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1. 发明申请

US20120048109A1 Mixed Matrix Membranes 审中-公开
标题翻译：混合基质膜
公开(公告)号：US20120048109A1
公开(公告)日：2012-03-01
申请号：US12862215
申请日：2010-08-24
申请人： Daniel Chinn , De Q. Vu , Stephen J. Miller , Paul F. Bryan , Curtis L. Munson
发明人： Daniel Chinn , De Q. Vu , Stephen J. Miller , Paul F. Bryan , Curtis L. Munson
IPC分类号： B01D53/14 , B01J20/28
CPC分类号： B01D69/148 , B01D53/228 , B01D63/10 , B01D67/0079 , B01D69/02 , B01D69/08 , B01D71/028 , B01D71/64 , B01D2323/12 , B01D2325/20
摘要： Disclosed herein are mixed matrix membranes which include a continuous phase organic polymer with molecular sieves interspersed therein, the molecular sieves comprising one or more zeolites having an HEU structure type; wherein the membrane exhibits a mixed matrix effect and further wherein the membrane has a N2/CH4 selectivity of greater than about 5, at 35° C. and a pressure of 100 psia (690 kPa). Methods for their preparation and use are also disclosed.
摘要翻译：本文公开了混合基质膜，其包括分散有分子筛的连续相有机聚合物，所述分子筛包含一种或多种具有HEU结构类型的沸石; 其中所述膜表现出混合基质效应，并且进一步其中所述膜在35℃和100psia（690kPa）的压力下具有大于约5的N 2 / CH 4选择性。还公开了其制备和使用方法。

2. 发明申请

US20100270205A1 HIGH ENERGY DISTILLATE FUEL COMPOSITION AND METHOD OF MAKING THE SAME 有权
标题翻译：高能量蒸馏燃料组合物及其制备方法
公开(公告)号：US20100270205A1
公开(公告)日：2010-10-28
申请号：US12582809
申请日：2009-10-21
申请人： Jaime Lopez , Janine Lichtenberger , William J. Cannella , Curtis L. Munson
发明人： Jaime Lopez , Janine Lichtenberger , William J. Cannella , Curtis L. Munson
IPC分类号： C10L1/04 , C10G47/00
CPC分类号： C10G65/12 , C10G45/44 , C10G47/00 , C10G2300/1048 , C10G2300/30 , C10G2400/08 , C10L1/04
摘要： The disclosure describes a high energy density jet fuel composition, having a smoke point about 18 mm as determined by ASTM D1322 and a thermal stability of no more than 25 mm Hg as determined by ASTM D 3241, and a method for making a jet fuel composition, wherein the net heat of combustion is determined by the aromatics content, cycloparaffins content, and normal plus or iso paraffins content in the jet fuel composition.
摘要翻译：本公开描述了一种高能量密度的喷气燃料组合物，其具有根据ASTM D1322测定的约18mm的烟雾点和通过ASTM D 3241测定的不超过25mm Hg的热稳定性，以及制备喷气燃料组合物的方法其中净燃烧热量由喷气燃料组合物中的芳族化合物含量，环烷烃含量和正常正或异链烷烃含量确定。

3. 发明授权

US06743962B2 Preparation of high octane alkylate from Fischer-Tropsch olefins 失效
标题翻译：从费 - 托烯烃制备高辛烷基烷基化物
公开(公告)号：US06743962B2
公开(公告)日：2004-06-01
申请号：US10059388
申请日：2002-01-31
申请人： Dennis J. O'Rear , Steven S. Mathur , Thomas Van Harris , Curtis L. Munson , Cong-Yan Chan
发明人： Dennis J. O'Rear , Steven S. Mathur , Thomas Van Harris , Curtis L. Munson , Cong-Yan Chan
IPC分类号： C07C256
CPC分类号： C07C9/16 , C07C2/58 , C07C2/62 , C07C2527/054 , C07C2527/1206 , C10G2/32 , Y02P30/20 , Y10S208/95
摘要： A Fischer-Tropsch C3-C4 olefin stream is treated to lower the oxygenate content to below 4000 ppm. Another Fischer-Tropsch fraction is hydrotreated and hydrocracked to provide an isobutane-containing stream. The treated C3-C4 olefin stream is reacted with the isobutane stream in an alkylation reactor to provide a highly branched, high octane isoparaffinic alkylate. The alkylate is useful as a blending component in motor gasoline.
摘要翻译：处理费托C3-C4烯烃流以将含氧化合物含量降低到低于4000ppm。将另一个费 - 托馏分加氢处理并加氢裂化以提供含异丁烷的物流。处理的C3-C4烯烃流在烷基化反应器中与异丁烷料流反应，得到高度支化的高辛烷值异链烷烃烷基化物。烷基化物可用作汽油汽油中的混合组分。

