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    • 2. 发明授权
    • Process for modifying synthetic bicomponent fiber cross-sections
    • 改性合成双组分纤维截面的方法
    • US6153138A
    • 2000-11-28
    • US288185
    • 1999-04-08
    • Charles F. Helms, Jr.Otto M. IlgDiane R. KentMatthew B. HoytJohn A. Hodan
    • Charles F. Helms, Jr.Otto M. IlgDiane R. KentMatthew B. HoytJohn A. Hodan
    • D01D5/253D01F8/12B29D31/00D01D5/24D01D8/04D01D8/12
    • D01F8/12D01D5/253Y10T428/2929Y10T428/2931Y10T428/2973Y10T428/2975
    • Bicomponent fibers of different cross-sections may be formed without changing the geometry of the spinneret orifices. More specifically, at least two polymers are co-melt-spun through an orifice of fixed geometry so as to achieve a bicomponent fiber having a desired cross-section. In order to change to a bicomponent fiber having a cross-section which is different, therefore, at least one of (1) the differential relative viscosity, (2) the relative proportions of the first and/or second polymers, and (3) the cross-sectional bicomponent distribution of the first and second polymers, is changed. In such a manner, therefore, a wide variety of bicomponent fibers having different cross-sectional geometries may be produced without changing the fixed geometry orifice through which the polymers are co-melt-spun. Thus, bicomponent fiber cross-sections may be "engineered" to suit a variety of needs without necessarily shutting down production equipment in order to change spinnerets. The bicomponent fibers are most preferably multilobal (e.g., trilobal) in which the core component is generally triangularly shaped.
    • 可以在不改变喷丝孔的几何形状的情况下形成不同横截面的双组分纤维。 更具体地说,至少两种聚合物通过固定几何形状的孔进行共熔纺丝,以达到具有所需横截面的双组分纤维。 因此,为了改变具有不同截面的双组分纤维,因此,(1)差分相对粘度,(2)第一和/或第二聚合物的相对比例和(3)中的至少一个, 改变第一和第二聚合物的横截面双组分分布。 因此,以这种方式,可以生产具有不同横截面几何形状的各种各样的双组分纤维,而不改变聚合物共熔共纺的固定几何孔。 因此,双组分纤维横截面可以“工程化”以适应各种需要,而不必关闭生产设备以改变喷丝头。 双组分纤维最优选为多叶形(例如三叶形),其中芯部分通常为三角形。
    • 7. 发明授权
    • Continuous polymerization and direct fiber spinning and apparatus for accomplishing same
    • 连续聚合和直接纺丝纺丝及其设备
    • US06441109B1
    • 2002-08-27
    • US09475675
    • 1999-12-30
    • Dominick A. BurloneMatthew B. HoytCharles F. Helms, Jr.John A. HodanRichard KotekCarol W. MorganRandall A. SferrazzaFang A. WangOtto M. IlgTerry D. RobertsRonald G. Morrow
    • Dominick A. BurloneMatthew B. HoytCharles F. Helms, Jr.John A. HodanRichard KotekCarol W. MorganRandall A. SferrazzaFang A. WangOtto M. IlgTerry D. RobertsRonald G. Morrow
    • C08F201
    • C08G69/18D01D1/06D01F6/60
    • Continuous anionic polymerization and melt-spinning of a polycaprolactam includes forming a reaction mixture by bringing at least two streams of liquid caprolactam respectively containing a polymerization initiator and co-initiator into contact with one another, and then subjecting the reaction mixture to anionic polymerization reaction conditions to obtain a molten polycaprolactam. The molten polycaprolactam is the directly (i.e., without intermediate solidification) transferred to, and extruded through, a fiber-forming orifice of a spinneret to form a fiber thereof. One exemplary system to achieve such continuous anionic polymerization and melt-spinning of polycaprolactam includes a mixer for receiving and mixing at least two streams of liquid caprolactam respectively containing a polymerization initiator and co-initiator, and a reactor and melt-spinning apparatus downstream of the mixer. The reactor and melt-spinning apparatus most preferably is formed of multiple plates which establish a reactor zone having a flow path for the reaction mixture which is sized and configured to achieve a predetermined residence time of the reaction mixture therein, and a temperature control zone in thermal communication with the reactor plate for controlling the temperature of the reaction plate to achieve anionic polymerization reaction conditions while the reaction mixture is flowing along the defined flow path therein to obtain the molten polycaprolactam. A spinneret zone downstream of the reactor zone thus receives the molten polycaprolactam directly and forms a fiber therefrom by extruding it through the spinneret's fiber-spinning orifice.
    • 聚己内酰胺的连续阴离子聚合和熔融纺丝包括通过使至少两股分别含有聚合引发剂和共引发剂的液体己内酰胺流彼此接触形成反应混合物,然后将反应混合物进行阴离子聚合反应条件 得到熔融的聚己内酰胺。 熔融的聚己内酰胺直接(即没有中间凝固)转移到喷丝板的纤维形成孔中并被挤出,以形成其纤维。 实现这种连续阴离子聚合和聚己内酰胺的熔融纺丝的一个示例性系统包括用于接收和混合分别含有聚合引发剂和共引发剂的至少两种液体己内酰胺流的混合器,以及在聚合引发剂和共引发剂下游的反应器和熔融纺丝装置 混合器。 反应器和熔体纺丝装置最优选地由多个板形成,该板形成具有反应混合物流动路径的反应器区,该反应器区的尺寸和构造被设计成达到其中反应混合物的预定停留时间,以及温度控制区 与反应器板的热连通,用于控制反应板的温度以实现阴离子聚合反应条件,同时反应混合物沿其中限定的流动路径流动以获得熔融的聚己内酰胺。 因此,反应器区域下游的喷丝头区域直接接收熔融的聚己内酰胺并通过将其通过喷丝头的纤维纺丝孔口挤出而形成纤维。