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    • 1. 发明授权
    • Coupled rubbery polymers
    • 偶联的橡胶聚合物
    • US06329467B1
    • 2001-12-11
    • US09467861
    • 1999-12-20
    • Adel Farhan HalasaWen-Liang HsuCharles John PearsonYi Feng
    • Adel Farhan HalasaWen-Liang HsuCharles John PearsonYi Feng
    • C08F842
    • C08C19/44B60C1/0016C08F8/42
    • It has been unexpectedly found that greatly improved properties for tire rubbers, such as lower hysteresis, can be attained by coupling the rubber with both a tin halide, such as tin tetrachloride, and a silicon halide, such as silicon tetrachloride. Even better characteristics for use in tire tread compounds can be realized by asymmetrically coupling the rubbery polymer. This invention more specifically discloses a coupled rubbery polymer which is particularly valuable for use in manufacturing tire tread compounds, said coupled rubbery polymer being comprised of (1) tin atoms having at least three polydiene arms covalently bonded thereto and (2) silicon atoms having at least three polydiene arms covalently bonded thereto.
    • 已经意外地发现,通过将橡胶与卤化锡如四氯化锡和卤化硅如四氯化硅二者相结合,可以获得轮胎橡胶的较好的性能,例如较低的滞后性。 用于轮胎胎面胶料的更好的特性可以通过不对称地偶合橡胶状聚合物来实现。 本发明更具体地公开了一种特别有价值地用于制造轮胎胎面胶料的偶联橡胶状聚合物,所述连接的橡胶状聚合物包括(1)具有至少三个与其共价连接的聚二烯臂的锡原子和(2) 共价键合至少三个聚二烯臂。