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1. 发明授权

US08877086B2 Compositions comprising 2,3-dichloro-1,1,1-trifluoropropane, 2-chloro-1,1,1-trifluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane or 2,3,3,3-tetrafluoropropene 有权
标题翻译：包含2,3-二氯-1,1,1-三氟丙烷，2-氯-1,1,1-三氟丙烯，2-氯-1,1,1,2-四氟丙烷或2,3,3,3-四氯丙烷的组合物，四氟丙烯
公开(公告)号：US08877086B2
公开(公告)日：2014-11-04
申请号：US12937661
申请日：2009-05-07
申请人： Barry Asher Mahler , Mario Joseph Nappa
发明人： Barry Asher Mahler , Mario Joseph Nappa
IPC分类号： C09K5/04 , F25D3/10 , C07C21/04 , C07C19/10 , C07C17/04 , C08J9/14 , C07C19/12 , C07C21/18 , C07C17/20 , C09K3/30 , C07C19/08 , C07C17/087 , C07C17/25
CPC分类号： C09K5/044 , A62D1/0028 , A62D1/0057 , A62D1/0092 , B01F17/0035 , B01F17/0085 , C07C17/04 , C07C17/087 , C07C17/204 , C07C17/206 , C07C17/23 , C07C17/25 , C07C19/08 , C07C19/10 , C07C19/12 , C07C21/04 , C07C21/18 , C08J9/144 , C08J9/146 , C08J9/149 , C08J2203/14 , C08J2203/142 , C08J2203/144 , C08J2203/164 , C09K3/00 , C09K3/30 , C09K5/045 , C09K5/048 , C09K21/08 , C09K2205/12 , C09K2205/122 , C09K2205/126 , C09K2205/22 , C11D7/30 , H01B3/56
摘要： Disclosed are compositions comprising HCFC-243db, HCFO-1233xf, HCFC-244db and/or HFO-1234yf and at least one additional compound. For the composition comprising 1234yf, the additional compound is selected from the group consisting of HFO-1234ze, HFO-1243zf, HCFC-243db, HCFC-244db, HFC-245cb, HFC-245fa, HCFO-1233xf, HCFO-1233zd, HCFC-253fb, HCFC-234ab, HCFC-243fa, ethylene, HFC-23, CFC-13, HFC-143a, HFC-152a, HFC-236fa, HCO-1130, HCO-1130a, HFO-1336, HCFC-133a, HCFC-254fb, HCFC-1131, HFO-1141, HCFO-1242zf, HCFO-1223xd, HCFC-233ab, HCFC-226ba, and HFC-227ca. Compositions comprising HCFC-243db, HCFO-1233xf, and/or HCFC-244db are useful in processes to make HFO-1234yf. Compositions comprising HFO-1234yf are useful, among other uses, as heat transfer compositions for use in refrigeration, air-conditioning and heat pump systems.
摘要翻译：公开了包含HCFC-243db，HCFO-1233xf，HCFC-244db和/或HFO-1234yf和至少一种另外的化合物的组合物。对于包含1234yf的组合物，附加化合物选自HFO-1234ze，HFO-1243zf，HCFC-243db，HCFC-244db，HFC-245cb，HFC-245fa，HCFO-1233xf，HCFO-1233zd，HCFC- 253fb，HCFC-234ab，HCFC-243fa，乙烯，HFC-23，CFC-13，HFC-143a，HFC-152a，HFC-236fa，HCO-1130，HCO-1130a，HFO-1336，HCFC-133a， 254fb，HCFC-1131，HFO-1141，HCFO-1242zf，HCFO-1223xd，HCFC-233ab，HCFC-226ba和HFC-227ca。包含HCFC-243db，HCFO-1233xf和/或HCFC-244db的组合物可用于制备HFO-1234yf的方法。包括HFO-1234yf的组合物在其它用途中可用作用于制冷，空调和热泵系统的热传递组合物。

