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1. 发明授权

US5397756A Process for the presulphurization of hydrocarbon treatment catalysts 失效
标题翻译：烃处理催化剂预硫化工艺
公开(公告)号：US5397756A
公开(公告)日：1995-03-14
申请号：US41380
申请日：1993-04-01
申请人： Pierre Dufresne , Bernard Legall , Georges Berrebi
发明人： Pierre Dufresne , Bernard Legall , Georges Berrebi
IPC分类号： B01J31/02 , B01J23/882 , B01J37/20 , C10G45/04 , C10G47/12 , C10G49/02 , B01J23/92 , B01J27/043 , B01J27/049
CPC分类号： B01J37/20
摘要： For the impregnation into the pores of a hydrocarbon treatment catalyst of a sulfurizing agent chosen from element sulfur and organic polysulfides with the aid of a solvent, the impregnation process totally or partially comprises a constituent of the olefin or olefin fraction type, e.g., of the vegetable oil type, or a similar constituent. The use of such a constituent makes it possible to significantly reduce the exothermal effect which occurs during presulfurization, compared with the exothermal effects obtained without using such a constituent.
摘要翻译：对于借助于溶剂浸入选自元素硫和有机多硫化物的硫化剂的烃处理催化剂的孔中，浸渍过程完全或部分地包含烯烃或烯烃级分的组分，例如植物油型或类似成分。与不使用这种成分的放热效果相比，使用这种成分可以显着降低在预硫化过程中发生的放热效应。

2. 发明授权

US5139983A Process for the presulphurization of a hydrocarbon treatment catalyst 失效
标题翻译：烃处理催化剂的预处理方法
公开(公告)号：US5139983A
公开(公告)日：1992-08-18
申请号：US671611
申请日：1991-03-19
申请人： Georges Berrebi , Bernard Le Gall
发明人： Georges Berrebi , Bernard Le Gall
IPC分类号： B01J37/20 , C10G29/10 , C10G45/02 , C10G45/08 , C10G45/10
CPC分类号： B01J37/20
摘要： The invention relates to a process making it possible when a refining catalyst is subject preferably in situ to the conventional activation reaction in the presence of hydrogen (generally at above 100.degree. C.) to carry out, as a result of the in situ presence of hydrogen, the sulphurization at the required stoichiometric or non-stoichiometric level of the active metal or metals in the composition of the catalyst. In the absence of hydrogen, the process consists of incorporating into the porosity of the new or regenerated catalyst at least one sulphurizing agent of general formula:R--S(n)--R'in which n is an integer from 3 to 20 and R represents an organic radical.The invention is characterized in that a critical elementary sulphur quantity is added to the sulphurizing agent. This addition makes it possible to adjust the sulphur content of the presulphurized catalyst to values equal to or higher than stoichiometry, to increase the fixed sulphur quantity after activation under hydrogen and to reduce the exothermy phenomena observed during activation.
摘要翻译：本发明涉及一种使得当精炼催化剂优选在氢气存在下（通常在高于100℃）常规活化反应的情况下进行的方法，由于原位存在氢气，催化剂组合物中所需的化学计量或非化学计量水平的活性金属或金属的硫化。在不存在氢气的情况下，该方法包括将新的或再生催化剂的孔隙结合入至少一种通式为：RS（n）-R'的硫化剂，其中n为3-20的整数，R表示有机基团。本发明的特征在于向硫化剂中加入临界基本硫的量。这种添加使得可以将预硫化催化剂的硫含量调节至等于或高于化学计量的数值，以在氢下活化后增加固定硫量并减少活化期间观察到的放热现象。

