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1. 发明申请

US20060082288A1 Light emitting devices with mixed phosphors 审中-公开
标题翻译：具有混合荧光体的发光器件
公开(公告)号：US20060082288A1
公开(公告)日：2006-04-20
申请号：US11264365
申请日：2005-11-01
申请人： Hisham Menkara , Christopher Summers , Brent Wagner
发明人： Hisham Menkara , Christopher Summers , Brent Wagner
IPC分类号： H01L33/00
CPC分类号： C09K11/7718 , C09K11/7731 , C09K11/886 , H01L33/502 , H01L33/504 , H05B33/14
摘要： The invention provides compositions, which are mixtures of phosphors. The compositions comprise a first component described by the formula: M1SxSey:B1 and a second component that comprises a material described by the formula M2Am(SpSeq)n:B2, in which: M1 and M2 may be any metal species and B1 and B2 may be any activator, typically a metal species, with the remaining variables representing effective numerical values necessary for conferring electrical neutrality to the compositions. A phosphor mixture according to the invention is produced by first preparing individual components, and then physically mixing the components, as in a mortar or ball mill.
摘要翻译：本发明提供了作为磷光体混合物的组合物。所述组合物包含由下式表示的第一组分：M1S Se y：：：：：：：：：：：：：：：：：/ / / / / / / / / / / / B2，其中：M1和M2可以是任何金属物质，B1和B2可以是任何活化剂，通常为金属物质，其余变量表示赋予组合物电中性所必需的有效数值。根据本发明的荧光体混合物通过首先制备各个组分，然后物理地混合组分，如在研钵或球磨机中制备。

2. 发明申请

US20050023962A1 Light emitting device having sulfoselenide fluorescent phosphor 失效
标题翻译：具有磺基硒化物荧光荧光体的发光器件
公开(公告)号：US20050023962A1
公开(公告)日：2005-02-03
申请号：US10661931
申请日：2003-09-15
申请人： Hisham Menkara , Christopher Summers
发明人： Hisham Menkara , Christopher Summers
IPC分类号： C09K20060101 , C09K11/88 , H01J1/62 , H01J63/04 , H01L33/50 , H05B33/00
CPC分类号： C09K11/885 , C09K11/886 , H01L33/502 , Y02B20/181
摘要： Provided herein are novel phosphors useful in the manufacture of white light emitting diodes. The phosphors provided by the invention are described by the formula: described by the formula: ZnSxSey:Cu,A in which x and y are each independently any value between 0 and about 1, subject to the proviso that the sum of x and y is equal to any number in the range of between about 0.75 and about 1.25; wherein A is optional and comprises at least one additional element selected from the group consisting of: Ag, Al, Ce, Tb, Cl, I, Mg, and Mn, including mixtures thereof, and wherein Cu is present in any amount between about 0.0001% and about 5% in mole percent based on the total molar weight of said composition. Standard techniques used in phosphor deposition for the manufacture of light emitting diodes which comprise phosphors may be employed to produce LED's having a white light output when the phosphors of the invention are utilized.
摘要翻译：本文提供了可用于制造白色发光二极管的新型荧光体。由本发明提供的荧光体由下式描述：ZnSxSey：Cu，A，其中x和y各自独立地为0和约1之间的任何值，条件是x和y之和为等于约0.75至约1.25范围内的任何数字; 其中A是任选的，并且包含至少一种选自Ag，Al，Ce，Tb，Cl，I，Mg和Mn的另外的元素，包括其混合物，其中Cu以约0.0001 ％和约5％（摩尔），基于所述组合物的总摩尔量。当利用本发明的荧光体时，用于制造包含磷光体的发光二极管的荧光体沉积中使用的标准技术可用于产生具有白光输出的LED。

