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    • 1. 发明授权
    • Fractionation of polymers
    • 聚合物的分级
    • US4429113A
    • 1984-01-31
    • US229032
    • 1981-01-26
    • Stephen H. WuClarence C. Dannelly
    • Stephen H. WuClarence C. Dannelly
    • C08F6/04C08F6/00
    • C08F6/04
    • Process of obtaining a high molecular weight fraction from a polar polymer which comprises the steps of first, forming a solution of the polar polymer in a solvent which is also a solvent for a selected coacervating substance, then mixing with the solution a coacervating substance having at least two proton donating or proton receiving groups which are opposite the polarity of the polar polymer in an amount sufficient to crosslink molecules of said polar polymer of a molecular weight above a selected range at the solution temperature, thereby forming coacervated high molecular weight polymer solids, and then separating the high molecular weight solids from the solution. The coacervated polymer may then be dissolved and the coacervating substance removed by precipitation.
    • 从极性聚合物获得高分子量级分的方法,该方法包括以下步骤:首先在极性聚合物溶液中形成溶剂,该溶剂也是选择的凝聚物质的溶剂,然后与溶液混合, 至少两个质子供体或质子接受基团,其极性与极性聚合物极性相反,其量足以使分子量分子的分子在溶液温度下高于所选范围,从而形成凝聚的高分子量聚合物固体, 然后从溶液中分离高分子量固体。 然后可以将凝聚的聚合物溶解,并通过沉淀除去凝聚物质。
    • 2. 发明授权
    • Fractionation of polymers
    • 聚合物的分级
    • US4518769A
    • 1985-05-21
    • US543677
    • 1983-10-20
    • Stephen H. WuClarence C. Dannelly
    • Stephen H. WuClarence C. Dannelly
    • C08F6/04
    • C08F6/04
    • Process of obtaining a high molecular weight fraction from a polar polymer which comprises the steps of first, forming a solution of the polar polymer in a solvent which is also a solvent for a selected coacervating substance, then mixing with the solution a coacervating substance having at least two proton donating or proton receiving groups which are opposite the polarity of the polar polymer in an amount sufficient to crosslink molecules of said polar polymer of a molecular weight above a selected range at the solution temperature, thereby forming coacervated high molecular weight polymer solids, and then separating the high molecular weight solids from the solution. The coacervated polymer may then be dissolved and the coacervating substance removed by precipitation.
    • 从极性聚合物获得高分子量级分的方法,该方法包括以下步骤:首先在极性聚合物溶液中形成溶剂,该溶剂也是选择的凝聚物质的溶剂,然后与溶液混合, 至少两个质子供体或质子接受基团,其极性与极性聚合物极性相反,其量足以使分子量分子的分子在溶液温度下高于所选范围,从而形成凝聚的高分子量聚合物固体, 然后从溶液中分离高分子量固体。 然后可以将凝聚的聚合物溶解,并通过沉淀除去凝聚物质。
    • 3. 发明授权
    • Seed coatings
    • 种子包衣
    • US4249343A
    • 1981-02-10
    • US60547
    • 1979-07-25
    • Clarence C. Dannelly
    • Clarence C. Dannelly
    • A01C1/06A23B9/14
    • A23B9/14A01C1/06
    • Compositions are disclosed comprising a water insoluble microgel which when used as a coating for seeds provides protection for the seeds and may be used as a carrier for materials such as fertilizers, herbicides, pesticides, etc. The microgel does not dissolve when contacted with water, but the outer layer of the microgel swells and falls away, thereby dissrupting the coating, and continues until the coating is removed. An advantage of such a coating is that there is no dissolved material available to fill the pores of the seeds to thereby retard germination. The coating quickly disintegrates upon contact with water for releasing any carried substances and exposing the seeds to their natural environment.
