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1. 发明申请

US20150175419A1 REACTOR AND PROCESS FOR PREPARING HYDROGEN SULPHIDE 有权
标题翻译：反应器和制备硫化氢的方法
公开(公告)号：US20150175419A1
公开(公告)日：2015-06-25
申请号：US14410378
申请日：2013-05-31
申请人： Caspar-Heinrich Finkeldei , Chiu Kee Cheung , Ralf Maassen , Geert Van Eester , Stefan Wenner , Martin Koerfer
发明人： Caspar-Heinrich Finkeldei , Chiu Kee Cheung , Ralf Maassen , Geert Van Eester , Stefan Wenner , Martin Koerfer
IPC分类号： C01B17/16 , B01J19/24
CPC分类号： C01B17/162 , B01J4/002 , B01J8/067 , B01J10/005 , B01J19/006 , B01J19/24 , B01J2219/00166 , B01J2219/00777 , B01J2219/24
摘要： The present invention relates to a reactor and to a process for synthesis of hydrogen sulphide from elemental sulphur and hydrogen at elevated pressure and elevated temperature. The invention further relates to the use of the reactor for preparation of hydrogen sulphide in high yield and with a low H2Sx content.
摘要翻译：本发明涉及一种反应器以及在升高的压力和升高的温度下从元素硫和氢合成硫化氢的方法。本发明进一步涉及反应器以高产率和低硫化氢含量制备硫化氢的用途。

2. 发明申请

US20140005437A1 INTEGRATED PROCESS FOR PREPARING ACROLEIN AND 3-METHYLMERCAPTOPROPIONALDEHYDE 有权
标题翻译：用于制备丙烯酸和3-甲基哌啶酮的一体化方法
公开(公告)号：US20140005437A1
公开(公告)日：2014-01-02
申请号：US13927430
申请日：2013-06-26
申请人： Pablo ZACCHI , Caspar Heinrich Finkeldei , Martin Koerfer
发明人： Pablo ZACCHI , Caspar Heinrich Finkeldei , Martin Koerfer
IPC分类号： C07C319/02
CPC分类号： C07C319/02 , C07C45/28 , C07C319/18 , Y02P20/125 , C07C323/22 , C07C47/22
摘要： A process to produce 3-methylmercaptopropionaldehyde is provided. The process comprises: A) oxidizing a mixture of propylene and inert diluent gases with air over a heterogeneous catalyst to obtain a gaseous oxidation reaction mixture comprising acrolein and by-products; B) quenching the gaseous oxidation reaction mixture to obtain a gas stream comprising acrolein and a quench liquid comprising residual acrolein and the by-products; C) stripping the acrolein from the by-products of the quench liquid and returning the stripped acrolein to the quench; D) absorbing a first portion of the gas stream comprising acrolein from the quench B) in water to obtain an aqueous acrolein solution and an uncondensable gaseous stream comprising inert gases; D1) recycling at least a portion of the uncondensable gaseous stream to the oxidation A) to supply the inert diluent gases; E) distilling the acrolein from the aqueous acrolein solution to obtain an acrolein-free aqueous bottom product; E1) condensing the distilled acrolein; F) reacting the distilled acrolein E1) and the gas stream comprising acrolein B) with methyl mercaptan in a mixture comprising at least one of 3-methylmercaptopropionaldehyde and a hemithioacetal of methyl mercaptan and 3-methylmercaptopropionaldehyde to obtain the 3-methylmercaptopropionaldehyde.
摘要翻译：提供了制备3-甲基巯基丙醛的方法。该方法包括：A）在多相催化剂上用空气氧化丙烯和惰性稀释气体的混合物，得到包含丙烯醛和副产物的气态氧化反应混合物; B）淬灭气态氧化反应混合物以获得包含丙烯醛和包含残余丙烯醛和副产物的骤冷液体的气流; C）从急冷液体的副产物中除去丙烯醛，并将汽提的丙烯醛返回到骤冷器中; D）从水中的骤冷B）吸收包含丙烯醛的气流的第一部分在水中以获得丙烯醛水溶液和包含惰性气体的不可冷凝气流; D1）将至少一部分不可冷凝的气流再循环到氧化物A）以供应惰性稀释气体; E）从丙烯醛水溶液中蒸馏出丙烯醛，得到无丙烯醛的含水底物; E1）冷凝蒸馏出的丙烯醛; F）使蒸馏的丙烯醛E1）和包含丙烯醛B）的气流与甲硫醇在包含3-甲基巯基丙醛和甲硫醇和3-甲基巯基丙醛的半硫缩醛中的至少一种的混合物中反应，得到3-甲基巯基丙醛。

