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1. 发明授权

US4596878A Process for the production of maleic anhydride 失效
标题翻译：马来酸酐生产工艺
公开(公告)号：US4596878A
公开(公告)日：1986-06-24
申请号：US645329
申请日：1984-08-29
申请人： Gaylon T. Click , Bruno J. Barone
发明人： Gaylon T. Click , Bruno J. Barone
IPC分类号： B01J27/28 , C07C51/215 , C07C51/25 , C07D307/60
CPC分类号： C07C51/215 , B01J27/285 , C07C51/252 , Y02P20/584
摘要： The useful life of vanadium-phosphorus-oxygen (PVO) catalyst in fixed bed reactors can be substantially extended by treatment with a phosphorus compound followed by steam treatment. The PVO catalysts may be treated with steam after long periods (months) of only phosphorus compound treatment and the benefit of the present invention obtained or the phosphorus and steam treatments may be of only a few hours duration and sequential. In extending the useful life of the PVO catalyst according to the present invention, the temperature profile in the catalyst bed is restored to substantially the same profile as the fresh catalyst.
摘要翻译：固定床反应器中的钒 - 磷 - 氧（PVO）催化剂的使用寿命可以通过用磷化合物处理然后进行蒸汽处理而大大延长。 PVO催化剂可以在仅经过磷化合物处理的长时间（月）之后用蒸汽处理，并且所获得的本发明的益处或磷和蒸汽处理可能只有几个小时的持续时间和顺序。在延长根据本发明的PVO催化剂的使用寿命期间，催化剂床中的温度曲线恢复到与新鲜催化剂基本相同的轮廓。

2. 发明授权

US4283307A Catalyst structure for the partial oxidation of n-butane to produce maleic anhydride 失效
标题翻译：用于部分氧化正丁烷以生产马来酸酐的催化剂结构
公开(公告)号：US4283307A
公开(公告)日：1981-08-11
申请号：US155556
申请日：1980-06-02
申请人： Bruno J. Barone , Gaylon T. Click
发明人： Bruno J. Barone , Gaylon T. Click
IPC分类号： C07D307/60 , B01J23/22 , B01J27/18 , B01J27/198 , B01J35/02 , C01B25/45 , C07B61/00 , C07C51/215 , B01J35/00
CPC分类号： C07C51/215 , B01J23/002 , B01J23/22 , B01J27/198 , B01J35/026 , B01J2523/00
摘要： Phosphorus-Vanadium oxidation catalyst prepared as tablets with a hole in the center produce higher yields of maleic anhydride from C.sub.4 's, particularly n-butane than the same catalyst without the hole.
摘要翻译：由中心产生的具有孔的片剂制备的磷 - 钒氧化催化剂比没有孔的相同催化剂产生更高的C4，特别是正丁烷的马来酸酐产率。

3. 再颁专利

USRE30430E Catalyst treatment 失效
标题翻译：催化剂处理
公开(公告)号：USRE30430E
公开(公告)日：1980-11-04
申请号：US14833
申请日：1979-02-26
申请人： Ralph O. Kerr
发明人： Ralph O. Kerr
IPC分类号： B01J23/92 , B01J37/28 , C07C51/31
CPC分类号： B01J37/28 , B01J23/92 , C07C51/313 , Y02P20/584
摘要： Molybdenum - vanadium - oxygen oxidation catalyst for producing maleic anhydride from benzene is regenerated and stabilized by the addition of a compound of Mo, Ni, Co, Mn or U, preferably a volatile compound, to the catalyst, after a decline in activity.

