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1. 发明授权

US06348604B1 Photochromic naphthopyrans 有权
标题翻译：光致变色萘并吡喃
公开(公告)号：US06348604B1
公开(公告)日：2002-02-19
申请号：US09656509
申请日：2000-09-06
申请人： Clara M. Nelson , Anu Chopra , David B. Knowles , Barry Van Gemert , Anil Kumar
发明人： Clara M. Nelson , Anu Chopra , David B. Knowles , Barry Van Gemert , Anil Kumar
IPC分类号： G02B523
CPC分类号： C07D311/92 , C07D493/04 , G02B5/23
摘要： Described are novel photochromic 2H-naphtho[1,2-b]pyran compounds essentially characterized by having two adjacent moderate to strong electron donor substituents at the 8 and 9 positions or a fused heterocyclic group formed by the substituents coming together, weak to moderate electron donors at the 2 position and a rating of at least 80 in the Relative &Dgr;OD at Saturation Test. The compounds also have certain substituents at the 5 position and optionally at the 6 position of the naphtho portion of the compound. These compounds may be represented by the following graphic formula: Also described are polymeric organic host materials that contain or that are coated with such compounds. Optically clear articles such as ophthalmic lenses or adjacent plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., certain other naphthopyrans, benzopyrans, and spiro(indoline)type compounds, are also described.
摘要翻译：描述了新颖的光致变色2H-萘并[1,2-b]吡喃化合物，其基本上特征在于在8和9位具有两个相邻的中等至强电子给体取代基或由取代基组成的稠合杂环基团，弱至中等电子捐助者在2位置，并且在饱和度测试的相对DELTAOD中评级至少为80。化合物在化合物的萘酚部分的5位和任选地位置上也具有某些取代基。这些化合物可以由以下图解表示：还描述了含有这些化合物或被这些化合物包被的聚合物有机主体材料。还描述了光学透明的物品，例如将眼用透镜或相邻的塑料透明胶片结合到新的萘并吡喃化合物或其组合与互补光致变色化合物，例如某些其它萘并吡喃，苯并吡喃和螺（二氢吲哚）型化合物。

2. 发明授权

US06296785B1 Indeno-fused photochromic naphthopyrans 有权
标题翻译：印度融合的光致变色萘并吡喃
公开(公告)号：US06296785B1
公开(公告)日：2001-10-02
申请号：US09656510
申请日：2000-09-06
申请人： Clara M. Nelson , Anu Chopra , Olga G. Petrovskaia , David B. Knowles , Barry Van Gemert , Anil Kumar
发明人： Clara M. Nelson , Anu Chopra , Olga G. Petrovskaia , David B. Knowles , Barry Van Gemert , Anil Kumar
IPC分类号： C07D31178
CPC分类号： C07D311/94 , C07D311/96 , G02B5/23
摘要： Described are novel photochromic indeno-fused naphthopyran compounds, examples of which include naphthopyran compounds having a substituted or unsubstituted indeno group, the 2,1 positions of which are fused to the naphtho portion of the naphthopyran as shown below. Also present on the naphthopyran are moderate to strong electron donor substituents at the number 6- and 7-positions and optionally at the 8-position of the pyran ring or a cyclic group fused to the h side of the naphtho portion and weak to moderate electron donor substiuents at the 3-position of the pyran ring. Certain substituents may also be present at the number 5, 8, 9, 10, 11, 12, or 13 carbon atoms of the compounds. These compounds have a rating of at least 80 in the Relative &Dgr;OD at Saturation Test and may be represented by the following graphic formula: Also described are polymeric organic host materials that contain or that are coated with such compounds. Optically clear articles such as ophthalmic lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., certain other naphthopyrans, benzopyrans, and spiro(indoline)type compounds, are also described.
摘要翻译：描述了新的光致变色茚并稠合萘并吡喃化合物，其实例包括具有取代或未取代的茚并基团的萘并吡喃化合物，其2,1个位置与萘并吡喃的萘酚部分稠合，如下所示。还存在于萘并吡喃上的是中子至强电子给体取代基，位于吡喃环的6-位和7-位，任选在8-位或稠合于萘酚部分的h侧的环状基团，弱至中等电子在吡喃环3位的供体位。某些取代基也可以存在于化合物的5,8,9,10,11,12或13个碳原子上。这些化合物在饱和度测试中的相对DELTAOD中的等级至少为80，并且可以由以下图形表示：还描述了含有或涂覆有这些化合物的聚合物有机主体材料。还描述了光学透明的物品，例如将眼用透镜或其它塑料透明胶片掺入新的萘并吡喃化合物或其组合与互补的光致变色化合物，例如某些其它萘并吡喃，苯并吡喃和螺（二氢吲哚）型化合物。

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