3. 发明申请

US20120215022A1 METHOD FOR THE PRODUCTION OF 2-HYDROXY-4-(METHYLTHIO)BUTYRONITRILE FROM 3-(METHYLTHIO)PROPANAL AND HYDROGEN CYANIDE 有权
标题翻译：从3-（甲基）丙醛和氢氰化物生产2-羟基-4-（甲基）苯并呋喃的方法
公开(公告)号：US20120215022A1
公开(公告)日：2012-08-23
申请号：US13402041
申请日：2012-02-22
申请人： Dieter Buss , Martin Steurenthaler , Michael R. Rinner , Stephan Kretz , Hans Joachim Hasselbach , Caspar-Heinrich Finkeldei , Martin Koerfer , Pablo Zacchi
发明人： Dieter Buss , Martin Steurenthaler , Michael R. Rinner , Stephan Kretz , Hans Joachim Hasselbach , Caspar-Heinrich Finkeldei , Martin Koerfer , Pablo Zacchi
IPC分类号： C07C51/08 , C07C253/00
CPC分类号： C07C319/20 , C07C323/60 , C07C323/58 , C07C323/52
摘要： A method for the production of 2-hydroxy-4-(methylthio)butyronitrile having good storage stability in a multi-zone reactor, is provided. 3-methylmercaptopropionaldehyde is reacted with hydrogen cyanide in the presence of a base as catalyst in a main reaction zone of the multizone reactor to form a reaction mixture comprising the 2-hydroxy-4-(methylthio)butyronitrile, unreacted 3-methylmercaptopropionaldehyde, the catalyst and residual amounts of gaseous hydrogen cyanide. The residual gaseous hydrogen cyanide is removed from the main reaction zone to an absorption and post-reaction zone of the reactor which comprises a mixture of 3-methylmercaptopropionaldehyde and the catalyst; and the gaseous hydrogen cyanide is further reacted with the 3-methylmercaptopropionaldehyde in the absorption and post reaction zone. A molar ratio of hydrogen cyanide to 3-(methylthio)propanal in the main reaction zone is from 0.98 to 1.03.
摘要翻译：提供了一种在多区域反应器中制备具有良好储存稳定性的2-羟基-4-（甲硫基）丁腈的方法。在多基团反应器的主反应区中，3-甲基巯基丙醛与作为催化剂的碱存在下，与氰化氢反应形成包含2-羟基-4-（甲硫基）丁腈，未反应的3-甲基巯基丙醛，催化剂和残留量的氰化氢气体。将残留的气态氰化氢从主反应区移除到包含3-甲基巯基丙醛和催化剂的混合物的反应器的吸收和后反应区域; 并且氰化氢气体在吸收和后反应区域中与3-甲基巯基丙醛进一步反应。主反应区氰化氢与3-（甲硫基）丙醛的摩尔比为0.98-1.03。

4. 发明授权

US08008530B2 Process for preparing methyl mercaptan 有权
标题翻译：制备甲硫醇的方法
公开(公告)号：US08008530B2
公开(公告)日：2011-08-30
申请号：US12065563
申请日：2006-08-22
申请人： Hubert Redlingshöfer , Stephan Kretz , Caspar-Heinrich Finkeldei , Christoph Weckbecker , Wolfgang Böck , Klaus Huthmacher
发明人： Hubert Redlingshöfer , Stephan Kretz , Caspar-Heinrich Finkeldei , Christoph Weckbecker , Wolfgang Böck , Klaus Huthmacher
IPC分类号： C07C319/00
CPC分类号： C01B17/162 , C07C319/08 , C07C321/04
摘要： The present invention relates to a process for continuously preparing methyl mercaptan from hydrogen sulphide and methanol in a direct connection with the preparation of hydrogen sulphide.
摘要翻译：本发明涉及一种从制备硫化氢直接连接硫化氢和甲醇连续制备甲硫醇的方法。