2. 发明授权

US08314273B2 Production processes for making 1,1,1,2,2,3-hexafluoropropane 失效
标题翻译：制备1,1,1,2,2,3-六氟丙烷的制备方法
公开(公告)号：US08314273B2
公开(公告)日：2012-11-20
申请号：US12439575
申请日：2007-09-04
申请人： Barry Asher Mahler , Xuehui Sun , Velliyur Nott Mallikarjuna Rao
发明人： Barry Asher Mahler , Xuehui Sun , Velliyur Nott Mallikarjuna Rao
IPC分类号： C07C17/266
CPC分类号： C07C17/278 , C07C19/08
摘要： A process for making HFC-236cb is disclosed. The process comprises reacting TFE with HFC-32 in the presence of at least one co-product and a suitable catalyst to produce a product mixture comprising HFC-236cb, wherein the total amount of the at least one co-product is at least 10 ppmv based on the total amount of the tetrafluoroethylene, the difluoromethane and the at least one co-product.
摘要翻译：公开了制备HFC-236cb的方法。该方法包括在至少一种共同产物和合适的催化剂的存在下使TFE与HFC-32反应以产生包含HFC-236cb的产物混合物，其中至少一种副产物的总量至少为10ppmv 基于四氟乙烯，二氟甲烷和至少一种副产物的总量。

3. 发明授权

US08232435B2 1,2,3,3,3-pentafluoropropene production processes 有权
标题翻译： 1,2,3,3,3-五氟丙烯生产工艺
公开(公告)号：US08232435B2
公开(公告)日：2012-07-31
申请号：US12440046
申请日：2007-09-05
申请人： Allen Capron Sievert , Mario Joseph Nappa , Barry Asher Mahler
发明人： Allen Capron Sievert , Mario Joseph Nappa , Barry Asher Mahler
IPC分类号： C07C17/00
CPC分类号： C07C17/25 , Y02P20/582 , C07C21/18
摘要： The present disclosure relates to a new and efficient manufacturing process for the production of HFC-1225ye. The process involves contacting at least one hexafluoropropane selected from the group consisting of 1,1,1,2,2,3-hexafluoropropane and 1,1,1,2,3,3-hexafluoropropane with a suitable catalyst in a reactor to obtain a product mixture containing HFC-1225ye (1,2,3,3,3-pentafluoropropene) where the pressure in the reactor ranges from about 0.5 psig to about 100 psig.
摘要翻译：本公开涉及用于生产HFC-1225ye的新的和有效的制造方法。该方法包括将至少一种选自1,1,1,2,2,3-六氟丙烷和1,1,1,2,3,3-六氟丙烷的六氟丙烷与合适的催化剂在反应器中接触以获得含有HFC-1225ye（1,2,3,3,3-五氟丙烯）的产物混合物，其中反应器中的压力为约0.5psig至约100psig。

4. 发明申请

US20120165578A1 COMPOSITIONS COMPRISING 1,1,1,2,3-PENTAFLUOROPROPANE OR 2,3,3,3- TETRAFLUOROPROPENE 有权
标题翻译：包含1,1,1,2,3-二芳基或2,3,3,3-四氯丙烯的组合物
公开(公告)号：US20120165578A1
公开(公告)日：2012-06-28
申请号：US13408686
申请日：2012-02-29
申请人： Barry Asher MAHLER , Mario Joseph NAPPA , Jeffrey P. KNAPP
发明人： Barry Asher MAHLER , Mario Joseph NAPPA , Jeffrey P. KNAPP
IPC分类号： C07C21/18 , C07C19/08
CPC分类号： C09K5/00 , B01J27/125 , B01J37/26 , C07C17/25 , C07C17/354 , C07C21/18 , C07C21/22 , C08J9/146 , C08J9/149 , C09K3/30 , C09K5/045 , C09K2205/12 , C09K2205/126 , C07C19/08
摘要： Disclosed are compositions comprising HFC-245eb and at least one additional compound selected from the group consisting of HFO-1234ze, HFC-245fa, HFC-236cb, HFC-236ea, HFC-236fa, HFC-227ea, HFC-227ca, HFO-1225yc, HFO-1225zc, HFO-1225ye, methane, ethane, propane, HFC-23, HFC-143a, HFC-134, HFC-134a, FC-1216, HFO-1234yf, HFC-254eb, HFO-1243zf, and HFC-254fb. Compositions comprising HFC-245eb are useful in processes to make HFO-1234yf. Also disclosed are compositions comprising HFO-1234yf and at least one additional compound selected from the group consisting of HFO-1234ze, HFC-254eb, HFC-254fb, HFO-1243zf, HFCHFC-245eb, HFC-245fa, HFC-245cb, HFC-236cb, HFC-236ea, HFC-236fa, HFC-227ea, HFC-227ca, HFO-1225yc, HFO-1225zc, HFO-1225ye, methane, ethane, propane, HFC-23, HFC-134, HFC-134a, HFO-1132a and FC-1216. Compositions comprising HFO-1234yf are useful as heat transfer compositions for use in refrigeration, air-conditioning and heat pump systems.
摘要翻译：公开了包含HFC-245eb和至少一种选自HFO-1234ze，HFC-245fa，HFC-236cb，HFC-236ea，HFC-236fa，HFC-227ea，HFC-227ca，HFO-1225yc ，HFO-1225zc，HFO-1225ye，甲烷，乙烷，丙烷，HFC-23，HFC-143a，HFC-134，HFC-134a，FC-1216，HFO-1234yf，HFC-254eb，HFO-1243zf和HFC- 254fb。包含HFC-245eb的组合物可用于制备HFO-1234yf的方法。还公开了包含HFO-1234yf和至少一种选自HFO-1234ze，HFC-254eb，HFC-254fb，HFO-1243zf，HFCHFC-245eb，HFC-245fa，HFC-245cb，HFC- 236cb，HFC-236ea，HFC-236fa，HFC-227ea，HFC-227ca，HFO-1225yc，HFO-1225zc，HFO-1225ye，甲烷，乙烷，丙烷，HFC-23，HFC-134，HFC-134a， 1132a和FC-1216。包含HFO-1234yf的组合物可用作用于制冷，空调和热泵系统的热转印组合物。

