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1. 发明授权

US6034026A Procatalyst for ethylene polymer production, method for its preparation and use 失效
标题翻译：用于乙烯聚合物生产的主催化剂，其制备和使用方法
公开(公告)号：US6034026A
公开(公告)日：2000-03-07
申请号：US14674
申请日：1998-01-28
申请人： Thomas Garoff , Solveig Johansson , Ulf Palmqvist , Daniel Lindgren , Marita Sutela , Paivi Waldvogel , Arja Kostiainen
发明人： Thomas Garoff , Solveig Johansson , Ulf Palmqvist , Daniel Lindgren , Marita Sutela , Paivi Waldvogel , Arja Kostiainen
IPC分类号： C08F4/654 , B01J37/00 , C08F4/02 , C08F4/64 , C08F4/646 , C08F4/651 , C08F4/655 , C08F4/658 , C08F10/00 , C08F10/02 , C08F110/02 , C08F110/06 , B01J31/00
CPC分类号： C08F110/02 , C08F110/06
摘要： The invention relates to a process for the preparation of a high activity procatalyst for the production of ethylene polymers. The process according to the present invention comprises the following steps:(a) contacting the inorganic support with an alkyl metal chloride which is soluble in non-polar hydrocarbon solvents, and has the formula(R.sub.n MeCl.sub.3-n).sub.m (1)wherein R is a C.sub.1 -C.sub.20 aklyl group, Me is a metal of group III(13) of the periodic table, n=1 or 2 and m=1 or 2, to give a first reaction product,(b) contacting said first reaction product with a compound or mixture containing hydrocarbyl and hydrocarbyl oxide linked to magnesium which is soluble in non-polar hydrocarbon solvents, to give a second reaction product, and(c) contacting said second reaction product with a titanium compound which contains chlorine, having the formulaCl.sub.x Ti(OR.sup.IV).sub.4-x (2)wherein R.sup.IV is a C.sub.2 -C.sub.20 hydrocarbyl group and x is 3 or 4, to give said procatalyst.
摘要翻译：本发明涉及制备用于生产乙烯聚合物的高活性前催化剂的方法。根据本发明的方法包括以下步骤：（a）使无机载体与可溶于非极性烃溶剂的烷基金属氯化物接触，并具有式（RnMeCl 3-n）m（1）其中R为 C 1 -C 20亚烷基，Me是周期表III（13）的金属，n = 1或2，m = 1或2，得到第一反应产物，（b）使所述第一反应产物与与可溶于非极性烃溶剂的镁连接的烃基和烃基氧化物的化合物或混合物，得到第二反应产物，和（c）使所述第二反应产物与含有氯的钛化合物接触，所述钛化合物具有式Cl x Ti（ ORIV）4-x（2）其中RIV为C 2 -C 20烃基，x为3或4，得到所述前催化剂。

2. 发明授权

US5480849A Method for the preparation of a polymerizing catalyst component, a polymerizing catalyst component prepared by the method and its use 失效
标题翻译：制备聚合催化剂组分的方法，通过该方法制备的聚合催化剂组分及其用途
公开(公告)号：US5480849A
公开(公告)日：1996-01-02
申请号：US75596
申请日：1993-08-16
申请人： Bill Gustafsson , Arja Kostiainen , Pekka Sormunen
发明人： Bill Gustafsson , Arja Kostiainen , Pekka Sormunen
IPC分类号： C08F4/02 , C08F4/61 , C08F10/00 , B01J31/12 , C08F2/00 , C08F4/42
CPC分类号： C08F10/00
摘要： The invention relates to a process for the preparation of a solid procatalyst composition of a catalyst system for the polymerization of olefins wherein a magnesium halide such as magnesium chloride is dissolved and/or suspended into an alkyl ester of a monocarboxylic acid such as ethyl acetate, impregnated to a carrier, treated with an organometallic compound or a silicon compound and thereafter with a transition metal compound. The invention also relates to a procatalyst composition and its use together with a cocatalyst for the polymerization of olefins. The activity has been enhanced according to the invention by the use of a carrier containing hydroxyl groups, which carrier is kept at a temperature of at most about 200.degree. C. prior to the impregnation so that the hydroxyl groups are retained in the carrier to an essential extent until the impregnation step. The carrier is preferably silica which is treated thermally at 100.degree.-200.degree. C. so that the water present is removed but the hydroxyl groups are retained to a considerable extent. The organometal compound is preferably an aluminumalkyl compound such as triethylaluminum, and the transition metal compound is preferably titanium tetrachloride.
摘要翻译： PCT No.PCT / FI91 / 00391 Sec。 371日期：1993年8月16日 102（e）日期1993年8月16日PCT 1991年12月17日PCT PCT。公开号WO92 / 11296 日本1992年7月9日。本发明涉及一种制备用于烯烃聚合的催化剂体系的固体前催化剂组合物的方法，其中将卤化镁如氯化镁溶解和/或悬浮于一元羧酸如乙酸乙酯，浸渍到载体上，用有机金属化合物或硅化合物处理，然后用过渡金属化合物处理。本发明还涉及前催化剂组合物及其与烯烃聚合用助催化剂的使用。通过使用含有羟基的载体，根据本发明增强了活性，该载体在浸渍之前保持在至多约200℃的温度，使得羟基保留在载体中至必不可少的程度，直到浸渍步骤。载体优选二氧化硅，其在100-200℃下热处理，以便除去存在的水，但羟基保留在相当大的程度上。有机金属化合物优选为三乙基铝等铝烷基化合物，过渡金属化合物优选为四氯化钛。

