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    • 5. 发明授权
    • Immobilization of Technetium by Electroless Plating
    • 通过无电解电镀固定锝
    • US09108867B2
    • 2015-08-18
    • US13964247
    • 2013-08-12
    • AREVA Inc.
    • Kevin J. Hagerty
    • C23C18/54C02F1/469G21F9/06G21F9/30G21F9/34C23C18/16C23C18/50
    • C02F1/4693C23C18/1651C23C18/1683C23C18/50C23C18/54G21F9/06G21F9/301G21F9/302G21F9/34
    • A process of incorporating technetium into an electroless deposit, forming an alloy that is extremely resistant to corrosion and reduces the mobility of technetium on a geologic time scale is disclosed and claimed. The process includes providing a liquid containing technetium, such as an aqueous waste stream generated during the used nuclear fuel reprocessing activities. The technetium is collected and concentrated, and provided into an electroless deposition bath. A substrate, such as suitably prepared zero valent iron or stainless steel, is introduced into the bath to initiate autocatalytic electroless deposition of the technetium onto the substrate due to the difference in electrochemical potential between the plating bath and the metals in solution. This causes a layer of technetium metal to form on the substrate. The electroless deposition is continued until virtually all of the technetium has been removed from the bath, and then continues to build a layer of technetium-free material on the outermost surface of the substrate. One or more additional deposition steps may be performed to armor the plated substrate against leaching/corrosion in a nuclear waste disposal facility.
    • 公开并要求保护将锝掺入无电沉积物中的方法,形成非常耐腐蚀的合金并降低锝在地质时间尺度上的流动性。 该方法包括提供含有锝的液体,例如在使用的核燃料后处理活动期间产生的废水。 将锝收集并浓缩,并提供到无电沉积浴中。 由于镀液与溶液中的金属之间的电化学势的差异,将诸如适当制备的零价铁或不锈钢的衬底引入浴中以引发锝在衬底上的自动催化无电沉积。 这会在基板上形成一层锝金属。 无电沉积继续,直到几乎所有的锝已经从浴中除去,然后继续在基底的最外表面上构建一层无锝材料。 可以执行一个或多个附加的沉积步骤以使镀覆的衬底防止在核废物处理设备中的浸出/腐蚀。
    • 9. 发明申请
    • PROBABILISTIC EVALUATION OF FASTENER DEGRADATION IN NUCLEAR POWER PLANTS
    • US20170337298A1
    • 2017-11-23
    • US15158851
    • 2016-05-19
    • AREVA Inc.
    • Greg TROYERBrian HAIBACHTim WIGER
    • G06F17/50G06N7/00G06F17/18
    • G06F17/5004G06F17/5009G06F2217/10G06F2217/76G06N7/005
    • A probabilistic method for determining an operability interval for fasteners in a nuclear power plant assembly is provided. The probabilistic method includes determining or assuming a geometric distribution of a given initial condition of fasteners in the nuclear power plant assembly at an initial time T0; determining a future fastener failure probability model of the geometric distribution over time; generating a plurality of random future fastener failure patterns by applying the fastener failure model to the geometric distribution at a given time T1>T0; postulating fastener spacing rules designed to evaluate the acceptability of fastener failure patterns for the fasteners in the nuclear power plant assembly; applying the fastener spacing rules to a plurality of randomly generated fastener failure patterns for the given time T1 to determine the probability of the randomly generated fastener failure patterns passing the fastener spacing rules at the given time T1; iterating, by a processor of a computer, the applying step for a given range of time values T2, T3, . . . , Tx>T0 and determining a maximum future time Tmax at which a predetermined acceptable probability of the fastener failure patterns passing the fastener spacing rules is met, thereby justifying the acceptability of the fasteners for continued operation of the nuclear power plant assembly; and determining the operability interval as being Tmax-T0.