4. 发明授权

US06500233B1 Purification of p-xylene using composite mixed matrix membranes 失效
标题翻译：使用复合混合基质膜纯化对二甲苯
公开(公告)号：US06500233B1
公开(公告)日：2002-12-31
申请号：US09697196
申请日：2000-10-26
申请人： Stephen J. Miller , Curtis L. Munson , Sudhir S. Kulkarni , David J. Hasse
发明人： Stephen J. Miller , Curtis L. Munson , Sudhir S. Kulkarni , David J. Hasse
IPC分类号： B01D5322
CPC分类号： B01D61/362 , B01D53/228 , B01D61/246 , B01D69/08 , B01D69/12 , B01D69/141 , B01D69/147 , B01D69/148 , B01D71/028 , B01D71/10 , B01D71/56 , B01D2323/21 , C07C7/144 , C10G2400/30 , C07C15/08
摘要： Composite membranes capable of separating p-xylene from mixtures including p-xylene and m-xylene, and processes for purifying p-xylene using the membranes, are disclosed. The membranes are polymer membranes with a thickness of between about 10 and 1000 microns that include non-interconnected zeolite particles less than 5 microns. In one embodiment, a relatively thin polymer layer (0.5-3 microns) that includes zeolite particles is adjacent to a relatively thick polymer layer which may or may not include zeolite particles, where the thickness of the two layers is between about 10 and 1000 microns. The preferred ratio of zeolite/polymer is about 0.2 by weight. A preferred method for preparing the composite is by dispersing the zeolite in a polymer solution, casting a film of the polymer solution, and evaporating the solvent to form a polymeric film. The polymer permits passage of p-xylene and m-xylene in the vapor state, such that p-xylene diffuses at the same or a faster rate through the polymer. The polymer is preferably a polyaramide, polyimide or cellulose polymer p-Xylene and m-xylene diffuse through the zeolite, albeit at different rates. The zeolite is preferably an intermediate pore size zeolite, and more preferably, is silicalite or ZSM-5. The composite membrane is preferably in the form of a dense film or a hollow fiber. A mixture containing p-xylene and m-xylene can be enriched in p-xylene by a perstractive, pervaporative or gas-phase process through the membrane.
摘要翻译：公开了能够从包括对二甲苯和间二甲苯的混合物中分离对二甲苯的复合膜，以及使用该膜纯化对二甲苯的方法。膜是厚度在约10至1000微米之间的聚合物膜，其包括小于5微米的非互连沸石颗粒。在一个实施方案中，包括沸石颗粒的相对薄的聚合物层（0.5-3微米）邻近相对厚的聚合物层，其可以包括或可以不包括沸石颗粒，其中两层的厚度在约10和1000微米之间。沸石/聚合物的优选比例为约0.2重量％。制备复合材料的优选方法是通过将沸石分散在聚合物溶液中，浇铸聚合物溶液的膜，并蒸发溶剂以形成聚合物膜。聚合物允许在蒸气状态下通过对二甲苯和间二甲苯，使得对二甲苯以相同或更快的速率通过聚合物扩散。聚合物优选聚芳酰胺，聚酰亚胺或纤维素聚合物对二甲苯和间二甲苯通过沸石扩散，尽管以不同的速率。沸石优选为中等孔径沸石，更优选为硅沸石或ZSM-5。复合膜优选为致密膜或中空纤维的形式。含有对二甲苯和间二甲苯的混合物可以通过膜的渗透，蒸发或气相方法富集在对二甲苯中。

