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    • 3. 发明授权
    • Separation of viscous hydrocarbons and minerals particles from aqueous
mixtures by mixtures by oleophilic adhesion
    • 通过亲油粘附将混合物从含水混合物中分离粘稠的烃和矿物颗粒
    • US4744889A
    • 1988-05-17
    • US849546
    • 1986-04-08
    • Jan Kruyer
    • Jan Kruyer
    • B01D17/02B03B1/04B03B5/00B03B9/02B03B1/00C10G1/00B01D15/00
    • B03B9/02B01D17/0202B03B1/04B03B5/00Y10S210/05
    • A method and apparatus for separating an oil phase from an aqueous phase by means of a rotating drum apparatus containing one or more compartments, each being partially filled with oleophilic free bodies. When containing two or more compartments, they are separated by an apertured baffle. The interior surfaces of the drum are oleophilic and the portion of the drum sidewall, where the mixture is removed is apertured. Due to the oleophilic free bodies and interior oleophilic surfaces, the aqueous phase velocity through the drum is faster than the oil phase which adheres to the oleophilic surfaces causing an in situ buildup and agglomeration of oil phase in the drum. The mixture exiting the apertured drum sidewall is partitioned by the tumbling free bodies, oleophilic drum surfaces and drum rotation such that aqueous phase leaves the drum between the 6 and 9 o'clock positions of counter clockwise rotation where free body concentration is minimal. The oil phase is carried with the free bodies as the drum rotates and is extruded through the apertures to the outside of the drum between the 3 and 6 o'clock positions where free body concentration is greatest. A scraper or an endless oleophilic belt partly wrapped around the apertured portion of the drum remove the extruded oil phase from the drum surface. The endless belt may be a woven mesh made of plastic or metal or may be a metal belt of joined flattened spiral metal strands.
    • 一种用于通过包含一个或多个隔室的旋转鼓装置从水相中分离油相的方法和装置,每个隔室部分地填充有亲油性游离体。 当包含两个或更多个隔间时,它们由有孔挡板分开。 滚筒的内表面是亲油的,并且滚筒侧壁的那部分去除混合物的部分是开孔的。 由于亲油性自由体和内部亲油表面,通过滚筒的水相速度比粘附到亲油表面的油相快,导致油相在油桶中的原位积累和附聚。 离开多孔鼓侧壁的混合物由滚动自如体,亲油性鼓表面和滚筒旋转分隔开,使得水相离开滚筒在逆时针旋转的6和9点位置之间,其中自由体浓度最小。 当滚筒旋转时,油相与自由体携带,并且在自由体浓度最大的3和6点位置之间通过孔挤压到滚筒的外部。 部分缠绕在滚筒的有孔部分上的刮刀或无端的亲油带从鼓表面去除挤出的油相。 环形带可以是由塑料或金属制成的编织网,或者可以是连接的扁平螺旋金属线的金属带。
    • 4. 发明授权
    • Separating oil phase from aqueous phase using an apertured oleophilic
sieve in contact with an apertured cylindrical cage wall
    • 使用开孔的亲油筛网与开孔圆柱形笼壁分离油相与水相
    • US4740311A
    • 1988-04-26
    • US511773
    • 1983-07-06
    • Jan Kruyer
    • Jan Kruyer
    • B01D17/00B01D17/022C10G33/06B01D33/04
    • C10G33/06B01D17/12
    • A mixture containing a viscous oil phase and an aqueous phase is separated by means of an apertured oleophilic endless sieve supported in a separation zone by a revolving cylindrical cage having apertured sidewalls and supported in a recovery zone by a support roller, each section of sieve surface alternately revolves through the separation zone and recovery zone. The mixture is introduced into the rotating cage in the separation zone. The endless sieve partly covers the outside surface of the cylindrical cage sidewall. The mixture tumbles inside of the cage and passes through the cage sidewall apertures to the sieve surface. The oil phase of the mixture is captured by the sieve upon contact and is conveyed out of the separation zone.In the recovery zone, oil phase is removed from the sieve by squeezing the oil phase on the sieve between two rollers at least one of which is oleophilic. Alternately, the oil phase on the sieve may be heated and, because of its apertured surface, be blown off, shaken off or thrown off the sieve under the influence of an applied force.