3. 发明授权

US4839031A Process for performing the separation of extruded materials which may or may not show imperfections 失效
标题翻译：用于分离挤出材料的方法，其可能显示或可能不显示缺陷
公开(公告)号：US4839031A
公开(公告)日：1989-06-13
申请号：US130571
申请日：1987-12-09
申请人： Francois Ackermann , Georges Berrebi
发明人： Francois Ackermann , Georges Berrebi
IPC分类号： B01J38/72 , B07B13/11
CPC分类号： B07B13/11 , B01J38/72
摘要： The invention relates to a process for the separation of granulate materials, in extruded form of different lengths and of the same or different diameter. It is characterized by the use of a helicoidal vibrating elevator subjected to vibrations whose amplitude is chosen so as to cause on the threads of the spiral on the one hand the ascending flow of all the particles and on the other hand the recovery of the finest particles on the outer edge of the upper thread of the spiral and the largest particles on the inner edge of the upper thread of this spiral.
摘要翻译：本发明涉及用不同长度和相同或不同直径的挤出形式分离颗粒材料的方法。其特征在于使用经受振动的螺旋振动升降机，其振幅被选择成使螺旋线上的一方面导致所有颗粒的上升流动，另一方面是最细颗粒的回收在螺旋的上线螺纹的外边缘上和该螺旋的上线内缘上的最大颗粒。

4. 发明授权

US5854162A Offsite regeneration process for a catalyst containing at least one precious metal 失效
标题翻译：含有至少一种贵金属的催化剂的非现场再生方法
公开(公告)号：US5854162A
公开(公告)日：1998-12-29
申请号：US949683
申请日：1997-10-14
申请人： Pierre Dufresne , Nilanjan Brahma
发明人： Pierre Dufresne , Nilanjan Brahma
IPC分类号： B01J23/90 , B01J23/40 , B01J23/96 , B01J38/02 , B01J38/12 , B01J38/44 , C10G35/06 , C10G35/085 , B01J20/34 , B01J38/18 , B01J38/22
CPC分类号： B01J23/96 , B01J38/44 , C10G35/085
摘要： The invention concerns a process for the regeneration of a used hydrocarbon treatment catalyst, preferably a reforming catalyst, containing at least one precious metal preferably platinum, optionally at least one additional metal selected from the group formed by metals from groups 7, 8, 9, 10, 13 and 14 of the periodic classification of the elements and copper, optionally and preferably at least one halogen, preferably chlorine, and at least one porous support, preferably alumina, said process comprising at least one of the following two successive steps: at least one step (1) for the combustion of the coke present on said catalyst, carried out in the presence of an oxygen-containing gas, at a temperature in the range of 300.degree. C. to 680.degree. C. for a time in the range 0.3 to 7 hours, at least one step (2) for oxyhalogenation, preferably oxychlorination, carried out in a controlled air atmosphere, at a temperature in the range 350.degree. C. to 550.degree. C., for a time in the range 0.3 to 3 hours and in the presence of a halogenated compound, wherein said process is carried out offsite, and in that a moving bed furnace is used for combustion step (1) and for oxyhalogenation step (2).
摘要翻译：本发明涉及一种用于再生含有至少一种贵金属，优选铂，或任选至少一种另外的金属的二烃类处理催化剂，优选重整催化剂的方法，所述另外的金属选自组7,8,9，元素和铜的任选和优选至少一种卤素，优选氯，和至少一种多孔载体，优选氧化铝的周期性分类的10,13和14，所述方法包括以下两个连续步骤中的至少一个：在在含氧气体的存在下，在300℃至680℃的温度范围内，存在于所述催化剂上的焦炭燃烧的至少一个步骤（1）一段时间范围为0.3〜7小时，在受控空气气氛中，在350℃〜550℃的温度范围内进行卤代卤化，优选氧氯化的至少一个步骤（2），时间范围为0.3 到3 小时，并且在卤代化合物的存在下，其中所述方法在异地进行，并且移动床炉用于燃烧步骤（1）和用于卤代卤化步骤（2）。