3. 发明申请

US20050023546A1 Light emitting device having selenium-based fluorescent phosphor 失效
标题翻译：具有硒系荧光体的发光元件
公开(公告)号：US20050023546A1
公开(公告)日：2005-02-03
申请号：US10801067
申请日：2004-03-15
申请人： Hisham Menkara , Christopher Summers , Brent Wagner
发明人： Hisham Menkara , Christopher Summers , Brent Wagner
IPC分类号： C09K20060101 , C09K11/88 , H01J1/62 , H01J63/04 , H01L33/50 , H05B33/00 , H01L33/00
CPC分类号： C09K11/885 , C09K11/886 , H01L33/502 , Y02B20/181
摘要： Provided herein are novel phosphors useful in the manufacture of white light emitting diodes. The phosphors provided by the invention are described by the formulae: MSxSey: Bin which x, and y are each independently any value between about 0 and about 1, subject to the proviso that the sum of x and y is equal to any number in the range of between about 0.75 and about 1.25; M is at least one of Be, Mg, Ca, Sr, Ba, Zn, excepting Zn alone; and wherein the activator(s) B comprises one or more elements selected from the group consisting of: Eu, Ce, Cu, Ag, Al, Tb, Sb, Bi, K, Na, Cl, F, Br, I, Mg, Pr, and Mn, including mixtures comprising any two, any three, any four, any five, any six, any seven, or more of these elements in any proportion, and wherein the elements in these mixtures may each independently be present in any amount between 0.0001% and about 10% in mole percent based on the total molar weight of said composition. Standard techniques used in conventional phosphor deposition for the manufacture of light emitting diodes which comprise phosphors according to the invention may be employed to produce LED's having a white light output.
摘要翻译：本文提供了可用于制造白色发光二极管的新型荧光体。由本发明提供的荧光体由下式描述：MSxSey：B，其中x和y各自独立地为约0和约1之间的任何值，条件是x和y之和等于在约0.75和约1.25之间的范围; M除Be之外还有Be，Mg，Ca，Sr，Ba，Zn中的至少一种; 并且其中所述活化剂B包含一种或多种选自Eu，Ce，Cu，Ag，Al，Tb，Sb，Bi，K，Na，Cl，F，Br，I，Mg， Pr和Mn，包括任何比例包含任何两种，任何三种，任何四种，任何五种，六种，任何七种或更多种这些元素的混合物，并且其中这些混合物中的元素可以各自独立地以任何量存在基于所述组合物的总摩尔量，0.0001％至约10％（摩尔）。用于制造包含根据本发明的磷光体的发光二极管的常规磷光体沉积中的标准技术可用于产生具有白光输出的LED。

4. 发明授权

US06987353B2 Light emitting device having sulfoselenide fluorescent phosphor 失效
标题翻译：具有磺基硒化物荧光荧光体的发光器件
公开(公告)号：US06987353B2
公开(公告)日：2006-01-17
申请号：US10661931
申请日：2003-09-15
申请人： Hisham Menkara , Christopher Summers
发明人： Hisham Menkara , Christopher Summers
IPC分类号： H01B33/20
CPC分类号： C09K11/885 , C09K11/886 , H01L33/502 , Y02B20/181
摘要： Provided herein are novel phosphors useful in the manufacture of white light emitting diodes. The phosphors provided by the invention are described by the formula: described by the formula: ZnSxSey:Cu,A in which x and y are each independently any value between 0 and about 1, subject to the proviso that the sum of x and y is equal to any number in the range of between about 0.75 and about 1.25; wherein A is optional and comprises at least one additional element selected from the group consisting of: Ag, Al, Ce, Tb, Cl, I, Mg, and Mn, including mixtures thereof, and wherein Cu is present in any amount between about 0.0001% and about 5% in mole percent based on the total molar weight of said composition. Standard techniques used in phosphor deposition for the manufacture of light emitting diodes which comprise phosphors may be employed to produce LED's having a white light output when the phosphors of the invention are utilized.
摘要翻译：本文提供了可用于制造白色发光二极管的新型荧光体。由本发明提供的荧光体由下式描述：由下式描述：<？in-line-formula description =“In-line Formulas”end =“lead”？> ZnS x Se < Cu，A <？in-line-formula description =“In-line Formulas”end =“tail”？>其中x和y各自独立地为0和1之间的任何值，对象条件是x和y之和等于约0.75至约1.25范围内的任何数字; 其中A是任选的，并且包含至少一种选自Ag，Al，Ce，Tb，Cl，I，Mg和Mn的另外的元素，包括其混合物，并且其中Cu以约0.0001 ％和约5％（摩尔），基于所述组合物的总摩尔量。当利用本发明的荧光体时，用于制造包含磷光体的发光二极管的荧光体沉积中使用的标准技术可用于产生具有白光输出的LED。