5. 发明授权

US06339182B1 Separation of olefins from paraffins using ionic liquid solutions 有权
标题翻译：使用离子液体溶液从石蜡中分离烯烃
公开(公告)号：US06339182B1
公开(公告)日：2002-01-15
申请号：US09735176
申请日：2000-12-12
申请人： Curtis L. Munson , Laura C. Boudreau , Michael S. Driver , William L. Schinski
发明人： Curtis L. Munson , Laura C. Boudreau , Michael S. Driver , William L. Schinski
IPC分类号： C07C700
CPC分类号： C10G70/002 , B01J2219/00047 , B01J2219/00306 , B01J2219/00599 , B01J2219/00702 , B01J2219/0072 , B01J2219/00759 , C07B63/00 , C07C1/0485 , C07C7/152 , C07C11/02 , C10G29/00 , C40B50/08 , C40B60/14 , G01N30/02 , Y02P30/42
摘要： Methods for separating olefins from non-olefins, such as parafins, including cycloparaffins, oxygenates and aromatics, are provided. The methods use metal salts to complex olefins, allowing the non-olefins to be separated by a variety of methods, including decantation and distillation. The metal salts are dissolved in ionic liquids, which tend to have virtually no vapor pressure, and which poorly solubilize the non-olefins. Accordingly, the non-olefins phase separate well, and can be distilled without carrying over any of the ionic liquid into the distillate. Preferred salts are Group IB salts, more preferably silver salts. A preferred silver salt is silver tetrafluoroborate. Preferred ionic liquids are those which form stable solutions or dispersions of the metal salts, and which do not dissolve the non-olefins. Further, if the olefins are subject to isomerization, the ionic liquid is preferably relatively non-acidic. The methods involve forming a solution of a suitable olefin-complexing salt in an appropriate ionic liquid. An olefin-containing mixture is contacted with the ionic liquid/salt solution, and the olefins are adsorbed. After the paraffins are removed, the olefins can be isolated by desorption. The olefin-containing mixture can be in the gas phase, or in the liquid phase. The flow of olefin-containing mixtures over/through the ionic liquid can be, for example, co-current, counter-current, or staged in stirred tanks. Countcrcurrent is preferred as it is the most efficient. The methods can be optimized using combinatorial chemistry.
摘要翻译：提供了从非烯烃分离烯烃的方法，如石蜡包括环烷烃，含氧化合物和芳族化合物。该方法使用金属盐来络合烯烃，允许通过各种方法分离非烯烃，包括倾析和蒸馏。金属盐溶解在离子液体中，其倾向于几乎不具有蒸气压，并且使非烯烃的溶解性差。因此，非烯烃相分离井，并且可以蒸馏而不将任何离子液体输送到馏出物中。优选的盐是IB族盐，更优选银盐。优选的银盐是四氟硼酸银。优选的离子液体是形成金属盐的稳定溶液或分散体并且不溶解非烯烃的离子液体。此外，如果烯烃经历异构化，离子液体优选是相对非酸性的。所述方法包括在合适的离子液体中形成合适的烯烃络合盐的溶液。使含烯烃的混合物与离子液体/盐溶液接触，并且吸附烯烃。在除去石蜡之后，可以通过解吸分离烯烃。含烯烃的混合物可以处于气相或液相中。通过离子液体的/通过离子液体的含烯烃混合物的流动可以是例如在搅拌釜中的并流，逆流或分段。 Countcrcurrent是首选，因为它是最有效的。该方法可以使用组合化学方法进行优化。

6. 发明授权

US09035113B2 High energy distillate fuel composition and method of making the same 有权
标题翻译：高能馏分燃料组成及其制作方法
公开(公告)号：US09035113B2
公开(公告)日：2015-05-19
申请号：US12582809
申请日：2009-10-21
申请人： Jaime Lopez , Janine Lichtenberger , William J. Cannella , Curtis L. Munson
发明人： Jaime Lopez , Janine Lichtenberger , William J. Cannella , Curtis L. Munson
IPC分类号： C10L1/04 , C10G65/12 , C10G45/44 , C10G47/00
CPC分类号： C10G65/12 , C10G45/44 , C10G47/00 , C10G2300/1048 , C10G2300/30 , C10G2400/08 , C10L1/04
摘要： The disclosure describes a high energy density jet fuel composition, having a smoke point about 18 mm as determined by ASTM D1322 and a thermal stability of no more than 25 mm Hg as determined by ASTM D 3241, and a method for making a jet fuel composition, wherein the net heat of combustion is determined by the aromatics content, cycloparaffins content, and normal plus or iso paraffins content in the jet fuel composition.
摘要翻译：本公开描述了一种高能量密度的喷气燃料组合物，其具有根据ASTM D1322测定的约18mm的烟雾点和通过ASTM D 3241测定的不超过25mm Hg的热稳定性，以及制备喷气燃料组合物的方法其中净燃烧热量由喷气燃料组合物中的芳族化合物含量，环烷烃含量和正常正或异链烷烃含量确定。