5. 发明授权

US09421511B2 Reactor and process for preparing hydrogen sulphide 有权
标题翻译：用于制备硫化氢的反应器和方法
公开(公告)号：US09421511B2
公开(公告)日：2016-08-23
申请号：US14410230
申请日：2013-05-31
申请人： Caspar-Heinrich Finkeldei , Chiu Kee Cheung , Ralf Maassen , Stefan Wenner , Martin Koerfer
发明人： Caspar-Heinrich Finkeldei , Chiu Kee Cheung , Ralf Maassen , Stefan Wenner , Martin Koerfer
IPC分类号： C01B17/16 , B01J10/00 , B01J12/00 , B01J19/24 , B01J8/06 , B01J19/00 , B01J4/00
CPC分类号： B01J19/24 , B01J4/002 , B01J8/067 , B01J10/005 , B01J19/006 , B01J2219/00074 , B01J2219/0015 , B01J2219/00166 , B01J2219/00777 , B01J2219/24 , C01B17/162
摘要： The present invention relates to a reactor and to a process for synthesis of hydrogen sulphide from elemental sulphur and hydrogen at elevated pressure and elevated temperature. The invention further relates to the use of the reactor for preparation of hydrogen sulphide in high yield and with a low H2Sx content.
摘要翻译：本发明涉及一种反应器以及在升高的压力和升高的温度下从元素硫和氢合成硫化氢的方法。本发明进一步涉及反应器以高产率和低硫化氢含量制备硫化氢的用途。

6. 发明申请

US20150197489A1 METHOD FOR THE PRODUCTION OF D,L-METHIONINE 审中-公开
标题翻译：生产D，L-甲硫氨酸的方法
公开(公告)号：US20150197489A1
公开(公告)日：2015-07-16
申请号：US14671435
申请日：2015-03-27
申请人： Dieter Buss , Martin Steurenthaler , Michael R. Rinner , Stephan Kretz , Hans Joachim Hasselbach , Caspar-Heinrich Finkeldei , Martin Koerfer , Pablo Zacchi
发明人： Dieter Buss , Martin Steurenthaler , Michael R. Rinner , Stephan Kretz , Hans Joachim Hasselbach , Caspar-Heinrich Finkeldei , Martin Koerfer , Pablo Zacchi
IPC分类号： C07C319/20
CPC分类号： C07C319/20 , C07C323/60 , C07C323/58 , C07C323/52
摘要： A method to produce D,L-Methionine from 2-hydroxy-4-(methylthio)butyronitrile by reaction with ammonia, optionally in the presence of carbon dioxide, is provided. The 2-hydroxy-4-(methylthio)butyronitrile is obtained by reaction of 3-methylmercapto-propionaldehyde with hydrogen cyanide in the presence of a base as catalyst in a main reaction zone of a multizone reactor. Residual gaseous hydrogen cyanide is removed from the main reaction zone to an absorption and post-reaction zone of the reactor which comprises a mixture of 3-methylmercaptopropionaldehyde and the catalyst; and the gaseous hydrogen cyanide is further reacted with the 3-methylmercaptopropionaldehyde in the absorption and post reaction zone. A molar ratio of hydrogen cyanide to 3-(methylthio)propanal in the main reaction zone is from 0.98 to 1.03.
摘要翻译：提供了通过与氨反应，任选在二氧化碳存在下，由2-羟基-4-（甲硫基）丁腈生成D，L-甲硫氨酸的方法。 2-羟基-4-（甲硫基）丁腈是通过在多基团反应器的主反应区中作为催化剂的碱作为催化剂使3-甲基巯基丙醛与氰化氢反应得到的。残留的气态氰化氢从主反应区除去反应器的吸收和后反应区，其包含3-甲基巯基丙醛和催化剂的混合物; 并且氰化氢气体在吸收和后反应区域中与3-甲基巯基丙醛进一步反应。主反应区氰化氢与3-（甲硫基）丙醛的摩尔比为0.98-1.03。

