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    • 3. 发明授权
    • Support tube for high temperature solid electrolyte electrochemical cell
    • 支撑管用于高温固体电解质电化学电池
    • US4596750A
    • 1986-06-24
    • US712282
    • 1985-03-15
    • Roswell J. RukaBarry R. Rossing
    • Roswell J. RukaBarry R. Rossing
    • H01M8/02C04B35/486H01M8/12
    • H01M8/12C04B35/486H01M8/1226
    • Disclosed is a compound having a fluorite-like structure comprising a solid solution having the general formula [(ZrO.sub.2).sub.1-x (MO.sub.s).sub.x ].sub.1-y [(La.sub.m A.sub.1-m).sub.2-z (Mn.sub.n B.sub.1-n).sub.z O.sub.r ].sub.y where MO.sub.5 is an oxide selected from the group consisting of calcia, yttria, rare earth oxides, and mixtures thereof, x is about 0.1 to 0.3, y is about 0.005 to about 0.06, z is about 0.1 to about 1.9, A is yttrium, rare earth element, alkaline earth element, or mixture thereof, B is iron, nickel, cobalt, or mixture thereof, m is 0.3 to 1, n is 0.5 to 1, and r is 2 to 4. A porous tube made from such a composition can be coated with an electrically conducting mixed oxide electrode such as lanthanum manganite, and can be used in making high temperature electrochemical cells such as solid electrolyte fuel cells.
    • 公开了具有萤石状结构的化合物,其包含具有通式[(ZrO 2)1-x(MOs)x] 1-y [(LamAl-m)2-z(MnnB1-n)zOr] y 其中MO5是选自氧化钙,氧化钇,稀土氧化物及其混合物的氧化物,x为约0.1至0.3,y为约0.005至约0.06,z为约0.1至约1.9,A为钇, 稀土元素,碱土金属元素或其混合物,B为铁,镍,钴或其混合物,m为0.3〜1,n为0.5〜1,r为2〜4。 组合物可以用诸如亚锰酸镧的导电混合氧化物电极涂覆,并且可以用于制备诸如固体电解质燃料电池的高温电化学电池。