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    • 1. 发明授权
    • Process for continuously converting coal into a saturated hydrocarbon gas
    • 将煤连续转化为饱和烃气的方法
    • US3973924A
    • 1976-08-10
    • US520669
    • 1974-11-04
    • Shozo Ito
    • Shozo Ito
    • C10J3/54C07C1/00C07C1/02C07C4/04C07C9/00C07C9/04C07C67/00C10K3/04C10K3/06C10J3/46C10K1/00
    • C10K3/06
    • Coal is continuously converted into a saturated hydrocarbon gas containing substantially no unsaturated hydrocarbon and having a high calorific value and a uniform composition by the operations of: providing a first treating gas having a predetermined temperature, pressure and composition, by mixing, in a first conditioning chamber, a first substantially inert burnt gas which has been prepared by burning a mixture of a fuel and air, containing therein 2% by volume or less of free oxygen, with steam and, if necessary, hydrogen gas; thermally cracking, in a first treating chamber, the coal particles with the first treating gas while fluidizing said coal particles; separately providing a second treating gas having a predetermined temperature, pressure and composition by mixing, in a second conditioning chamber, a second substantially inert burnt gas which has been prepared by burning a fuel, and contains therein 2% by volume or less of free hydrogen gas, with hydrogen gas and, if necessary, an additional gas; hydrogenating, in a second treating chamber, the thermally cracked product with the second treating gas while fluidizing the thermally cracked product to generate the saturated hydrocarbon gas and isolating the saturated hydrocarbon gas from the hydrogenation mixture, the hydrogen gas used in the above process being prepared by collecting char from the hydrogenation mixture, converting the char into water-gas containing hydrogen and carbon monoxide gases by treating with a third treating gas containing steam, converting the carbon monoxide into a mixture of hydrogen and carbon dioxide gases by steam treatment and isolating the hydrogen gas from the conversion mixture.
    • 通过以下操作将煤连续地转化为基本上不含不饱和烃并具有高热值和均匀组成的饱和烃气体:通过在第一调理中混合提供具有预定温度,压力和组成的第一处理气体 通过燃烧含有2体积%以下的游离氧的燃料和空气的混合物与蒸汽和必要时的氢气制备的第一基本上惰性的燃烧气体; 在第一处理室中热裂解煤颗粒与第一处理气体同时使所述煤颗粒流化; 分别提供具有预定温度,压力和组成的第二处理气体,在第二调节室中,通过燃烧燃料制备的第二基本上惰性的燃烧气体,并且其中含有2体积%以下的游离氢 气体,带有氢气,如有必要,还有一个额外的气体; 在第二处理室中将热裂化产物与第二处理气体氢化,同时使热裂化产物流化以产生饱和烃气体并从饱和烃气体中分离氢化混合物,在上述方法中使用的氢气被制备 通过从氢化混合物中收集焦炭,通过用含有蒸汽的第三处理气体处理将焦炭转化为含有氢气和一氧化碳气体的水气,通过蒸汽处理将一氧化碳转化成氢气和二氧化碳气体的混合物,并将 来自转化混合物的氢气。