5. 发明授权

US08066899B2 Non-ignitable gaseous composition comprising difluoromethane and tetrafluoroethylene 有权
标题翻译：包含二氟甲烷和四氟乙烯的不可燃气体组合物
公开(公告)号：US08066899B2
公开(公告)日：2011-11-29
申请号：US12439565
申请日：2007-09-04
申请人： Barry Asher Mahler
发明人： Barry Asher Mahler
IPC分类号： C09K5/04
CPC分类号： C07C19/08 , C07C17/42 , C07C21/185
摘要： The present disclosure relates to non-ignitable gaseous compositions comprising difluoromethane and tetrafluoroethylene. When the pressure is at least 150 psig, the molar percentage of tetrafluoroethylene in the non-ignitable gaseous composition is no more than 111.6−0.124X. When the pressure is less than 150 psig, the molar percentage of tetrafluoroethylene in the non-ignitable gaseous composition is no more than 102−0.06X. X is the pressure in the unit of psig.The present disclosure also provides processes for making such non-ignitable gaseous compositions.Also disclosed are azeotropic compositions of TFE and HFC-32.
摘要翻译：本公开涉及包含二氟甲烷和四氟乙烯的不可燃气体组合物。当压力至少为150psig时，不燃点气体组合物中四氟乙烯的摩尔百分数不超过111.6-0.124X。当压力小于150psig时，不燃性气体组合物中四氟乙烯的摩尔百分比不大于102-0.06X。 X是以psig为单位的压力。本公开还提供了制备这种不可燃气体组合物的方法。还公开了TFE和HFC-32的共沸组合物。

