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    • 9. 发明授权
    • Water soluble thioxantone photoinitiators
    • 水溶性噻吨酮光引发剂
    • US4459416A
    • 1984-07-10
    • US411570
    • 1982-08-25
    • John R. CurtisPeter E. Heaton
    • John R. CurtisPeter E. Heaton
    • C07D335/16C08F2/00C08F2/50G03F7/031
    • C07D335/16C08F2/50G03F7/031
    • The invention provides novel thioxanthone photoinitiators having the formula: ##STR1## wherein R.sub.1 alkyl, alkoxy, alkylthio, halogeno, nitro, amino, alkyl-amino, di-alkyl-amino, hydroxy alkyl-amino, alkanoylamino, benzoylamino, N-alkanoyl-N-benzoyl-amino, sulphonamido, or acetyl, R.sub.2 is alkylene, A is --COOH, --SO.sub.3 H, --OSO.sub.3 H, or --O--CO--X--COOH (where X is such that HO--CO--X--COOH is a di- or tri-carboxylic acid of up to 8 carbon atoms), n is 0, 1, or 2 and m is 1 or 2, provided that when A is --COOH, m is 2, the aforesaid alkyl, alkoxy, alkanoyl, and alkylene residues containing up to 4 carbon atoms each, as the free acid or as a salt thereof. The photoinitiators may advantageously be used in water-based photopolymerizable compositions, e.g. for use in screen stencil production.
    • 本发明提供具有下式的新型噻吨酮光引发剂:其中R 1为烷基,烷氧基,烷硫基,卤代,硝基,氨基,烷基氨基,二烷基氨基,羟基烷基 - 氨基,烷酰基氨基,苯甲酰氨基,N-烷酰基 - N-苯甲酰氨基,磺酰氨基或乙酰基,R 2为亚烷基,A为-COOH,-SO 3 H,-OSO 3 H或-O-CO-X-COOH(其中X为HO-CO-X-COOH为 最多8个碳原子的二羧酸或三羧酸),n为0,1或2,m为1或2,条件是当A为-COOH时,m为2,前述烷基,烷氧基,烷酰基, 和各自含有至多4个碳原子的亚烷基残基,作为游离酸或其盐。 光引发剂可有利地用于水基光聚合组合物,例如, 用于丝网印刷生产。