5. 发明申请

US20050156510A1 Device and method for emitting output light using group IIB element selenide-based and group IIA element gallium sulfide-based phosphor materials 审中-公开
标题翻译：使用IIB族元素硒化物基和IIA族元素硫化镓基荧光体材料发射输出光的装置和方法
公开(公告)号：US20050156510A1
公开(公告)日：2005-07-21
申请号：US10761763
申请日：2004-01-21
申请人： Janet Chua , Azlida Ahmad , Hwai Choo , Hisham Menkara , Christopher Summers
发明人： Janet Chua , Azlida Ahmad , Hwai Choo , Hisham Menkara , Christopher Summers
IPC分类号： C09K11/08 , C09K11/00 , C09K11/62 , C09K11/77 , C09K11/88 , H01J61/44 , H01L33/50 , H05B33/00 , H05B33/02 , H05B33/04 , H05B33/10
CPC分类号： C09K11/7731 , C09K11/883 , H01L33/502 , H01L33/507 , H01L2224/48091 , H01L2224/8592 , H01L2924/181 , Y02B20/181 , H01L2924/00014 , H01L2924/00012
摘要： A device and method for emitting output light utilizes a mixture of Group IIB element Selenide-based phosphor material and Group IIA element Gallium Sulfide-based phosphor material in which the Group IIA element includes Calcium, Strontium and/or Barium to convert some of the original light emitted from a light source of the device to longer wavelength light to change the optical spectrum the output light. Thus, the device and method can be used to produce white color light. The mixture of Group IIB element Selenide-based and Group IIA element Gallium Sulfide-based phosphor materials is included in a wavelength-shifting region optically coupled to the light source, which may be a blue light emitting diode (LED) die.
摘要翻译：用于发射输出光的装置和方法利用基于IIB族元素硒化物基荧光体材料和IIA族元素硫化镓基荧光体材料的混合物，其中IIA族元素包括钙，锶和/或钡，以将一些原始光从设备的光源发射到较长波长的光，以改变光谱的输出光。因此，可以使用该装置和方法来产生白色光。 IIB族元素硒化物基和IIA族元素硫化镓基荧光体材料的混合物包括在光学耦合到可以是蓝色发光二极管（LED）裸片的光源的波长移动区域中。

6. 发明申请

US20050023963A1 Light emitting device having thio-selenide fluorescent phosphor 失效
标题翻译：具有硫代硒化物荧光荧光体的发光器件
公开(公告)号：US20050023963A1
公开(公告)日：2005-02-03
申请号：US10801082
申请日：2004-03-15
申请人： Hisham Menkara , Christopher Summers , Brent Wagner
发明人： Hisham Menkara , Christopher Summers , Brent Wagner
IPC分类号： C09K20060101 , C09K11/88 , H01J1/62 , H01J63/04 , H01L33/50 , H05B33/00
CPC分类号： C09K11/885 , C09K11/886 , H01L33/502 , Y02B20/181
摘要： Provided herein are novel phosphors useful in the manufacture of white light emitting diodes. The phosphors provided by the invention are described by the formulae: MA2(SxSey)4:Band/or M2A4(SxSey)7:Bin which x, and y are each independently any value between 0 and 1, including 0 and 1 subject to the proviso that the sum of x and y is equal to any number in the range of between about 0.75 and about 1.25; M is at least one of Be, Mg, Ca, Sr, Ba, Zn; A is at least one of Al, Ga, In, Y, La, and Gd; and wherein the activator(s), B, comprises one or more element selected from the group consisting of: Eu, Ce, Cu, Ag, Al, Tb, Cl, Br, F, I, Mg, Pr, K, Na, and Mn, including mixtures comprising any two, any three, any four, any five, any six, any seven, or more of these elements in any proportion, and wherein the elements in these mixtures may each independently be present in any amount between 0.0001% and about 10% in mole percent based on the total molar weight of said composition. Standard techniques used in phosphor deposition for the manufacture of light emitting diodes which comprise phosphors may be employed to produce LED's having a white light output when the phosphors of the invention are utilized.
摘要翻译：本文提供了可用于制造白色发光二极管的新型荧光体。由本发明提供的荧光体由下式描述：MA2（SxSey）4：B和/或M2A4（SxSey）7：B，其中x和y各自独立地为0和1之间的任何值，包括0和1个受试者条件是x和y之和等于约0.75至约1.25范围内的任何数字; M是Be，Mg，Ca，Sr，Ba，Zn中的至少一种; A是Al，Ga，In，Y，La和Gd中的至少一种; 并且其中所述活化剂B包含一种或多种选自Eu，Ce，Cu，Ag，Al，Tb，Cl，Br，F，I，Mg，Pr，K，Na，和Mn，包括任何比例包含任何两种，任何三种，任何四种，任何五种，六种，任何七种或更多种这些元素的混合物，并且其中这些混合物中的元素可以各自独立地以0.0001 ％和约10％（摩尔），基于所述组合物的总摩尔量。当利用本发明的荧光体时，用于制造包含磷光体的发光二极管的荧光体沉积中使用的标准技术可用于产生具有白光输出的LED。