    • 将含有粘性油相和水相的混合物通过支撑在分离区中的开孔亲油环状分隔器,通过具有多孔侧壁的旋转圆柱形保持架分离,并通过支撑辊支撑在回收区中,筛分表面的每个部分 交替旋转穿过分离区和回收区。 将混合物引入分离区中的旋转笼中。 无端筛部分地覆盖圆柱形保持架侧壁的外表面。 混合物在保持架内部滚动并穿过保持架侧壁孔到达筛面。 混合物的油相在接触时被筛子捕获并被输送出分离区。 在回收区中,通过在两个辊之间的筛上挤压油相将油相从筛上除去,其中至少一个是亲油的。 或者,筛子上的油相可以被加热,并且由于其有孔表面被吹掉,在施加的力的影响下被摇动或者从筛子上扔掉。
    • 5. 发明授权
    • Use of free bodies to increase size of dispersed phase particles
    • 使用自由体增加分散相颗粒的尺寸
    • US4406793A
    • 1983-09-27
    • US387957
    • 1982-06-14
    • Jan Kruyer
    • Jan Kruyer
    • B01D17/02C10G1/04C10G33/00B01D15/02
    • C10G33/00B01D17/0205C10G1/047Y10S210/05
    • A mixture containing a dispersed bitumen, oil or hydrocarbon phase and a continuous aqueous phase is passed for treatment through a rotating horizontal tumbler, containing oleophilic free bodies, for the purpose of increasing the particle size of the dispersed phase and facilitating subsequent separation of the phases of the mixture. Alternately, a mixture containing a dispersed aqueous phase and a continuous bitumen, oil or hydrocarbon phase is passed for treatment through a rotating horizontal tumbler, containing hydrophilic and oleophilic free bodies, for the purpose of increasing the particle size of the dispersed phase and facilitating subsequent separation of the phases of the mixture. The free bodies tumbling with the mixture in the drum have affinity for the dispersed phase particles and cause an increase in the particles' size of the dispersed phase of the mixture through a process of cyclic coalescence, agglutination, condensation and/or coherence of dispersed phase particles from the mixture onto the surface of the free bodies and cyclic shedding or sloughing off of coalesced dispersed phase back into the mixture. Some mixtures that may be treated include oil sand slurries, effluent streams from a hot sands extraction plant, oil-in-water emulsions from processes that use enhanced oil well recovery, and bitumen froth.
    • 通过含有亲油性游离体的旋转水平滚筒进行包含分散的沥青,油或烃相以及连续水相的混合物,以便增加分散相的粒径并有利于相的分离 的混合物。 或者,含有分散的水相和连续的沥青,油或烃相的混合物通过含有亲水和亲油性游离体的旋转水平滚筒进行处理,目的是增加分散相的粒度并促进随后的 分离混合物的相。 与滚筒中的混合物滚动的自由体对分散相颗粒具有亲和性,并且通过分散相的循环聚结,凝集,缩合和/或相干的过程引起混合物的分散相的颗粒大小的增加 从混合物中的颗粒到游离体的表面上,并将合并的分散相循环脱落或脱落回混合物。 可以处理的一些混合物包括油砂浆料,来自热砂提取装置的流出物流,使用增强的油井回收的方法的水包油乳液和沥青泡沫。
    • 6. 发明授权
    • Process for recovering bitumen from oil sand
    • 从油砂中回收沥青的工艺
    • US4224138A
    • 1980-09-23
    • US37896
    • 1979-05-10
    • Jan Kruyer
    • Jan Kruyer
    • C10C3/00C10G1/00
    • C10C3/007C10G1/00
    • Bituminous sand such as oil sand or tar sand is mixed with steam and water in a tumbler to produce a slurry. Oversized particles are removed and the slurry is transferred into a water bath containing a submerged moving, apertured, separator, such as an endless belt having an oleophilic surface and top and bottom flights. The slurry falls through the water onto the top flight of the belt where the bitumen is attracted to the apertured oleophilic surface and adheres thereto. The adhering bitumen is then removed from the belt. Mineral particles in the slurry and the remaining bitumen pass through the apertures of the top flight and fall through the water onto the bottom flight of the belt. The remaining bitumen of the slurry is attracted to the apertured oleophilic surface of the bottom flight and adheres thereto. The adhering bitumen is then removed from the belt. The mineral particles of the slurry and a very small amount of remaining bitumen pass through the apertures to fall to the bottom of the water bath for subsequent removal.The process gives a good recovery of bitumen product which has acceptable quantities of solid and water contamination. Compared with the prior art it has the feature that the oleophilic apertured surface does not have to be removed from the water bath to collect bitumen therefrom.