5. 发明授权

US5823684A Protective belt for a drum formed by a transport bag for powdery materials 失效
标题翻译：由用于粉末材料的运输袋形成的鼓的保护带
公开(公告)号：US5823684A
公开(公告)日：1998-10-20
申请号：US935340
申请日：1997-10-02
申请人： Francis Valeri
发明人： Francis Valeri
IPC分类号： B65D8/04 , B65D88/16 , B65D33/02
CPC分类号： B65D88/1618
摘要： The present invention relates to belts used to protect drums formed by bags intended for transport of powders, granules or other powdery materials from tearing. The invention relates in particular to a belt designed to protect the drum formed by a bag intended for transporting materials placed in the body of said bag, to prevent it from tearing as a result of an external force, and being characterised in that it is cylindrical in shape, at least the top edge of its top and bottom edges being provided with an elastic band.
摘要翻译：本发明涉及用于保护由用于运输粉末，颗粒或其它粉末材料的袋子由撕裂形成的桶形成的带的带。本发明具体涉及一种设计用于保护由用于输送放置在所述袋体中的材料的袋形成的桶的带，以防止其由于外力而被撕裂，并且其特征在于其为圆柱形在其形状中，其顶部和底部边缘的至少顶部边缘设置有弹性带。

6. 发明授权

US5153163A Process for the pretreatment of a catalyst by a mixture of a sulphur agent and an organic reducing agent 失效
标题翻译：硫化剂和有机还原剂混合物预处理催化剂的方法
公开(公告)号：US5153163A
公开(公告)日：1992-10-06
申请号：US729300
申请日：1991-07-12
申请人： Raymond Roumieu , Jean-Paul Boitiaux
发明人： Raymond Roumieu , Jean-Paul Boitiaux
IPC分类号： B01J37/16 , B01J37/20 , C10G45/04 , C10G45/46 , C10G47/12 , C10G49/02
CPC分类号： B01J37/16 , B01J37/20 , Y10S502/508
摘要： The invention relates to a pretreatment of a petrochemical or refining catalyst containing at least one metal in metallic or metallic oxide form, deposited on a support.The catalyst is impreganted by a solution or a suspension containing on the one hand a specific sulphur agent, e.g., diethanol disulfide and on the other an organic reducing agent, e.g., formic acid.
摘要翻译：本发明涉及一种石油化学或精炼催化剂的预处理，该催化剂含有金属或金属氧化物形式的至少一种沉积在载体上的金属。催化剂被一方面含有一种特定硫剂，例如二乙醇二硫化物，另一方面含有有机还原剂，例如甲酸的溶液或悬浮液渗透。

7. 发明授权

US06100216A Process for incorporating sulfur into the pores of a hydrocarbon treatment catalyst 失效
标题翻译：将硫加入到烃处理催化剂的孔中的方法
公开(公告)号：US06100216A
公开(公告)日：2000-08-08
申请号：US784954
申请日：1997-01-16
申请人： Pierre Dufresne , Nilanjan Brahma , Jean Darcissac , Franck Labruyere
发明人： Pierre Dufresne , Nilanjan Brahma , Jean Darcissac , Franck Labruyere
IPC分类号： B01J27/047 , B01J37/20 , C10G45/08 , C10G47/06 , B01J27/051
CPC分类号： B01J37/20 , C10G45/08
摘要： A process for presulfurizing a hydrocarbon treatment catalyst and/or for preconditioning a catalyst, comprising one or two stages of incorporating sulfur into the pores of a hydrocarbon conversion catalyst conducted off-site in at least one zone that contains a catalyst, preferably in motion, and with either suilirated hydrogen (H.sub.2 S), sulfur, or a sulfur compound capable of evolving nascent suilirated hydrogen.
摘要翻译：一种用于预硫化烃处理催化剂和/或预处理催化剂的方法，包括一个或两个阶段将硫引入到烃转化催化剂的孔中，该烃转化催化剂在含有催化剂，优选运动的至少一个区域内的非现场进行，并且可以使用能够形成新生的合适氢的硫酸氢（H 2 S），硫或硫化合物。