3. 发明授权

US5770540A Procatalyst for ethylene polymer production, method for its preparation and use 失效
标题翻译：用于乙烯聚合物生产的主催化剂，其制备和使用方法
公开(公告)号：US5770540A
公开(公告)日：1998-06-23
申请号：US492799
申请日：1995-06-20
申请人： Thomas Garoff , Solveig Johansson , Ulf Palmqvist , Daniel Lindgren , Marita Sutela , Paivi Waldvogel , Arja Kostiainen
发明人： Thomas Garoff , Solveig Johansson , Ulf Palmqvist , Daniel Lindgren , Marita Sutela , Paivi Waldvogel , Arja Kostiainen
IPC分类号： C08F4/06 , C08F4/655 , C08F110/02 , C08F110/06 , B01J31/00
CPC分类号： C08F4/6555 , C08F110/02 , C08F110/06
摘要： The invention relates to a procatalyst for the production of ethylene polymers, which procatalyst comprises an inorganic support, a chlorine compound carried on said support, a magnesium compound carried on said support, a titanium compound carried on said support, whereby the chlorine compound can be different from or the same as the magnesium compound and/or the titanium compound. The activity balance AB of the procatalyst in specified polymerization conditions, is AB>3.2 wherein AB=�(A+A'):2!.multidot.�log (MFR.sub.2 ':MFR.sub.2):(A-A')!, A means polymerization activity expressed an kg PE/g cat .multidot.h, MFR.sub.2 means the melt flow rate in g/min units at a load of 2,16 kg, according to the standard ISO 1133, the absence of the upper index ' means low melt flow rate polymerization and the presence of the upper index ' means high melt flow polymerization. This means that the catalyst activity is relatively independent of the presence of chain transfer agents.
摘要翻译：本发明涉及一种用于生产乙烯聚合物的前催化剂，其主催化剂包括无机载体，载体上携带的氯化合物，载体上的镁化合物，载于所述载体上的钛化合物，其中氯化合物可以是与镁化合物和/或钛化合物不同或相同。在规定的聚合条件下，前催化剂的活性平衡AB为AB> 3.2其中AB = [（A + A'）：2] x [log（MFR 2'：MFR 2）:( A-A'）]]，A表示聚合活性表示kg PE / g cat xh，MFR2是指根据ISO 1133标准，在2,16kg载荷下的熔体流动速率，单位为g / min，上限指数为“低熔体流动速率聚合”，上指数的存在意味着高熔体流动聚合。这意味着催化剂活性相对独立于链转移剂的存在。

4. 发明授权

US5413979A Method for the preparation of a catalyst component for the polymerization of olefins, a polymerization catalyst component produced by the method and use of the same 失效
标题翻译：制备烯烃聚合用催化剂组分的方法，通过该方法制备的聚合催化剂组分及其用途
公开(公告)号：US5413979A
公开(公告)日：1995-05-09
申请号：US856967
申请日：1992-06-16
申请人： Arja Kostiainen , Bill Gustafsson , Pekka Sormunen
发明人： Arja Kostiainen , Bill Gustafsson , Pekka Sormunen
IPC分类号： C08F4/658 , C08F4/60 , C08F10/00 , B01J31/00
CPC分类号： C08F10/00
摘要： The invention relates to a method for the preparation of a solid procatalyst composition for a catalyst system intended for the polymerization of olefins, wherein a magnesium halide, such as magnesium chloride, is dissolved and/or slurried in a mono-carboxylic acid alkyl ester, such as ethyl acetate, is impregnated into a support material, dried, treated with an organometallic compound or a silicon compound and thereafter with a transition metal compound. The invention also relates to such a procatalyst composition and its use together with a cocatalyst for the polymerization of olefins. According to the invention it has been possible to increase the activity of the catalyst composition by using a silanated support material, such as silanated silica, which is then treated with an organometallic or silicon compound before treatment with a transition metal compound. The silanated silica is preferably a silicon dioxide which has been heat-treated at 1000.degree.-200.degree. and thereafter treated with hexamethyldisilazane and contains 3-6% carbon. The organometallic compound is preferably an aluminum alkyl compound, such as triethylaluminum, and the transition metal compound is preferably titanium tetrachloride.
摘要翻译： PCT No.PCT / FI90 / 00279 Sec。 371日期：1992年6月16日 102（e）日期1992年6月16日PCT 1990年11月20日PCT PCT。公开号WO91 / 07443 日本1991年5月30日本发明涉及一种制备用于烯烃聚合的催化剂体系的固体前催化剂组合物的方法，其中卤化镁如氯化镁以单体形式溶解和/或浆化羧酸烷基酯如乙酸乙酯浸渍到载体材料中，干燥，用有机金属化合物或硅化合物处理，然后用过渡金属化合物处理。本发明还涉及这种前催化剂组合物及其与烯烃聚合用助催化剂的使用。根据本发明，可以通过使用硅烷化载体材料如硅烷化二氧化硅来提高催化剂组合物的活性，然后用过渡金属化合物处理之前用有机金属或硅化合物处理。硅烷化二氧化硅优选是在1000℃-200℃下热处理的二氧化硅，然后用六甲基二硅氮烷处理并含有3-6％的碳。有机金属化合物优选为烷基铝化合物，例如三乙基铝，过渡金属化合物优选为四氯化钛。

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