7. 发明申请

US20050224779A1 Large scale patterned growth of aligned one-dimensional nanostructures 有权
标题翻译：对齐的一维纳米结构的大规模图案生长
公开(公告)号：US20050224779A1
公开(公告)日：2005-10-13
申请号：US11010178
申请日：2004-12-10
申请人： Zhong Wang , Christopher Summers , Xudong Wang , Elton Graugnard , Jeffrey King
发明人： Zhong Wang , Christopher Summers , Xudong Wang , Elton Graugnard , Jeffrey King
IPC分类号： G02B5/20 , H01J1/304 , H01J9/02 , H01L29/06 , H01L29/22
CPC分类号： B82Y30/00 , B82Y10/00 , G02B5/206 , H01J1/304 , H01J9/025 , H01L29/0665 , H01L29/0673 , H01L29/0676 , H01L29/22 , Y10S977/712 , Y10S977/811 , Y10S977/938
摘要： A method of making nanostructures using a self-assembled monolayer of organic spheres is disclosed. The nanostructures include bowl-shaped structures and patterned elongated nanostructures. A bowl-shaped nanostructure with a nanorod grown from a conductive substrate through the bowl-shaped nanostructure may be configured as a field emitter or a vertical field effect transistor. A method of separating nanoparticles of a desired size employs an array of bowl-shaped structures.
摘要翻译：公开了使用有机球的自组装单层制备纳米结构的方法。纳米结构包括碗形结构和图案化的细长纳米结构。具有通过碗形纳米结构从导电基底生长的纳米棒的碗状纳米结构可以被配置为场致发射体或垂直场效应晶体管。分离所需尺寸的纳米颗粒的方法采用碗形结构阵列。

8. 发明授权

US07112921B2 Light emitting device having selenium-based fluorescent phosphor 失效
标题翻译：具有硒系荧光体的发光元件
公开(公告)号：US07112921B2
公开(公告)日：2006-09-26
申请号：US10801067
申请日：2004-03-15
申请人： Hisham Menkara , Christopher Summers , Brent K. Wagner
发明人： Hisham Menkara , Christopher Summers , Brent K. Wagner
IPC分类号： H05B33/14 , C09K11/56
CPC分类号： C09K11/885 , C09K11/886 , H01L33/502 , Y02B20/181
摘要： Provided herein are novel phosphors useful in the manufacture of white light emitting diodes. The phosphors provided by the invention are described by the formulae: MSxSey: B in which x, and y are each independently any value between about 0 and about 1, subject to the proviso that the sum of x and y is equal to any number in the range of between about 0.75 and about 1.25; M is at least one of Be, Mg, Ca, Sr, Ba, Zn, excepting Zn alone; and wherein the activator(s) B comprises one or more elements selected from the group consisting of: Eu, Ce, Cu, Ag, Al, Tb, Sb, Bi, K, Na, Cl, F, Br, I, Mg, Pr, and Mn, including mixtures comprising any two, any three, any four, any five, any six, any seven, or more of these elements in any proportion, and wherein the elements in these mixtures may each independently be present in any amount between 0.0001% and about 10% in mole percent based on the total molar weight of said composition. Standard techniques used in conventional phosphor deposition for the manufacture of light emitting diodes which comprise phosphors according to the invention may be employed to produce LED's having a white light output.
摘要翻译：本文提供了可用于制造白色发光二极管的新型荧光体。由本发明提供的荧光体由下式描述：<？in-line-formula description =“In-line Formulas”end =“lead”？> MS Se SUB>：B <？in-line-formula description =“In-line Formulas”end =“tail”？>其中x和y各自独立为约0至约1之间的任何值，但条件是 x和y的和等于约0.75至约1.25范围内的任何数字; M除Be之外还有Be，Mg，Ca，Sr，Ba，Zn中的至少一种; 并且其中所述活化剂B包含一种或多种选自Eu，Ce，Cu，Ag，Al，Tb，Sb，Bi，K，Na，Cl，F，Br，I，Mg， Pr和Mn，包括任何比例包含任何两种，任何三种，任何四种，任何五种，六种，任何七种或更多种这些元素的混合物，并且其中这些混合物中的元素可以各自独立地以任何量存在基于所述组合物的总摩尔量，0.0001％至约10％（摩尔）。用于制造包含根据本发明的磷光体的发光二极管的常规磷光体沉积中的标准技术可用于产生具有白光输出的LED。