    • 公开了包含水不溶性微凝胶的组合物,当用作种子的包衣时,为种子提供保护,并且可以用作诸如肥料,除草剂,农药等的材料的载体。当与水接触时,微凝胶不溶解, 但是微凝胶的外层膨胀并掉落,从而破坏涂层,并持续直到涂层被去除。 这种涂层的优点是没有可用于填充种子孔的溶解材料,从而延缓发芽。 与水接触时,涂层迅速崩解,以释放任何携带的物质,并将种子暴露于自然环境中。
    • 4. 发明授权
    • Encapsulating method
    • 封装方法
    • US4218409A
    • 1980-08-19
    • US934118
    • 1978-08-16
    • Clarence C. Dannelly
    • Clarence C. Dannelly
    • A61J3/07A61K9/50
    • A61J3/07A61K9/50
    • Method is disclosed for forming encapsulated material. Centrifugal force developed by a rotating nozzle having a plurality of radial orifices is used for extruding material to be encapsulated. The nozzle is mounted for rotation about a generally vertical axis and is provided with a circumferential outside surface near its bottom inclined upwardly away from the axis of the nozzle which, when partially submerged in a liquid during rotation, impels a sheet or spray of the liquid along the circumferential surface and shears off successive leading tips of extruded material to form capsules.
    • 公开了形成包封材料的方法。 由具有多个径向孔的旋转喷嘴产生的离心力用于挤出被包封的材料。 喷嘴安装成围绕大致垂直的轴线旋转,并且在其底部附近设置有周向外表面,其向上倾斜向上远离喷嘴的轴线,当旋转期间部分地浸没在液体中时,推动液体的片材或喷雾 沿着圆周表面剪切挤压材料的连续前端以形成胶囊。
    • 9. 发明授权
    • Encapsulating apparatus
    • 封装机
    • US4123206A
    • 1978-10-31
    • US766294
    • 1977-02-07
    • Clarence C. Dannelly
    • Clarence C. Dannelly
    • A61J3/07A61K9/50B29C13/00
    • A61K9/50A61J3/07
    • Apparatus and method are disclosed for forming encapsulated material. Centrifugal force developed by a rotating nozzle having a plurality of radial orifices is used for extruding material to be encapsulated. The nozzle is mounted for rotation about a generally vertical axis and is provided with a circumferential outside surface near its bottom inclined upwardly away from the axis of the nozzle which, when partially submerged in a liquid during rotation, impels a sheet or spray of the liquid along the circumferential surface and shears off successive leading tips of extruded material to form capsules.
    • 公开了用于形成包封材料的装置和方法。 由具有多个径向孔的旋转喷嘴产生的离心力用于挤出被包封的材料。 喷嘴安装成围绕大致垂直的轴线旋转,并且在其底部附近设置有周向外表面,其向上倾斜向上远离喷嘴的轴线,当旋转期间部分地浸没在液体中时,推动液体的片材或喷雾 沿着圆周表面剪切挤压材料的连续前端以形成胶囊。
    • 10. 发明授权
    • Seed coatings
    • 种子包衣
    • US4245432A
    • 1981-01-20
    • US60546
    • 1979-07-25
    • Clarence C. Dannelly
    • Clarence C. Dannelly
    • A01C1/06A01N25/10B01J2/00
    • B01J2/006A01C1/06A01N25/10
    • Disclosed are plant seed coating compositions comprising water insoluble but water sensitive polyelectrolyte complexes. The polyelectrolyte complexes, which are formed by combining an acidic polymer with a basic polymer, provide protection for the seeds and may be used as a carrier for materials such as fertilizers, herbicides, pesticides, etc. An important feature is the fact that the polyelectrolyte complex does not dissolve when contacted with water. Instead, it swells and falls away, thereby disrupting the coating, and the swelling and falling away continue until the coating is removed. An advantage of such a coating is that there is no dissolved material available to fill the pores of the seeds to thereby retard germination. The coating quickly disintegrates upon contact with water for releasing any carried substances and exposes the seeds to their natural environment.
    • 公开了包含水不溶但是水敏聚合电解质复合物的植物种子包衣组合物。 通过将酸性聚合物与碱性聚合物结合形成的聚电解质配合物为种子提供保护,并且可以用作诸如肥料,除草剂,农药等的材料的载体。一个重要的特征是聚电解质 当与水接触时,复合物不溶解。 相反,它会膨胀和掉落,从而破坏涂层,并且持续的膨胀和掉落直到涂层被去除。 这种涂层的优点是没有可用于填充种子孔的溶解材料,从而延缓发芽。 与水接触时,涂层迅速崩解,以释放任何携带的物质,并将种子暴露于自然环境中。