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    • 7. 发明授权
    • System and method for converting the spent remnants of a first pickling acid solution into a usable second pickling acid solution
    • 将第一酸洗溶液的废残余物转化为可用的第二酸洗溶液的系统和方法
    • US07351391B1
    • 2008-04-01
    • US11129639
    • 2005-05-16
    • Douglas R. OlsenCharles D. Blumenschein
    • Douglas R. OlsenCharles D. Blumenschein
    • C01B7/07C01B17/90C01G49/00C23G1/02
    • C23G1/36C01B7/035C01G49/14Y10S423/01Y10S423/02
    • A system and method of economically converting a spent first pickling acid solution that contains hydrochloric acid, water and ferrous chloride into a suitable second pickling solution. Sulfuric acid is added to the first pickling acid solution. This produces a regeneration solution. In the regeneration solution, the sulfuric acid reacts with said ferrous chloride and water to produce ferrous sulfate heptahydrate and hydrochloric acid. The regeneration solution is cooled to promote precipitation of the ferrous sulfate heptahydrate from the regeneration solution, therein creating ferrous sulfate heptahydrate crystals and a second pickling acid solution. The second pickling acid solution contains both hydrochloric acid and sulfuric acid. The ferrous sulfate heptahydrate crystals are separated from second pickling solution. The ferrous sulfate heptahydrate is sold commercially and the second pickling acid solution is used to directly pickle ferrous metal.
    • 将含有盐酸,水和氯化亚铁的用过的第一酸洗溶液经济地转化成合适的第二酸洗溶液的系统和方法。 将硫酸加入到第一酸洗溶液中。 这产生再生溶液。 在再生溶液中,硫酸与氯化亚铁和水反应生成硫酸亚铁七水合物和盐酸。 将再生溶液冷却以促进来自再生溶液的七水合硫酸汞的沉淀,其中产生硫酸亚铁七水合物晶体和第二酸洗溶液。 第二酸洗液含有盐酸和硫酸。 将七水合硫酸亚铁晶体与第二酸洗溶液分离。 七水合硫酸亚铁是商业上销售的,第二酸洗溶液用于直接腌制黑色金属。