8. 发明授权

US5654252A Process for starting a hydrocarbon conversion by the prior treatment of the catalyst with a sulphur agent and then diluted hydrogen 失效
标题翻译：通过用硫剂先前处理催化剂然后稀释氢来开始烃转化的方法
公开(公告)号：US5654252A
公开(公告)日：1997-08-05
申请号：US455988
申请日：1995-05-31
申请人： Pierre Dufresne , Hans Rabehasaina , Georges Berrebi
发明人： Pierre Dufresne , Hans Rabehasaina , Georges Berrebi
IPC分类号： B01J37/20 , C10G35/04 , C10G45/04 , C10G45/06 , C10G45/08 , C10G49/24 , B01J25/02
CPC分类号： C10G49/24 , B01J37/20
摘要： A process is provided for starting a catalytic hydrocarbon conversion reaction or using a hydrocarbon conversion catalyst into which a sulfur agent has been incorporated. In an inert atmosphere, the sulfur-impregnated catalyst is treated with dilute hydrogen to prevent excessive temperatures during the exothermic transformation of oxides into sulfides of the active metals of the catalyst.
摘要翻译：提供用于开始催化烃转化反应或使用已经加入硫剂的烃转化催化剂的方法。在惰性气氛中，用稀氢处理含硫浸渍的催化剂，以防止氧化物在催化剂的活性金属的硫化物中放热转化过程中过度的温度。

9. 发明授权

US5499746A Process and apparatus for loading and unloading powder catalyst 失效
标题翻译：粉末催化剂装卸工艺及装置
公开(公告)号：US5499746A
公开(公告)日：1996-03-19
申请号：US225725
申请日：1994-04-11
申请人： Georges Berrebi , Yves Jacquier , Habbo Edens , Gerrit Middelkoop
发明人： Georges Berrebi , Yves Jacquier , Habbo Edens , Gerrit Middelkoop
IPC分类号： B65G65/23 , B01J4/00 , B01J8/00 , B65D88/56 , B67D5/64
CPC分类号： B65D88/56 , B01J8/0015 , B01J2208/00761
摘要： The invention relates to a process and apparatus for transport, storage, loading and unloading of catalyst or adsorbent particles utilizing a special container equipped with a fluid-tight valve and which can rock progressively by means of a reverse-lock, escapement-type ratchet.
摘要翻译：本发明涉及一种使用装有流体密封阀的特殊容器运输，储存，装载和卸载催化剂或吸附剂颗粒的方法和装置，该装置可通过反向锁定的擒纵型棘轮逐渐摇摆。

10. 发明授权

US5068477A Process for reducing a refining catalyst and use of the catalyst in hydrogenation 失效
标题翻译：减少精炼催化剂的方法和催化剂在氢化反应中的应用
公开(公告)号：US5068477A
公开(公告)日：1991-11-26
申请号：US692756
申请日：1991-04-29
申请人： Georges Berrebi
发明人： Georges Berrebi
IPC分类号： B01J23/96 , B01J23/40 , B01J23/50 , B01J23/74 , B01J23/94 , B01J37/02 , B01J37/16 , B01J38/52 , B01J38/62 , C07C1/00 , C07C5/02 , C07C67/00 , C10G45/02 , C10G45/40
CPC分类号： B01J37/0203 , B01J23/40 , B01J23/50 , B01J23/74 , B01J37/16 , C10G45/40
摘要： This invention concerns a process for reducing a refining catalyst before it is put into use, the catalyst containing a support and an active phase based on at least one noble or non-noble metal of group VIII or of group Ib of the periodic classification of elements, consisting of:(a) impregnating the catalyst with an aqueous or organic solution of a reducing agent,(b) decomposing the reducing agent by heating with a catalyst, and(c) drying the catalyst thus obtained.The catalyst is used in selective hydrogention of a feed such as olefin, acetylenes, diolefins etc.

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