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    • 6. 发明授权
    • Process for making curable amide gellant compounds
    • 制备可固化酰胺胶凝剂化合物的方法
    • US07271284B2
    • 2007-09-18
    • US11289882
    • 2005-11-30
    • Eniko TomaAdela GoredemaJennifer L. BeleliePeter G. Odell
    • Eniko TomaAdela GoredemaJennifer L. BeleliePeter G. Odell
    • C07C229/00
    • C08F290/06C08F220/14C08F290/061C08F290/067C08G69/26C08G69/28
    • Disclosed is a process for preparing a compound of the formula wherein R1 is an alkyl group having at least one ethylenic unsaturation, an arylalkyl group having at least one ethylenic unsaturation, or an alkylaryl group having at least one ethylenic unsaturation, R2 and R3 each, independently of the others, are alkylene groups, arylene groups, arylalkylene groups, or alkylarylene groups, R4 and R5 each, independently of the other, is a hydrogen atom or an alkyl group, and n is an integer representing the number of repeat amide units and is at least 1, said process comprising: (a) reacting a diacid of the formula HOOC—R2—COOH with a diamine of the formula in the presence of a catalyst, a solvent, and a coupling agent to form an oligoamide intermediate; and (b) reacting the oligoamide intermediate with an alcohol of the formula R1—OH to form the product.
    • 公开了一种制备下式化合物的方法,其中R 1是具有至少一个烯属不饱和键的烷基,具有至少一个烯属不饱和键的芳基烷基或具有至少一个烯属不饱和键的烷基芳基 R 1,R 2,R 3和R 3各自独立地是亚烷基,亚芳基,芳基亚烷基或烷基亚芳基,R 4, 各自独立地是氢原子或烷基,n是表示重复酰胺单元数的整数,并且至少为1,所述方法包括: (a)使式(Ⅳ)的二酸与式-I-in-line-formula中的二酸反应, 在存在催化剂,溶剂和偶联剂的情况下,使式II的化合物描述=“内联式”末端=“尾”→,形成低聚酰胺中间体; 和(b)使低聚酰胺中间体与式(Ⅳ)的醇反应,其中式(Ⅳ)中,式 -line-formula description =“In-Line Formulas”end =“tail”?>来形成产品。
    • 7. 发明授权
    • Method for preparing curable amide gellant compounds
    • 制备可固化酰胺胶凝剂化合物的方法
    • US07259275B2
    • 2007-08-21
    • US11290328
    • 2005-11-30
    • Jennifer L. BelelieAdela GoredemaPeter G. OdellEniko Toma
    • Jennifer L. BelelieAdela GoredemaPeter G. OdellEniko Toma
    • C07C229/00
    • C07C231/02C08G69/26C08G69/28C09D11/34C07C233/34C07C233/36
    • Disclosed is a process for preparing a compound of the formula wherein R1 is an alkyl group having at least one ethylenic unsaturation, an arylalkyl group having at least one ethylenic unsaturation, or an alkylaryl group having at least one ethylenic unsaturation, R2 and R3 each, independently of the others, are alkylene groups, arylene groups, arylalkylene groups, or alkylarylene groups, and n is an integer representing the number of repeat amide units and is at least 1, said process comprising: (a) reacting a diacid of the formula HOOC—R2—COOH with a diamine of the formula in the absence of a solvent while removing water from the reaction mixture to form an acid-terminated oligoamide intermediate; and (b) reacting the acid-terminated oligoamide intermediate with a monoalcohol of the formula R1—OH in the presence of a coupling agent and a catalyst to form the product.
    • 公开了一种制备下式化合物的方法,其中R 1是具有至少一个烯属不饱和键的烷基,具有至少一个烯属不饱和键的芳基烷基或具有至少一个烯属不饱和键的烷基芳基 烯键式不饱和键,R 2和R 3各自独立地为亚烷基,亚芳基,芳基亚烷基或烷基亚芳基,n为代表 重复酰胺单元的数目并且至少为1,所述方法包括:(a)使式Ⅳ的二酸与-in-line-formula description =“In-Line Formulas”end =“lead”→> HOOC-R' 在不存在溶剂的情况下,在从反应混合物中除去水的情况下,使用下式所示的二胺,在线式描述=“In-line Formula”中, 以形成酸封端的低聚酰胺中间体; 和(b)使酸封端的低聚酰胺中间体与下式的一元醇反应:式中:=“引入”→R 1 -OH 在偶联剂和催化剂的存在下,<?in-line-formula description =“In-line formula”end =“tail”?>以形成产物。