6. 发明申请

US20110031436A1 COMPOSITIONS COMPRISING 2,3-DICHLORO-1,1,1-TRIFLUOROPROPANE, 2-CHLORO-1,1,1-TRIFLUOROPROPENE, 2-CHLORO-1,1,1,2-TETRAFLUOROPROPANE OR 2,3,3,3-TETRAFLUOROPROPENE 有权
标题翻译：包含2,3-二氯-1,1,1-三氟硼酸的组合物，2-氯代-1,1,1-三氟丙烯，2-氯代-1,1,1,2-四氢吡喃，或2,3,3,3-四氢 - 四氯丙烯
公开(公告)号：US20110031436A1
公开(公告)日：2011-02-10
申请号：US12937661
申请日：2009-05-07
申请人： Barry Asher Mahler , Mario Joseph Nappa
发明人： Barry Asher Mahler , Mario Joseph Nappa
IPC分类号： C09K5/00
CPC分类号： C09K5/044 , A62D1/0028 , A62D1/0057 , A62D1/0092 , B01F17/0035 , B01F17/0085 , C07C17/04 , C07C17/087 , C07C17/204 , C07C17/206 , C07C17/23 , C07C17/25 , C07C19/08 , C07C19/10 , C07C19/12 , C07C21/04 , C07C21/18 , C08J9/144 , C08J9/146 , C08J9/149 , C08J2203/14 , C08J2203/142 , C08J2203/144 , C08J2203/164 , C09K3/00 , C09K3/30 , C09K5/045 , C09K5/048 , C09K21/08 , C09K2205/12 , C09K2205/122 , C09K2205/126 , C09K2205/22 , C11D7/30 , H01B3/56
摘要： Disclosed are compositions comprising HCFC-243db, HCFO-1233xf, HCFC-244db and/or HFO-1234yf and at least one additional compound. For the composition comprising 1234yf, the additional compound is selected from the group consisting of HFO-1234ze, HFO-1243zf, HCFC-243db, HCFC-244db, HFC-245cb, HFC-245fa, HCFO-1233xf, HCFO-1233zd, HCFC-253fb, HCFC-234ab, HCFC-243fa, ethylene, HFC-23, CFC-13, HFC-143a, HFC-152a, HFC-236fa, HCO-1130, HCO-1130a, HFO-1336, HCFC-133a, HCFC-254fb, HCFC-1131, HFO-1141, HCFO-1242zf, HCFO-1223xd, HCFC-233ab, HCFC-226ba, and HFC-227ca. Compositions comprising HCFC-243db, HCFO-1233xf, and/or HCFC-244db are useful in processes to make HFO-1234yf. Compositions comprising HFO-1234yf are useful, among other uses, as heat transfer compositions for use in refrigeration, air-conditioning and heat pump systems.
摘要翻译：公开了包含HCFC-243db，HCFO-1233xf，HCFC-244db和/或HFO-1234yf和至少一种另外的化合物的组合物。对于包含1234yf的组合物，附加化合物选自HFO-1234ze，HFO-1243zf，HCFC-243db，HCFC-244db，HFC-245cb，HFC-245fa，HCFO-1233xf，HCFO-1233zd，HCFC- 253fb，HCFC-234ab，HCFC-243fa，乙烯，HFC-23，CFC-13，HFC-143a，HFC-152a，HFC-236fa，HCO-1130，HCO-1130a，HFO-1336，HCFC-133a， 254fb，HCFC-1131，HFO-1141，HCFO-1242zf，HCFO-1223xd，HCFC-233ab，HCFC-226ba和HFC-227ca。包含HCFC-243db，HCFO-1233xf和/或HCFC-244db的组合物可用于制备HFO-1234yf的方法。包括HFO-1234yf的组合物在其它用途中可用作用于制冷，空调和热泵系统的热传递组合物。

7. 发明申请

US20090278075A1 COMPOSITIONS COMPRISING 1,1,1,2,3-PENTAFLUOROPROPANE OR 2,3,3,3- TETRAFLUOROPROPENE 有权
标题翻译：包含1,1,1,2,3-二芳基或2,3,3,3-四氯丙烯的组合物
公开(公告)号：US20090278075A1
公开(公告)日：2009-11-12
申请号：US12437014
申请日：2009-05-07
申请人： Barry Asher Mahler , Mario Joseph Nappa , Jeffrey P. Knapp
发明人： Barry Asher Mahler , Mario Joseph Nappa , Jeffrey P. Knapp
IPC分类号： C09K5/00
CPC分类号： C09K5/00 , B01J27/125 , B01J37/26 , C07C17/25 , C07C17/354 , C07C21/18 , C07C21/22 , C08J9/146 , C08J9/149 , C09K3/30 , C09K5/045 , C09K2205/12 , C09K2205/126 , C07C19/08
摘要： Disclosed are compositions comprising HFC-245eb and at least one additional compound selected from the group consisting of HFO-1234ze, HFC-245fa, HFC-236cb, HFC-236ea, HFC-236fa, HFC-227ea, HFC-227ca, HFO-1225yc, HFO-1225zc, HFO-1225ye, methane, ethane, propane, HFC-23, HFC-143a, HFC-134, HFC-134a, FC-1216, HFO-1234yf, HFC-254eb, HFO-1243zf, and HFC-254fb. Compositions comprising HFC-245eb are useful in processes to make HFO-1234yf. Also disclosed are compositions comprising HFO-1 234yf and at least one additional compound selected from the group consisting of HFO-1234ze, HFC-254eb, HFC-254fb, HFO-1243zf, HFCHFC-245eb, HFC-245fa, HFC-245cb, HFC-236cb, HFC-236ea, HFC-236fa, HFC-227ea, HFC-227ca, HFO-1225yc, HFO-1225zc, HFO-1225ye, methane, ethane, propane, HFC-23, HFC-134, HFC-134a, HFO-1132a and FC-1216. Compositions comprising HFO-1234yf are useful as heat transfer compositions for use in refrigeration, air-conditioning and heat pump systems.
摘要翻译：公开了包含HFC-245eb和至少一种选自HFO-1234ze，HFC-245fa，HFC-236cb，HFC-236ea，HFC-236fa，HFC-227ea，HFC-227ca，HFO-1225yc ，HFO-1225zc，HFO-1225ye，甲烷，乙烷，丙烷，HFC-23，HFC-143a，HFC-134，HFC-134a，FC-1216，HFO-1234yf，HFC-254eb，HFO-1243zf和HFC- 254fb。包含HFC-245eb的组合物可用于制备HFO-1234yf的方法。还公开了包含HFO-123 234ff和至少一种选自HFO-1234ze，HFC-254eb，HFC-254fb，HFO-1243zf，HFCHFC-245eb，HFC-245fa，HFC-245cb，HFC -236cb，HFC-236ea，HFC-236fa，HFC-227ea，HFC-227ca，HFO-1225yc，HFO-1225zc，HFO-1225ye，甲烷，乙烷，丙烷，HFC-23，HFC-134，HFC-134a， -1132a和FC-1216。包含HFO-1234yf的组合物可用作用于制冷，空调和热泵系统的热转印组合物。

