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    • 1. 发明授权
    • Sulfonated amphoteric surfactants for IOR
    • 用于IOR的磺化两性表面活性剂
    • US08714247B1
    • 2014-05-06
    • US13998108
    • 2013-10-01
    • Paul Daniel BergerChristie Huimin BergerSusanta Mohapatra
    • Paul Daniel BergerChristie Huimin BergerSusanta Mohapatra
    • E21B43/22
    • C09K8/584
    • Sulfonated betaines amine oxides, and sultaines are made by the reaction of the corresponding unsaturated betaines or sultaines. These are formulated into injection fluids suitable for the recovery of residual oil from subterranean reservoirs. The sulfonated betaines, amine oxides, and sultaines exhibit lower adsorption onto reservoir rock compared to their corresponding unsulfonated betaines, amine oxides, and sultaines. They can be used in applications where their respective amphoteric surfactants are currently used such as personal care, mining, improved oil recovery (IOR), oil field drilling, fracturing, acidizing, foaming, oil field stimulation, and agricultural formulations.
    • 磺化的甜菜碱氧化胺和磺基甜菜碱通过相应的不饱和甜菜碱或磺基甜菜碱的反应制备。 这些被配制成适合于从地下储层回收残余油的注射液。 与其相应的未磺化的甜菜碱,氧化胺和磺基甜菜碱相比,磺化的甜菜碱,氧化胺和磺基甜菜碱对储层岩石的吸附性能较低。 它们可以用于目前使用它们各自的两性表面活性剂的应用,例如个人护理,采矿,改进的油回收(IOR),油田钻井,压裂,酸化,发泡,油田刺激和农业制剂。
    • 9. 发明授权
    • Process for oil recovery employing surfactant gels
    • 使用表面活性剂凝胶的油回收方法
    • US07373977B1
    • 2008-05-20
    • US11081232
    • 2005-03-16
    • Paul Daniel BergerChristie Huimin Berger
    • Paul Daniel BergerChristie Huimin Berger
    • E21B43/20E21B43/22C09K8/584C09K8/588
    • C09K8/584Y10S507/936
    • A process for recovering oil by injecting into a subterranean oil-bearing reservoir through one or more injection wells, an aqueous solution containing one or more amphoteric alkyl amido betaine surfactants that form a viscoelastic gel reducing interfacial tension and increasing the viscosity of the injection fluid simultaneously, displacing the solution into the reservoir, and recovering the oil from one or more production wells. These viscoelastic gels are tolerant to electrolytes and multivalent cations. They are shear reversible and adsorbed little onto the reservoir. Their viscosity is reduced when contacting certain hydrocarbons but remains high when contacting water or brine. This allows the fluid to preferentially penetrate the oil-bearing portions of the formation and resulting additional oil recovery. These viscoelastic surfactant gels are particularly suitable for use with reservoirs and brines characterized by medium to high temperatures, higher salinity, higher concentrations of divalent cations, and low formation porosities.
    • 一种通过一个或多个注入井注入地下含油储层的方法,含有一种或多种两性烷基酰氨基甜菜碱表面活性剂的水溶液,其形成粘弹性凝胶,同时降低界面张力并增加注射液的粘度 将溶液置于储存器中,并从一个或多个生产井回收油。 这些粘弹性凝胶耐电解质和多价阳离子。 它们是剪切可逆的,并且很少吸附到储层上。 当接触某些烃时,它们的粘度降低,而当接触水或盐水时它们的粘度保持较高。 这允许流体优先地穿透地层的含油部分并且导致额外的油回收。 这些粘弹性表面活性剂凝胶特别适用于以中等至高温,较高盐度,较高浓度的二价阳离子和较低的地层孔隙度为特征的储层和盐水。