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    • 1. 发明申请
    • FUEL CELL COMPRISING OXYGEN ELECTRODE WITH SURFACE NANOSTRUCTURE
    • 含有表面纳米结构的氧电极的燃料电池
    • US20100104915A1
    • 2010-04-29
    • US12652468
    • 2010-01-05
    • Daisuke INOMitsuru HashimotoAkira TaomotoNobuyasu SuzukiYuka Yamada
    • Daisuke INOMitsuru HashimotoAkira TaomotoNobuyasu SuzukiYuka Yamada
    • H01M8/10
    • H01M4/8657H01M4/8605H01M4/92
    • The present invention is aimed to realize, in a fuel cell with an oxygen electrode (a catalytic electrode), both catalytic function and immobilization of the catalyst nanoparticles when the catalyst nanoparticles are very small nanoparticles in the size of 1-3 nm.Oxygen electrode used in the fuel cell according to the present invention is an oxygen electrode comprising a plurality of carbon particles, a carbon thin-film, and surface nanostructure, wherein the carbon particles are bonded to one another with the carbon thin-film 2, the surface nanostructure is formed on the surface of the carbon thin-film, the surface nanostructure comprises catalyst nanoparticles made of platinum (Pt) and carbon nanoparticles, diameter of each of the carbon particles is 30 nm or more and 100 nm or less, diameter of the catalyst nanoparticle is 1.7 nm or more and 3.1 nm or less, and diameter of the carbon nanoparticle is 1.0 nm or more and 11.2 nm or less. According to this combination of these elements, the catalyst nanoparticles are confined within three-dimensional structure to be formed by the carbon nanoparticles and are immobilized without losing space which allows any reactant to be accessed to the surface of the catalyst nanoparticles.
    • 本发明旨在在具有氧电极(催化电极)的燃料电池中实现催化剂纳米颗粒在1-3nm尺寸的非常小的纳米颗粒时催化剂纳米颗粒的催化功能和固定。 根据本发明的燃料电池中使用的氧电极是包含多个碳颗粒,碳薄膜和表面纳米结构的氧电极,其中碳颗粒通过碳薄膜2彼此接合, 在碳薄膜的表面上形成表面纳米结构,表面纳米结构包括由铂(Pt)和碳纳米颗粒制成的催化剂纳米颗粒,每个碳颗粒的直径为30nm以上至100nm以下,直径 的催化剂纳米粒子的粒径为1.7nm以上且3.1nm以下,碳纳米粒子的直径为1.0nm以上且11.2nm以下。 根据这些元素的这种组合,催化剂纳米颗粒被限制在由碳纳米颗粒形成的三维结构内,并且被固定化而不会损失允许任何反应物进入催化剂纳米颗粒表面的空间。