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    • 2. 发明授权
    • Method of making clad materials using lead alloys and composite strips made by such method
    • 采用这种方法制作的铅合金和复合带制造复合材料的方法
    • US06475675B1
    • 2002-11-05
    • US09568829
    • 2000-05-11
    • Awadh K. PandeyBijendra Jha
    • Awadh K. PandeyBijendra Jha
    • H01M464
    • B23K20/04B23K35/001B32B15/01C22C11/06H01M4/685H01M4/70H01M4/82H01M2004/029Y10T428/12701
    • Lead alloy strip material (4, 6, 8) is roll bonded on one or both opposite face surfaces of a core strip material (2). The core material can be commercially pure titanium, austenitic stainless steel, low carbon steel, copper, aluminum, alloys thereof or other suitable metal that has sufficient ductility and that can provide desired attributes of stiffness and corrosion resistance to the composite. The lead alloy material is strengthened by the addition of less than approximately 1% of calcium or antimony and the core material is softened by fully annealing it prior to bonding. The several strips are reduced in thickness, preferably in approximately the same proportion, by at least 40% in the bonding pass to create a solid phase bond among the strips. The bonded composite is then rolled to final gauge and, for selected applications, is corrugated and cut to form panels (20, 22, 24) and etched to form pockets (8b) for pasting of active materials such as lead oxide for battery plates.
    • 铅芯合金条材料(4,6,8)在芯条材料(2)的一个或两个相对的表面上滚动粘结。 核心材料可以是商业上纯钛,奥氏体不锈钢,低碳钢,铜,铝,它们的合金或具有足够的延展性的其它合适的金属,并且可以提供对复合材料的刚性和耐腐蚀性所需的属性。 通过添加少于约1%的钙或锑来增强铅合金材料,并且通过在结合之前将其完全退火使芯材料软化。 在条带中,若干条的厚度,优选以大致相同的比例减少至少40%,以在条带之间产生固相结合。 然后将粘合的复合材料轧制成最终规格,并且对于所选择的应用,是波纹状的并且被切割以形成板(20,22,24)并被蚀刻以形成用于粘贴活性材料(例如电池板的氧化铅)的凹穴(8b)。
    • 5. 发明申请
    • FeCrAl ALLOY FOIL FOR CATALYTIC CONVERTERS AT MEDIUM HIGH TEMPERATURE AND A METHOD OF MAKING THE MATERIAL
    • 用于中温高温催化转化器的FeCrAl合金箔及其制备方法
    • US20070237690A1
    • 2007-10-11
    • US11537148
    • 2006-09-29
    • Lichun ChenBijendra Jha
    • Lichun ChenBijendra Jha
    • B23K20/04B01D53/34
    • B01J35/04B01J37/08
    • A FeCrAl alloy for catalytic converter substrates having excellent oxidation resistance and dimension stability at a medium high temperature, e.g. the temperature encountered by catalytic converter substrates in truck diesel engines, without necessary addition of extra Y, Hf, Zr, or rare earth elements beyond that inherently present in commercial stainless steel. A roll bonding and diffusion alloying annealing method is used for making such materials with the following two deviated paths. First, material in which layers of ferritic stainless steel and aluminum are solid state metallurgically bonded together forming a multilayer composite material. Such composite material is then further rolled to an intermediate foil gauge, cleaned, and then subjected to a thermal reaction to form a resulting uniform solid solution foil material followed by rolling to the final foil thickness. Alternatively, such composite material is further rolled to the final foil thickness, cleaned, and then subjected to a thermal in-situ reaction in the material after a honeycomb-like catalytic converter is made from the foil composite material. Both deviated approaches result in a uniform solid solution foil material.
    • 一种用于催化转化器基底的FeCrAl合金,其在中等高温下具有优异的抗氧化性和尺寸稳定性,例如, 催化转化器基板在卡车柴油发动机中遇到的温度,不需要额外添加额外的Y,Hf,Zr或稀土元素,超出商业不锈钢中固有的含量。 使用辊粘合和扩散合金化退火方法制造具有以下两个偏离路径的这种材料。 首先,铁素体不锈钢和铝层是固态冶金结合在一起形成多层复合材料的材料。 然后将这种复合材料进一步轧制到中间箔计量器上,进行清洗,然后进行热反应以形成均匀的固溶体箔材料,然后轧制至最终的箔厚度。 或者,将这种复合材料进一步轧制到最终的箔厚度,清洁,然后在由箔复合材料制成蜂窝状催化转化器之后在材料中进行热原位反应。 两种偏离的方法都产生均匀的固溶箔材料。
    • 7. 发明申请
    • FeCrAl alloy foil for catalytic converters at medium high temperature and a method of making the material
    • 用于中等温度催化转化器的FeCrAl合金箔及其制备方法
    • US20050058581A1
    • 2005-03-17
    • US10914457
    • 2004-08-09
    • Lichun ChenBijendra Jha
    • Lichun ChenBijendra Jha
    • B01D53/34B01J35/04B01J37/08B23K20/04
    • B01J35/04B01J37/08Y10T29/49345Y10T428/12431
    • A FeCrAl alloy for catalytic converter substrates having excellent oxidation resistance and dimension stability at a medium high temperature, e.g. the temperature encountered by catalytic converter substrates in truck diesel engines, without necessary addition of extra Y, Hf, or rare earth elements beyond that inherently present in commercial stainless steel. A roll bonding and diffusion alloying annealing method is used for making such materials with the following two deviated paths. First, material in which layers of ferritic stainless steel and aluminum are solid state metallurgically bonded together forming a multilayer composite material. Such composite material is then further rolled to an intermediate foil gauge and then subjected to a thermal reaction to form a resulting uniform solid solution foil material followed by rolling to the final foil thickness. Alternatively, such composite material is further rolled to the final foil thickness and then subjected to a thermal in-situ reaction in the material after a honeycomb-like catalytic converter is made from the foil composite material. Both deviated approaches result in a uniform solid solution foil material.
    • 一种用于催化转化器基底的FeCrAl合金,其在中等高温下具有优异的抗氧化性和尺寸稳定性,例如, 催化转化器基板在卡车柴油发动机中遇到的温度,不需要额外的添加额外的Y,Hf或稀土元素超出商业不锈钢中固有的。 使用辊粘合和扩散合金化退火方法制造具有以下两个偏离路径的这种材料。 首先,铁素体不锈钢和铝层是固态冶金结合在一起形成多层复合材料的材料。 然后将这种复合材料进一步轧制成中间箔片,然后进行热反应以形成均匀的固溶体箔材料,然后轧制至最终的箔厚度。 或者,将这种复合材料进一步轧制到最终的箔厚度,然后在由箔复合材料制成蜂窝状催化转化器之后在材料中进行热原位反应。 两种偏离的方法都产生均匀的固溶箔材料。