8. 发明授权

US5827492A Hydrogen chloride purification process 失效
标题翻译：氯化氢净化工艺
公开(公告)号：US5827492A
公开(公告)日：1998-10-27
申请号：US481516
申请日：1995-07-26
申请人： David R. Corbin , Barry Asher Mahler
发明人： David R. Corbin , Barry Asher Mahler
IPC分类号： B01D53/04 , C01B7/07 , B01D53/00
CPC分类号： C01B7/0725 , B01D53/04 , C01B7/0718 , B01D2253/102 , B01D2253/106 , B01D2253/108 , B01D2253/308 , B01D2257/206 , B01D2257/2064 , B01D2257/2066 , B01D2259/40083 , B01D53/0462 , B01D53/047 , Y02P20/154 , Y10S95/901
摘要： A process is disclosed for purifying an impure HCl containing at least one saturated or olefinic impurity of the formula C.sub.a H.sub.b Cl.sub.c F.sub.d (wherein a is an integer from 1 to 4, b and c are each integers from 0 to 9, and d is an integer from 1 to 10; provided b+c+d=2a+2 for acyclic compounds and b+c+d=2a for cyclic compounds and olefinic compounds) which comprises the step of contacting the impure HCl with a sorbent for said impurities selected from activated carbons and inorganic molecular sieves (e.g., silicalites and zeolites) at a temperature and a pressure suitable for sorption for a period of time sufficient to remove a substantial amount of said impurities.
摘要翻译： PCT No.PCT / US93 / 00455 Sec。 371日期：1995年7月26日 102（e）日期1995年7月26日PCT提交1993年1月28日PCT公布。第WO94 / 16988号公报日期1994年8月4日公开了一种纯化含有至少一种式CaHbClcFd饱和或烯烃杂质的不纯的HCl的方法（其中a为1至4的整数，b和c各自为0至9的整数，d 是1至10的整数;对于环状化合物和烯烃化合物，b + c + d = 2a + 2，对于环状化合物和烯烃化合物，b + c + d = 2a），其包括使不纯的HCl与所述在活性碳和无机分子筛（例如，硅沸石和沸石）中的杂质在适于吸附的温度和压力下足以除去大量所述杂质的时间。