9. 发明授权

US06982045B2 Light emitting device having silicate fluorescent phosphor 失效
标题翻译：具有硅酸盐荧光荧光体的发光器件
公开(公告)号：US06982045B2
公开(公告)日：2006-01-03
申请号：US10628115
申请日：2003-07-28
申请人： Hisham Menkara , Christopher Summers
发明人： Hisham Menkara , Christopher Summers
IPC分类号： C09K11/59
CPC分类号： C09K11/7734 , Y02B20/181
摘要： Provided herein are novel phosphors useful in the manufacture of white light emitting diodes. The phosphors provided by the invention are described by the formula: SrxBayCazSiO4:Eu in which x, y, and z are each independently variable to be any value between about 0 and about 2, including without limitation 0.001 and 2, and every thousandth therebetween, subject to the proviso that the sum of x, y, or z is equal to at least 1, and in which Eu is present in any amount between about 0.0001% and about 5% by weight based upon the phosphor's total weight, wherein substantially all of the europium present is present in the divalent state. A phosphor according to the invention may optionally further comprise an element selected from the group consisting of: Ce, Mn, Ti, Pb, and Sn and is present in any amount between about 0.0001% and about 5% by weight based on the phosphor's total weight. The silicate phosphor materials provided by the present invention do not require the addition of dissimilar blue and red phosphor compounds, and do not contain zinc and/or magnesium. In addition, the present invention provides materials which emit a broad yellowish color containing both green and red emissions. Standard techniques used in phosphor deposition for the manufacture of light emitting diodes which comprise phosphors may be employed to produce LED's having a white light output when the phosphors of the invention are utilized.
摘要翻译：本文提供了可用于制造白色发光二极管的新型荧光体。由本发明提供的荧光体由下式描述：<？in-line-formula description =“In-line Formulas”end =“lead”→> Sr 其中x，y，y，y，y分别表示“ 并且z各自独立地可变为约0至约2之间的任何值，包括但不限于0.001和2，以及每一千位之间，条件是x，y或z的和等于至少1，并且其中Eu以基于荧光体的总重量计约0.0001％至约5％（重量）之间的任何量存在，其中基本上所有存在的铕以二价态存在。根据本发明的荧光体可以任选地进一步包括选自由Ce，Mn，Ti，Pb和Sn组成的组的元素，并且以基于荧光体总量的约0.0001％至约5％重量。由本发明提供的硅酸盐荧光体材料不需要添加不同的蓝色和红色荧光体化合物，并且不含锌和/或镁。此外，本发明提供了发出包含绿色和红色发射的泛黄色的材料。当利用本发明的荧光体时，用于制造包含磷光体的发光二极管的荧光体沉积中使用的标准技术可用于产生具有白光输出的LED。

10. 发明授权

US07109648B2 Light emitting device having thio-selenide fluorescent phosphor 失效
公开(公告)号：US07109648B2
公开(公告)日：2006-09-19
申请号：US10801082
申请日：2004-03-15
申请人： Hisham Menkara , Christopher Summers , Brent K. Wagner
发明人： Hisham Menkara , Christopher Summers , Brent K. Wagner
IPC分类号： H05B33/14 , C09K11/56
CPC分类号： C09K11/885 , C09K11/886 , H01L33/502 , Y02B20/181
摘要： Provided herein are novel phosphors useful in the manufacture of white light emitting diodes. The phosphors provided by the invention are described by the formulae: MA2(SxSey)4:B and/or M2A4(SxSey)7:B in which x, and y are each independently any value between 0 and 1, including 0 and 1 subject to the proviso that the sum of x and y is equal to any number in the range of between about 0.75 and about 1.25; M is at least one of Be, Mg, Ca, Sr, Ba, Zn; A is at least one of Al, Ga, In, Y, La, and Gd; and wherein the activator(s), B, comprises one or more element selected from the group consisting of: Eu, Ce, Cu, Ag, Al, Tb, Cl, Br, F, I, Mg, Pr, K, Na, and Mn, including mixtures comprising any two, any three, any four, any five, any six, any seven, or more of these elements in any proportion, and wherein the elements in these mixtures may each independently be present in any amount between 0.0001% and about 10% in mole percent based on the total molar weight of said composition. Standard techniques used in phosphor deposition for the manufacture of light emitting diodes which comprise phosphors may be employed to produce LED's having a white light output when the phosphors of the invention are utilized.

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