    • 沥青砂如油砂或焦油砂与蒸汽和水在转筒中混合以产生浆料。 将超大颗粒除去并将浆料转移到含有浸没移动的多孔分离器的水浴中,例如具有亲油表面和顶部和底部飞行的环形带。 浆料通过水滴落到带的顶部飞行上,沥青被吸引到有孔的亲油表面并粘附在其上。 然后将粘附的沥青从带上取出。 浆料中的矿物颗粒和剩余的沥青通过顶部飞行物的孔,并通过水落到皮带的底部飞行上。 浆料的剩余沥青被吸引到底部飞行的有孔亲油表面并粘附到其上。 然后将粘附的沥青从带上取出。 浆料的矿物颗粒和非常少量的剩余沥青通过孔落到水浴的底部以便随后除去。 该方法提供了可接受量的固体和水污染的沥青产品的良好回收。 与现有技术相比,其特征在于不需要从水浴中除去亲油性有孔表面以从其中收集沥青。
    • 7. 发明授权
    • Method and apparatus for separating slurries and emulsions
    • 用于分离浆料和乳液的方法和设备
    • US4529496A
    • 1985-07-16
    • US178100
    • 1980-08-14
    • Jan Kruyer
    • Jan Kruyer
    • B01D17/00B01D17/02C10G33/06C10G1/04
    • C10G33/06B01D17/00B01D17/0202Y10S210/924
    • A mixture containing dispersed phase and continuous aqueous phase, with particulate solids being part of either or both phases, is separated by passing it one or more times through apertures in an endless oleophilic conveyor belt in a separation zone wherein bitumen phase adheres to the belt and bitumen adhering to the belt is conveyed to one or more bitumen treatment zones and to a recovery zone where bitumen is removed from the belt. The end rolls of the belt are not immersed in a water bath; however, portions of the belt, while in the separation, treatment and recovery zones, may be partly or completely in an aqueous environment. More than one set of separation, treatment and recovery zones may be used on the same endless belt conveyor. Also, a mixture containing dispersed aqueous phase and continuous bitumen or oil phase, and possibly gas, is deposited onto an apertured oleophilic endless belt conveyor and is treated in one or more treatment zones and is then removed from the belt.
