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    • 2. 发明申请
    • Polymer composition
    • 聚合物组成
    • US20060052534A1
    • 2006-03-09
    • US10531307
    • 2003-10-20
    • Kenji SuzukiAkihiro KotakaKenji ShachiMizuho Maeda
    • Kenji SuzukiAkihiro KotakaKenji ShachiMizuho Maeda
    • C08L53/00
    • C08L53/02C08F297/04C08L33/04C08L33/06C08L33/08C08L53/025C08L2666/24C08L2666/02C08L2666/04C08L33/00
    • The invention provides a polymer composition containing an addition polymerization-based block copolymer (a), an acrylic resin (b), and a softener (c), wherein the addition polymerization-based block copolymer (a) has a weight average molecular weight of 30000 to 200000 and is at least one selected from block copolymers comprising at least one polymer block A and at least one polymer block B, and hydrogenated products of the block copolymers; the polymer block A essentially comprises an aromatic vinyl compound unit containing at least 1% by mass of an alkylstyrene-derived structural unit (I) in which at least one alkyl group having 1 to 8 carbon atoms is bound to a benzene ring; the block copolymer B comprises a conjugated diene compound unit; and the components of the polymer composition are present in respective proportions (by mass) so that the following relationships (1) and (2) hold: 0.05≦Wb/Wa≦2  (1) Wc/(Wa+Wb+Wc)≦0.5  (2) where Wa, Wb, and Wc are the amounts (by mass) of the components of the polymer composition: the addition polymerization-based block copolymer (a), the acrylic resin (b) and the softener (c), respectively. Not only does the polymer composition of the present invention offer various advantageous properties, including moldability, flexibility, rubber elasticity, mechanical properties, and transparency, but it also exhibits superior scratch resistance and superior abrasion resistance, which make the polymer composition suitable for use in various applications.
    • 本发明提供含有加成聚合型嵌段共聚物(a),丙烯酸树脂(b)和软化剂(c)的聚合物组合物,其中加成聚合型嵌段共聚物(a)的重均分子量 30000至200000,并且是选自包含至少一个聚合物嵌段A和至少一个聚合物嵌段B的嵌段共聚物和嵌段共聚物的氢化产物中的至少一种; 聚合物嵌段A基本上包含芳族乙烯基化合物单元,其含有至少1质量%的烷基苯乙烯衍生的结构单元(I),其中至少一个具有1至8个碳原子的烷基与苯环结合; 嵌段共聚物B包含共轭二烯化合物单元; 并且聚合物组合物的成分以各自的比例(质量%)存在,使得以下关系(1)和(2)ho
    • 6. 发明授权
    • Polymer composition
    • 聚合物组成
    • US07906584B2
    • 2011-03-15
    • US10531307
    • 2003-10-20
    • Kenji SuzukiAkihiro KotakaKenji ShachiMizuho Maeda
    • Kenji SuzukiAkihiro KotakaKenji ShachiMizuho Maeda
    • C08L53/02C08L33/08C08F297/04
    • C08L53/02C08F297/04C08L33/04C08L33/06C08L33/08C08L53/025C08L2666/24C08L2666/02C08L2666/04C08L33/00
    • The invention provides a polymer composition containing an addition polymerization-based block copolymer (a), an acrylic resin (b), and a softener (c), wherein the addition polymerization-based block copolymer (a) has a weight average molecular weight of 30000 to 200000 and is at least one selected from block copolymers comprising at least one polymer block A and at least one polymer block B, and hydrogenated products of the block copolymers; the polymer block A essentially comprises an aromatic vinyl compound unit containing at least 1% by mass of an alkylstyrene-derived structural unit (I) in which at least one alkyl group having 1 to 8 carbon atoms is bound to a benzene ring; the block copolymer B comprises a conjugated diene compound unit; and the components of the polymer composition are present in respective proportions (by mass) so that the following relationships (1) and (2) hold: 0.05≦Wb/Wa≦2  (1) Wc/(Wa+Wb+Wc)≦0.5  (2) where Wa, Wb, and Wc are the amounts (by mass) of the components of the polymer composition: the addition polymerization-based block copolymer (a), the acrylic resin (b) and the softener (c), respectively. Not only does the polymer composition of the present invention offer various advantageous properties, including moldability, flexibility, rubber elasticity, mechanical properties, and transparency, but it also exhibits superior scratch resistance and superior abrasion resistance, which make the polymer composition suitable for use in various applications.
    • 本发明提供含有加成聚合型嵌段共聚物(a),丙烯酸树脂(b)和软化剂(c)的聚合物组合物,其中加成聚合型嵌段共聚物(a)的重均分子量 30000至200000,并且是选自包含至少一个聚合物嵌段A和至少一个聚合物嵌段B的嵌段共聚物和嵌段共聚物的氢化产物中的至少一种; 聚合物嵌段A基本上包含芳族乙烯基化合物单元,其含有至少1质量%的烷基苯乙烯衍生的结构单元(I),其中至少一个具有1至8个碳原子的烷基与苯环结合; 嵌段共聚物B包含共轭二烯化合物单元; 并且聚合物组合物的成分以各自的比例(质量比)存在,使得以下关系式(1)和(2)成立:0.05≦̸ Wb / Wa≦̸ 2(1)Wc /(Wa + Wb + Wc) < nlE; 0.5(2)其中,Wa,Wb和Wc是聚合物组合物的组分的量(质量):加成聚合基嵌段共聚物(a),丙烯酸树脂(b)和软化剂 ), 分别。 本发明的聚合物组合物不仅具有成型性,柔韧性,橡胶弹性,机械性能和透明性等各种有利性质,而且还具有优异的耐擦伤性和优异的耐磨性,使聚合物组合物适用于 各种应用。