusion of at least some of said metal precursor into said article to obtain an article having a treated surface layer; and treating the surface layer with a reducing agent to produce metal in the form of nanoparticles. Articles prepared by the inventive process exhibit advantageous electrical and/or optical properties.
    • 公开了将纳米颗粒形式的金属掺入聚合物的表面层的方法。 该方法包括使所述制品的表面的至少一部分与含有(a)水,(b)符合R1 - [ - O-(CH2)n] mOR2的载体的溶剂混合物接触,其中R 1和R 2 独立地一个表示选自直链和支链C 1-18烷基,苄基,苯甲酰基,苯基和H的基团,n为2或3,m为1-35,(c)金属前体, 和任选地(d)流平剂,持续足以使至少一些所述金属前体浸入所述制品中以获得具有经处理的表面层的制品的时间; 并用还原剂处理表层以产生纳米颗粒形式的金属。 通过本发明方法制备的制品表现出有利的电和/或光学性质。