7. 发明授权

US06623659B2 Separation of olefins from paraffins using ionic liquid solutions 有权
公开(公告)号：US06623659B2
公开(公告)日：2003-09-23
申请号：US09998138
申请日：2001-12-03
申请人： Curtis L. Munson , Laura C. Boudreau , Michael S. Driver , William L. Schinski
发明人： Curtis L. Munson , Laura C. Boudreau , Michael S. Driver , William L. Schinski
IPC分类号： C09K300
CPC分类号： C10G70/002 , B01J2219/00047 , B01J2219/00306 , B01J2219/00599 , B01J2219/00702 , B01J2219/0072 , B01J2219/00759 , C07B63/00 , C07C1/0485 , C07C7/152 , C07C11/02 , C10G29/00 , C40B50/08 , C40B60/14 , G01N30/02 , Y02P30/42
摘要： Methods for separating olefins from non-olefins, such as paraffins, including cycloparaffins, oxygenates and aromatics, are provided. The methods use metal salts to complex olefins, allowing the non-olefins to be separated by a variety of methods, including decantation and distillation. The metal salts are dissolved in ionic liquids, which tend to have virtually no vapor pressure, and which poorly solubilize the non-olefins. Accordingly, the non-olefins phase separate well, and can be distilled without carrying over any of the ionic liquid into the distillate. Preferred salts are Group IB salts, more preferably silver salts. A preferred silver salt is silver tetrafluoroborate. Preferred ionic liquids are those which form stable solutions or dispersions of the metal salts, and which do not dissolve the non-olefins. Further, if the olefins are subject to isomerization, the ionic liquid is preferably relatively non-acidic. The methods involve forming a solution of a suitable olefin-complexing salt in an appropriate ionic liquid. An olefin-containing mixture is contacted with the ionic liquid/salt solution, and the olefins are adsorbed. After the paraffins are removed, the olefins can be isolated by desorption. The olefin-containing mixture can be in the gas phase, or in the liquid phase. The flow of olefin-containing mixtures over/through the ionic liquid can be, for example, co-current, counter-current, or staged in stirred tanks. Countercurrent is preferred as it is the most efficient. The methods can be optimized using combinatorial chemistry.

8. 发明授权

US06454836B1 Method and apparatus for wellbore gas separation 失效
标题翻译：井筒气体分离方法和装置
公开(公告)号：US06454836B1
公开(公告)日：2002-09-24
申请号：US09721156
申请日：2000-11-21
申请人： Mark H. Koelmel , Stephen Miller , Curtis L. Munson , David R. Underdown , Rick A. Wright , Jean P. Camy , Steve E. Ross , Peter C. Schmidt
发明人： Mark H. Koelmel , Stephen Miller , Curtis L. Munson , David R. Underdown , Rick A. Wright , Jean P. Camy , Steve E. Ross , Peter C. Schmidt
IPC分类号： B01D5322
CPC分类号： E21B43/38 , E21B43/385
摘要： A downhole preferential hydrocarbon gas recovery system and method employ preferentially selective materials to separate the hydrocarbon gas from contaminants. According to one aspect of the invention, the preferentially selective materials are arranged in tubes with the hydrocarbon gas flowing through the tubes and the contaminants permeating out through the preferentially selective material.
摘要翻译：井下优先烃气回收系统和方法优选使用选择性材料将烃气体与污染物分离。根据本发明的一个方面，优先选择性材料被布置在管中，烃类气体流过管，污染物通过优先选择性材料渗出。

9. 发明授权

US06215037B1 Method for selective adsorption of dienes 有权
标题翻译：二烯选择性吸附方法
公开(公告)号：US06215037B1
公开(公告)日：2001-04-10
申请号：US09179667
申请日：1998-10-27
申请人： Joel Padin , Curtis L. Munson , Ralph T. Yang
发明人： Joel Padin , Curtis L. Munson , Ralph T. Yang
IPC分类号： C07C700
CPC分类号： C07C7/13
摘要： The invention provides specific adsorbents and methods for separating an unsaturated hydrocarbon from a mixture containing such hydrocarbon. The adsorbents and methods are useful for separating dienes from mono-olefins.
摘要翻译：本发明提供了特定的吸附剂和从含有这种烃的混合物中分离不饱和烃的方法。吸附剂和方法可用于从单烯烃中分离二烯。

10. 发明授权

US6057487A Method for producing 2,6-DMN from mixed dimethylnaphthalenes by crystallization, adsorption and isomerization 失效
标题翻译：通过结晶，吸附和异构化由混合二甲基萘生产2,6-DMN的方法
公开(公告)号：US6057487A
公开(公告)日：2000-05-02
申请号：US858
申请日：1997-12-30
申请人： Curtis L. Munson , Patrick C. Bigot , Zunqing Alice He
发明人： Curtis L. Munson , Patrick C. Bigot , Zunqing Alice He
IPC分类号： C07B61/00 , C07C5/373 , C07C7/12 , C07C7/13 , C07C7/14 , C07C15/24 , C07C5/22
CPC分类号： C07C15/24 , C07C7/13 , C07C7/14 , C07C2521/04 , C07C2523/04 , C07C2523/14 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/755
摘要： A method is disclosed to produce 2,6-dimethylnaphthalene (2,6-DMN), used for the production of polyethylene naphthalate, at high purity and high yield from a mixture of dimethylnaphthalene isomers without limitation to the specific isomers present in the feed by a series of fractionation, crystallization and adsorption steps.
摘要翻译：公开了以二甲基萘异构体的混合物制备用于生产聚萘二甲酸乙二醇酯的高纯度和高收率的2,6-二甲基萘（2,6-DMN）的方法，但不限于进料中存在的特定异构体一系列分馏，结晶和吸附步骤。

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