    • 将分散相和连续水相的混合物,其中颗粒固体是两相或两相的一部分,通过使其一次或多次通过分离区中的无端亲油输送带中的孔而分离,其中沥青相粘附到带和 粘附到带上的沥青被输送到一个或多个沥青处理区域和从带传送沥青的回收区域。 皮带的端辊不浸没在水浴中; 然而,在分离,处理和回收区域中,带的一部分可以部分或完全在水性环境中。 在同一环形带式输送机上可以使用多套分离,处理和回收区。 此外,将含有分散的水相和连续的沥青或油相以及可能的气体的混合物沉积到有孔亲油环形带式输送机上,并在一个或多个处理区域中处理,然后从带中取出。
    • 8. 发明授权
    • Process for recovering minerals and metals by oleophilic adhesion
    • 通过亲油粘附回收矿物和金属的方法
    • US4511461A
    • 1985-04-16
    • US511776
    • 1983-07-06
    • Jan Kruyer
    • Jan Kruyer
    • B03B1/04B03B5/00B03B7/00B07B13/00
    • B03B1/04B03B5/00B03B7/00
    • A mixture containing oleophilic surfaced mineral particles and oleophobic gangue particles in an aqueous phase is separated by means of an apertured oleophilic endless sieve supported in a separation zone by a revolving cylindrical cage having apertured sidewalls and supported in a recovery zone by a support roller, each section of sieve surface alternately revolves through the separation zone and recovery zone. The aqueous mixture is introduced as a slurry into the rotating cage. The endless sieve partly covers the outside surface of the cylindrical cage sidewall. An oleophilic adhesive is placed on the sieve as a coating or added to the aqueous slurry in the cage or both. The mixture tumbles inside of the cage and passes through the cage sidewall apertures to the sieve surface. The oleophilic mineral particles of the mixture adhere to the oleophilic adhesive and are captured by the sieve upon contact and conveyed out of the separation zone into the recovery zone.In the recovery zone, mineral particles and adhesive mixture are heated and removed from the sieve by squeezing the mixture on the sieve between two rollers at least one of which is oleophilic. Alternately, the mineral particles and adhesive mixture on the sieve may because of its apertured surface, be blown off, shaken off or thrown off the sieve under the influence of an applied force.
    • 在水相中含有亲油性表面矿物颗粒和疏油脉石ue石颗粒的混合物通过支撑在分离区中的开孔亲油环状筛分离,该旋转圆柱形笼具有多孔侧壁并通过支撑辊支撑在回收区中, 筛面交替旋转穿过分离区和回收区。 将水性混合物作为浆料引入旋转笼中。 无端筛部分地覆盖圆柱形保持架侧壁的外表面。 将亲油性粘合剂作为涂层放置在筛子上或加入到保持架中的水性浆料中或两者中。 混合物在保持架内部滚动并穿过保持架侧壁孔到达筛面。 混合物的亲油矿物颗粒粘附到亲油粘合剂上,并在接触时被筛子捕获并从分离区输送到回收区。 在回收区中,将矿物颗粒和粘合剂混合物通过在两个辊之间的筛上挤压混合物而加热并除去,其中至少一个是亲油的。 或者,筛上的矿物颗粒和粘合剂混合物可能是由于其有孔表面,在施加的力的影响下被吹走,摇摆或从筛子上扔掉。
    • 9. 发明授权
    • Preparation of bitumen froths and emulsions for separation
    • 制备沥青泡沫和分离乳液
    • US4405446A
    • 1983-09-20
    • US338600
    • 1982-03-15
    • Jan Kruyer
    • Jan Kruyer
    • C10G1/04C10G33/06
    • C10G1/047C10G33/06Y10S210/05
    • An oil and water mixture containing a dispersed phase and a continuous phase is passed for treatment through a rotating horizontal tumbler containing free bodies and a hydrocarbon diluent for the purpose of facilitating subsequent separation of the phases of the mixture. The free bodies tumbling with the mixture in the drum have affinity for the dispersed phase particles, and the hydrocarbon diluent reduces the viscosity of the oil phase thereby causing an increase in the particle size of the dispersed phase of the mixture. Some mixtures that may be treated include effluent streams from a hot-water oil sands extraction plant, oil-in-water emulsions from processes that use enhanced oil well recovery and bitumen froth.
    • 通过含有分散相和连续相的油和水混合物通过含有游离体和烃类稀释剂的旋转卧式制动栓进行处理,目的是便于随后分离混合物的相。 与滚筒中的混合物一起滚动的自由体对分散相颗粒具有亲和力,烃稀释剂降低了油相的粘度,从而引起混合物分散相的粒度增加。 可以处理的一些混合物包括来自热水油砂提取装置的流出物流,使用增强的油井回收和沥青泡沫的方法的水包油乳液。