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    • 1. 发明授权
    • Solid-state hydrogen storage systems
    • 固态储氢系统
    • US07279222B2
    • 2007-10-09
    • US10851313
    • 2004-05-21
    • Andrew K. HearleyScott D. Redmond
    • Andrew K. HearleyScott D. Redmond
    • B32B18/00
    • B82Y30/00B22F1/0018B22F9/082B22F2998/00B22F2999/00C01B3/0078C01P2004/64Y02E60/327Y10S420/90Y10T428/2982Y10T428/2991B22F3/1208B22F2202/13
    • Improved hydrogen storage materials are disclosed. A first material comprises a hydrogen storage nanomaterial that contains nanoparticles or nanoparticle clusters of a metal that is capable of combining with hydrogen to form a metal hydride. The nanomaterials may be formed using a thermal spray process. A second material comprises a micro-sized support that contains a hydrogen storage material deposited thereon. The hydrogen storage material may comprise a thermal spray deposit formed on a fly ash particle. A third material comprises a hydrogen permeable container having a hydrogen storage material therein. The container may comprise a microparticle having an internal void (e.g., a fly ash cenosphere or glass microsphere) containing a hydrogen storage material that has been permeated therein. Alternatively, the container may comprise an enclosing layer formed over a hydrogen storage material. The enclosing layer may be a deposited protective layer formed over a particle of a hydrogen storage material.
    • 公开了改进的储氢材料。 第一种材料包括含有可与氢结合以形成金属氢化物的金属的纳米颗粒或纳米颗粒簇的储氢纳米材料。 纳米材料可以使用热喷涂方法形成。 第二种材料包括含有沉积在其上的储氢材料的微尺寸载体。 储氢材料可以包括形成在飞灰颗粒上的热喷涂沉积物。 第三种材料包括其中具有储氢材料的氢渗透性容器。 容器可以包括具有内部空隙(例如,飞灰碳粉或玻璃微球)的微粒,其含有已经渗透在其中的储氢材料。 或者,容器可以包括形成在储氢材料上的封闭层。 封闭层可以是在储氢材料的颗粒上形成的沉积保护层。
    • 2. 发明授权
    • Methods for hydrogen storage using doped alanate compositions
    • 使用掺杂的铝酸盐组合物的储氢方法
    • US07011768B2
    • 2006-03-14
    • US10463352
    • 2003-06-16
    • Craig M. JensenScott D. Redmond
    • Craig M. JensenScott D. Redmond
    • C01B6/06C01B6/24B01J7/00C22C21/00H01M8/18
    • H01M8/065C01B3/001C01B3/0031C01B3/0078C01B6/243C07F17/00H01M8/04Y02E60/327Y10S420/90
    • The present invention concerns compositions, apparatus and methods for hydrogen storage. In certain embodiments, the compositions comprise sodium alanate and {n5-C5H5}2TiH2. In preferred embodiments, the components of the composition are present in specified molar ratios, for example 0.7 NaH to 1.0 Al to 0.1 Ti. In various embodiments, the hydrocarbon rings coordinating the titanium are removed from the composition, for example by melting at 182° C. or higher or by cyclic discharge and recharge of hydrogen at temperatures of 100° C. or less. Methods for producing and using the claimed compositions are also provided. In various embodiments, the alanate composition may be stored, shipped and used in a modular container, such as a cassette. Exemplary hydrogen utilizing systems and methods for ordering, distribution and shipping of cassettes are also disclosed herein.
    • 本发明涉及用于储氢的组合物,装置和方法。 在某些实施方案中,所述组合物包含阿拉伯酸钠和(n-5)-C 5 H 5 H 2 H 2 Ti SUB> 2 。 在优选的实施方案中,组合物的组分以特定的摩尔比存在,例如0.7NaH-1.0Al至0.1Ti。 在各种实施方案中,从组合物中除去配位钛的烃环,例如通过在182℃或更高温度下熔融或通过在100℃或更低的温度下循环放电和再循环氢。 还提供了生产和使用要求保护的组合物的方法。 在各种实施方案中,可以将铝酸盐组合物储存,运输并使用在模块化容器中,例如盒式磁带。 本文还公开了用于订购,分配和运送盒的示例性氢利用系统和方法。