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1. 发明授权

US5104630A Processes for removing carbonyl sulfide from hydrocarbon feedstreams 失效
标题翻译：从烃类进料流中除去羰基硫的方法
公开(公告)号：US5104630A
公开(公告)日：1992-04-14
申请号：US611565
申请日：1990-11-13
申请人： Ervine S. Holmes , Alexander J. Kosseim
发明人： Ervine S. Holmes , Alexander J. Kosseim
IPC分类号： B01D53/14
CPC分类号： B01D53/1406 , Y02C10/06
摘要： Processes are disclosed for purifying hydrocarbon feedstreams, e.g, natural gas, to remove carbonyl sulfide and other acid gases such as carbon dioxide and hydrogen sulfide. The processes employ a conversion step to convert carbonyl sulfide to hydrogen sulfide and carbon dioxide followed by an absorption step to remove the carbon dioxide and hydrogen sulfide from the feedstream. Carbonyl sulfide is converted to carbon dioxide and hydrogen sulfide in the presence of an aqueous alkaline solution which preferably has the same composition as the absorption solution used in the absorption step.
摘要翻译：公开了用于纯化烃进料流（例如天然气）以除去羰基硫化物和其它酸性气体如二氧化碳和硫化氢的方法。该方法采用转化步骤，将羰基硫化物转化为硫化氢和二氧化碳，然后进行吸收步骤以从进料流中除去二氧化碳和硫化氢。在优选与吸收步骤中使用的吸收溶液具有相同组成的碱性水溶液的存在下，将羰基硫化物转化为二氧化碳和硫化氢。

2. 发明授权

US4764354A Alkanolamine gas treating process for a feedstream containing hydrogen sulfide 失效
标题翻译：含有硫化氢的原料流的烷醇胺气体处理方法
公开(公告)号：US4764354A
公开(公告)日：1988-08-16
申请号：US10819
申请日：1987-02-04
申请人： Daniel J. Kubek , John G. McCullough , Kenneth J. Barr , Alexander J. Kosseim
发明人： Daniel J. Kubek , John G. McCullough , Kenneth J. Barr , Alexander J. Kosseim
IPC分类号： B01D53/14 , C01B17/16 , C23F11/04
CPC分类号： C01B17/167 , B01D53/1468 , B01D53/1493
摘要： In an alkanolamine gas treating process for removing acid gas from a feedstream in which hydrogen sulfide is present, reduced corrosion of steel parts or components is observed when solution concentrations of hydrogen sulfide and vanadium in the plus five valence state are maintained above certain minimum levels.
摘要翻译：在从其中存在硫化氢的进料流中除去酸性气体的链烷醇胺气体处理方法中，当加号5价态的硫化氢和钒的溶液浓度保持在某些最低水平以上时，可观察到钢部件或组分的腐蚀减少。

3. 发明授权

US4170628A Process for removing SO.sub.2 from effluent gases and for removing heat stable salts from systems in which they accumulate using an anion exchange resin 失效
标题翻译：从排出气体中除去SO（HD 2 {B）并从使用阴离子交换树脂积累的系统除去热稳定盐的方法
公开(公告)号：US4170628A
公开(公告)日：1979-10-09
申请号：US910521
申请日：1978-05-30
申请人： Alexander J. Kosseim , David A. Dunnery , Gilbert R. Atwood
发明人： Alexander J. Kosseim , David A. Dunnery , Gilbert R. Atwood
IPC分类号： B01D53/50 , C01B17/00
CPC分类号： B01D53/501 , B01D53/50
摘要： Improvement in processes for the selective removal of sulfur dioxide with respect to carbon dioxide from a gas mixture containing same wherein the gas mixture is contacted with an aqueous absorbent solution, such as alkanolamine, alkali metal hydroxide, ammonium hydroxide or sulfites thereof, to remove sulfur dioxide from the gas mixture and form a SO.sub.2 -rich aqueous absorbent solution which is moved to a stripping zone where sulfur dioxide is driven off to form a SO.sub.2 -depleted aqueous absorbent solution which is recycled and re-contacted with the gas mixture, the improvement comprising removing sulfur oxyanions of heat stable salts which accumulate in the aqueous absorbent solution by contacting a portion of it with an anion exchange resin having hydroxyl anions displaceable by the heat stable sulfur oxyanions whereby the hydroxyl anions of the resin are replaced by the heat stable divalent sulfur oxyanions which are thus taken out of the solution. The anion exchange resin preferably is a strong base anion exchange resin which can be regenerated by contacting it with aqueous sodium hydroxide to replace the heat stable sulfur oxyanions on said resin with hydroxyl anions.
摘要翻译：从含有其的气体混合物中选择性除去二氧化碳的方法的改进，其中气体混合物与含水吸收剂溶液如烷醇胺，碱金属氢氧化物，氢氧化铵或其亚硫酸盐接触以除去硫二氧化碳从气体混合物形成，并形成富含SO2的吸收剂溶液，该溶液被移至汽提区，其中二氧化硫被排出以形成SO 2贫化的含水吸收剂溶液，其被再循环并与气体混合物重新接触，改进包括通过使其一部分与具有可通过热稳定性硫氧阴离子置换的羟基阴离子的阴离子交换树脂接触而除去累积在吸收水溶液中的热稳定盐的硫氧化阴离子，由此树脂的羟基阴离子被热稳定的二价因此硫氧醛阴离子从溶液中取出。阴离子交换树脂优选是强碱性阴离子交换树脂，其可以通过使其与氢氧化钠水溶液接触而再生，以用羟基阴离子代替所述树脂上的热稳定性硫氧阴离子。

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