7. 发明授权

US08759592B2 Process for preparing methylmercaptopropionaldehyde 有权
标题翻译：甲基巯基丙醛的制备方法
公开(公告)号：US08759592B2
公开(公告)日：2014-06-24
申请号：US14067098
申请日：2013-10-30
申请人： Caspar Heinrich Finkeldei , Pablo Zacchi , Benjamin Fonfe , Stephan Kretz , Martin Koerfer , Hans Joachim Hasselbach , Wolfgang Boeck
发明人： Caspar Heinrich Finkeldei , Pablo Zacchi , Benjamin Fonfe , Stephan Kretz , Martin Koerfer , Hans Joachim Hasselbach , Wolfgang Boeck
IPC分类号： C07C319/20
CPC分类号： C07C319/20 , C07C319/16 , C07C323/22
摘要： A process for preparing methylmercaptopropionaldehyde in a single reaction unit, is provided. According to the preferred embodiment, the process comprises, simultaneously contacting a gaseous mixture comprising acrolein with a liquid mixture comprising methylmercaptopropionaldehyde, methyl mercaptan, a catalyst and methylmercaptopropionaldehyde methyl thiohemiacetal in the reactive absorber; absorbing the acrolein from the gaseous mixture into the liquid mixture; reacting the absorbed acrolein with the methyl mercaptan or the methylmercaptopropionaldehyde methyl thiohemiacetal to obtain methylmercapto-propionaldehyde; removing gaseous impurities and by-products from the liquid mixture; and separating the obtained methylmercaptopropionaldehyde product from the reactive absorber, directing a portion of the separated product to storage or further processing and recycling the remaining portion to the reactive absorber; wherein the methyl mercaptan optionally comprises dimethyl sulfide or dimethyl ether.
摘要翻译：提供了在单个反应单元中制备甲基巯基丙醛的方法。根据优选实施方案，该方法包括同时使包含丙烯醛的气体混合物与包含甲基巯基丙醛，甲硫醇，催化剂和甲基巯基丙醛甲硫基缩醛的液体混合物接触; 将丙烯醛从气态混合物吸收到液体混合物中; 使吸收的丙烯醛与甲基硫醇或甲基巯基丙醛甲基硫代缩甲醛反应，得到巯基丙醛甲缩醛; 从液体混合物中除去气态杂质和副产物; 并将所获得的甲基巯基丙醛产物与反应性吸收剂分离，将一部分分离产物导入储存或进一步加工并将剩余部分再循环至反应性吸收剂; 其中甲硫醇任选地包括二甲基硫醚或二甲醚。

8. 发明授权

US09440208B2 Reactor and process for preparing hydrogen sulphide 有权
标题翻译：用于制备硫化氢的反应器和方法
公开(公告)号：US09440208B2
公开(公告)日：2016-09-13
申请号：US14410360
申请日：2013-05-31
申请人： Caspar-Heinrich Finkeldei , Chiu Kee Cheung , Ralf Maassen , Stefan Wenner , Martin Koerfer
发明人： Caspar-Heinrich Finkeldei , Chiu Kee Cheung , Ralf Maassen , Stefan Wenner , Martin Koerfer
IPC分类号： C01B17/16 , B01J10/00 , B01J8/02 , B01J8/06 , B01J19/00 , B01J19/24
CPC分类号： B01J8/0285 , B01J8/02 , B01J8/067 , B01J10/005 , B01J19/006 , B01J19/24 , B01J2208/00327 , B01J2208/027 , B01J2219/00166 , B01J2219/00777 , C01B17/162
摘要： The present invention relates to a reactor and to a process for synthesis of hydrogen sulphide from elemental sulphur and hydrogen at elevated pressure and elevated temperature. The invention further relates to the use of the reactor for preparation of hydrogen sulphide in high yield and with a low H2SX content.
摘要翻译：本发明涉及一种反应器以及在升高的压力和升高的温度下从元素硫和氢合成硫化氢的方法。本发明进一步涉及反应器以高产率和低硫化氢含量制备硫化氢的用途。