9. 发明授权

US5723699A Purification process for hexafluoroethane products 失效
标题翻译：六氟乙烷产品净化过程
公开(公告)号：US5723699A
公开(公告)日：1998-03-03
申请号：US789173
申请日：1997-01-24
申请人： Ralph Newton Miller , Mark Richard Deschere , Barry Asher Mahler , Olagappan Muthu
发明人： Ralph Newton Miller , Mark Richard Deschere , Barry Asher Mahler , Olagappan Muthu
IPC分类号： C07C17/383 , C01B7/07 , C01B7/19 , C07C17/38 , C07C17/386 , C07C19/08
CPC分类号： C07C19/08 , C01B7/0712 , C01B7/196 , C07C17/38 , C07C17/386 , Y02P20/582
摘要： The disclosure relates to removing impurities from hexafluoroethane (CF.sub.3 CF.sub.3), also known as Perfluorocarbon 116 (PFC-116) or Fluorocarbon 116 (FC-116), by using azeotropic distillation such that an overhead product consisting essentially of HCl-hexafluoroethane is formed, optionally combined with a phase separation step to break the HCl-hexafluoroethane azeotropic or azeotrope-like composition thereby permitting recovery of substantially pure hexafluoroethane. Unreacted hydrogen fluoride (HF) may be removed from hexafluoroethane during the above azeotropic distillation with HCl or alternatively by an azeotropic distillation wherein an HF-hexafluoroethane azeotropic or azeotrope-like composition exits overhead and substantially pure HF exits in the bottoms stream.
摘要翻译：本公开涉及通过共沸蒸馏从六氟乙烷（CF 3 CF 3）（也称为全氟化碳116（PFC-116）或氟碳116（FC-116））除去杂质，从而形成基本上由HCl-六氟乙烷组成的塔顶馏出物结合相分离步骤以破坏HCl-六氟乙烷共沸或类共沸组合物，从而允许回收基本上纯的六氟乙烷。在HCl的上述共沸蒸馏过程中，可以从六氟乙烷中除去未反应的氟化氢（HF），或者通过共沸蒸馏除去六氟乙烷，其中HF-六氟乙烷共沸或类共沸组合物离开塔顶馏出物，基本上纯的HF在塔底物流中离开。

10. 发明授权

US08147709B2 Compositions comprising 3,3,3-trifluoropropyne 有权
标题翻译：包含3,3,3-三氟丙炔的组合物
公开(公告)号：US08147709B2
公开(公告)日：2012-04-03
申请号：US12437014
申请日：2009-05-07
申请人： Barry Asher Mahler , Mario Joseph Nappa , Jeffrey P. Knapp
发明人： Barry Asher Mahler , Mario Joseph Nappa , Jeffrey P. Knapp
IPC分类号： C09K5/04
CPC分类号： C09K5/00 , B01J27/125 , B01J37/26 , C07C17/25 , C07C17/354 , C07C21/18 , C07C21/22 , C08J9/146 , C08J9/149 , C09K3/30 , C09K5/045 , C09K2205/12 , C09K2205/126 , C07C19/08
摘要： Disclosed are compositions comprising HFC-245eb and at least one additional compound selected from the group consisting of HFO-1234ze, HFC-245fa, HFC-236cb, HFC-236ea, HFC-236fa, HFC-227ea, HFC-227ca, HFO-1225yc, HFO-1225zc, HFO-1225ye, methane, ethane, propane, HFC-23, HFC-143a, HFC-134, HFC-134a, FC-1216, HFO-1234yf, HFC-254eb, HFO-1243zf, and HFC-254fb. Compositions comprising HFC-245eb are useful in processes to make HFO-1234yf. Also disclosed are compositions comprising HFO-1234yf and at least one additional compound selected from the group consisting of HFO-1234ze, HFC-254eb, HFC-254fb, HFO-1243zf, HFCHFC-245eb, HFC-245fa, HFC-245cb, HFC-236cb, HFC-236ea, HFC-236fa, HFC-227ea, HFC-227ca, HFO-1225yc, HFO-1225zc, HFO-1225ye, methane, ethane, propane, HFC-23, HFC-134, HFC-134a, HFO-1132a and FC-1216. Compositions comprising HFO-1234yf are useful as heat transfer compositions for use in refrigeration, air-conditioning and heat pump systems.
摘要翻译：公开了包含HFC-245eb和至少一种选自HFO-1234ze，HFC-245fa，HFC-236cb，HFC-236ea，HFC-236fa，HFC-227ea，HFC-227ca，HFO-1225yc ，HFO-1225zc，HFO-1225ye，甲烷，乙烷，丙烷，HFC-23，HFC-143a，HFC-134，HFC-134a，FC-1216，HFO-1234yf，HFC-254eb，HFO-1243zf和HFC- 254fb。包含HFC-245eb的组合物可用于制备HFO-1234yf的方法。还公开了包含HFO-1234yf和至少一种选自HFO-1234ze，HFC-254eb，HFC-254fb，HFO-1243zf，HFCHFC-245eb，HFC-245fa，HFC-245cb，HFC- 236cb，HFC-236ea，HFC-236fa，HFC-227ea，HFC-227ca，HFO-1225yc，HFO-1225zc，HFO-1225ye，甲烷，乙烷，丙烷，HFC-23，HFC-134，HFC-134a， 1132a和FC-1216。包含HFO-1234yf的组合物可用作用于制冷，空调和热泵系统的热转印组合物。

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