9. 发明授权

US08624066B2 Process for preparing methylmercaptopropionaldehyde 有权
标题翻译：甲基巯基丙醛的制备方法
公开(公告)号：US08624066B2
公开(公告)日：2014-01-07
申请号：US13337434
申请日：2011-12-27
申请人： Caspar Heinrich Finkeldei , Pablo Zacchi , Benjamin Fonfe , Stephan Kretz , Martin Koerfer , Hans Joachim Hasselbach , Wolfgang Boeck
发明人： Caspar Heinrich Finkeldei , Pablo Zacchi , Benjamin Fonfe , Stephan Kretz , Martin Koerfer , Hans Joachim Hasselbach , Wolfgang Boeck
IPC分类号： C07C319/18
CPC分类号： C07C319/20 , C07C319/16 , C07C323/22
摘要： A process for preparing methylmercaptopropionaldehyde in a single reaction unit, is provided. According to the preferred embodiment, the process comprises, simultaneously contacting a gaseous mixture comprising acrolein with a liquid mixture comprising methylmercaptopropionaldehyde, methyl mercaptan, a catalyst and methylmercaptopropionaldehyde methyl thiohemiacetal in the reactive absorber; absorbing the acrolein from the gaseous mixture into the liquid mixture; reacting the absorbed acrolein with the methyl mercaptan or the methylmercaptopropionaldehyde methyl thiohemiacetal to obtain methylmercapto-propionaldehyde; removing gaseous impurities and by-products from the liquid mixture; and separating the obtained methylmercaptopropionaldehyde product from the reactive absorber, directing a portion of the separated product to storage or further processing and recycling the remaining portion to the reactive absorber; wherein the methyl mercaptan optionally comprises dimethyl sulfide or dimethyl ether.
摘要翻译：提供了在单个反应单元中制备甲基巯基丙醛的方法。根据优选实施方案，该方法包括同时使包含丙烯醛的气体混合物与包含甲基巯基丙醛，甲硫醇，催化剂和甲基巯基丙醛甲硫基缩醛的液体混合物接触; 将丙烯醛从气态混合物吸收到液体混合物中; 使吸收的丙烯醛与甲基硫醇或甲基巯基丙醛甲基硫代缩甲醛反应，得到甲基巯基丙醛; 从液体混合物中除去气态杂质和副产物; 并将所获得的甲基巯基丙醛产物与反应性吸收剂分离，将一部分分离产物导入储存或进一步加工并将剩余部分再循环至反应性吸收剂; 其中甲硫醇任选地包括二甲基硫醚或二甲醚。

10. 发明申请

US20120165573A1 PROCESS FOR PREPARING METHYLMERCAPTOPROPIONALDEHYDE 有权
标题翻译：制备甲基苦参碱的方法
公开(公告)号：US20120165573A1
公开(公告)日：2012-06-28
申请号：US13337434
申请日：2011-12-27
申请人： Caspar Heinrich FINKELDEI , Pablo Zacchi , Benjamin Fonfe , Stephan Kretz , Martin Koerfer , Hans Joachim Hasselbach , Wolfgang Boeck
发明人： Caspar Heinrich FINKELDEI , Pablo Zacchi , Benjamin Fonfe , Stephan Kretz , Martin Koerfer , Hans Joachim Hasselbach , Wolfgang Boeck
IPC分类号： C07C319/18
CPC分类号： C07C319/20 , C07C319/16 , C07C323/22
摘要： A process for preparing methylmercaptopropionaldehyde in a single reaction unit, is provided. According to the preferred embodiment, the process comprises, simultaneously contacting a gaseous mixture comprising acrolein with a liquid mixture comprising methylmercaptopropionaldehyde, methyl mercaptan, a catalyst and methylmercaptopropionaldehyde methyl thiohemiacetal in the reactive absorber; absorbing the acrolein from the gaseous mixture into the liquid mixture; reacting the absorbed acrolein with the methyl mercaptan or the methylmercaptopropionaldehyde methyl thiohemiacetal to obtain methylmercapto-propionaldehyde; removing gaseous impurities and by-products from the liquid mixture; and separating the obtained methylmercaptopropionaldehyde product from the reactive absorber, directing a portion of the separated product to storage or further processing and recycling the remaining portion to the reactive absorber; wherein the methyl mercaptan optionally comprises dimethyl sulfide or dimethyl ether.
摘要翻译：提供了在单个反应单元中制备甲基巯基丙醛的方法。根据优选实施方案，该方法包括同时使包含丙烯醛的气体混合物与包含甲基巯基丙醛，甲硫醇，催化剂和甲基巯基丙醛甲硫基缩醛的液体混合物接触; 将丙烯醛从气态混合物吸收到液体混合物中; 使吸收的丙烯醛与甲基硫醇或甲基巯基丙醛甲基硫代缩甲醛反应，得到甲基巯基丙醛; 从液体混合物中除去气态杂质和副产物; 并将所获得的甲基巯基丙醛产物与反应性吸收剂分离，将一部分分离产物导入储存或进一步加工并将剩余部分再循环至反应性吸收剂; 其中甲硫醇任选地包括二甲基硫醚或二甲醚。

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