4. 发明授权

US4212780A Polychloroprene non-phasing solvent cements 失效
标题翻译：聚氯丁二烯非相溶剂水泥
公开(公告)号：US4212780A
公开(公告)日：1980-07-15
申请号：US899080
申请日：1978-04-24
申请人： Kenneth D. Fitzgerald
发明人： Kenneth D. Fitzgerald
IPC分类号： C08F2/26 , C08L11/00 , C09J111/00 , C09J161/06 , C08L93/04 , C08K5/01 , C08L9/00
CPC分类号： C09J111/00 , C09J161/06 , C08L11/00
摘要： Chloroprene polymer-phenolic resin-metal oxide-solvent adhesives, which are non-phasing and which contain from about 4 to 6 parts by weight based on polymer of a rosin which must contain less than 2.16 parts by weight based on polymer of dehydroabietic acid, a constituent of rosin.
摘要翻译：氯丁橡胶聚合物 - 酚醛树脂 - 金属氧化物 - 溶剂粘合剂，其为非定相并且基于松香聚合物含有约4至6重量份，其必须含有基于脱氢松香酸的聚合物小于2.16重量份，松香的成分。

5. 发明授权

US4203905A Method for preparing stable, liquid tetrahydrophthalic anhydride for use in preparing polyesters 失效
标题翻译：制备用于制备聚酯的稳定的液体四氢邻苯二甲酸酐的方法
公开(公告)号：US4203905A
公开(公告)日：1980-05-20
申请号：US934505
申请日：1978-08-17
申请人： Marvin Z. Woskow
发明人： Marvin Z. Woskow
IPC分类号： C07C51/50 , C07D317/64 , C07D307/24
CPC分类号： C07D317/64 , C07C51/50
摘要： Tetrahydrophthalic anhydride for the preparation of polyesters is conveniently prepared in a stable, liquid form for transportation and storage by adding molten anhydride to a 100.degree. to 120.degree. C., C.sub.2 to C.sub.9 glycol at rate to maintain this temperature range without raising the temperature of the mixture in increments of more than 5.degree. F., reacting the mixture for a sufficient time to reduce the acid number of the mixture to a number in the range below the theoretical acid number for the half ester of the glycol and anhydride and 165; thereafter cooling the mixture to 155.degree. C., adding glycol as necessary to provide a mole ratio of glycol to anhydride in the range of 1.2 to 2:1 and cooling the mixture to a temperature in the range of 40.degree. to 70.degree. C.
摘要翻译：用于制备聚酯的四氢邻苯二甲酸酐方便地以稳定的液体形式制备，用于运输和储存，通过将熔融的酸酐加入到100-120℃，速率维持该温度范围而不升高温度该混合物的增量大于5°F，使混合物反应足够的时间以将该混合物的酸值降低到低于二醇和酐的半酯的理论酸值的范围内且165; 然后将混合物冷却至155℃，根据需要加入乙二醇以使乙二醇与酐的摩尔比在1.2至2:1的范围内，并将该混合物冷却至40℃至70℃的温度。

6. 发明授权

US4179404A Catalyst preparative method 失效
标题翻译：催化剂制备方法
公开(公告)号：US4179404A
公开(公告)日：1979-12-18
申请号：US750920
申请日：1976-12-15
申请人： Bruno J. Barone
发明人： Bruno J. Barone
IPC分类号： B01J27/198 , C07C51/215 , B01J27/14
CPC分类号： B01J27/198 , C07C51/215
摘要： The preparation of phosphorus-vanadium oxidation catalyst by the reduction of the valence of vanadium to less than +5 is obtained by employing less than the stoichiometric amount of reducing agent necessary to reduce the valence of the vanadium from +5 to +4, preferably 70 to 98% of the stoichiometric amount of reducing agent can be used.
摘要翻译：通过使用少于化学计量量的还原剂将钒降低至+5至+4，优选为70来获得，钒 - 钒氧化催化剂通过将钒价态降低至小于+5得到。可以使用98％的化学计量的还原剂。

7. 发明授权

US4172961A Production of 1,4-butanediol 失效
标题翻译：生产1,4-丁二醇
公开(公告)号：US4172961A
公开(公告)日：1979-10-30
申请号：US602992
申请日：1975-08-08
申请人： James D. Henery , Robert P. Arganbright
发明人： James D. Henery , Robert P. Arganbright
IPC分类号： C07C29/149 , C07C29/76 , C07C29/80 , C07C29/86 , C07C31/20
CPC分类号： C07C29/86 , C07C29/149 , C07C29/76 , C07C29/80
摘要： An improved process for the production of 1,4-butanediol is disclosed wherein a dialkyl alkoxy succinate-containing mixture is contacted with hydrogen at elevated temperature and pressure in the presence of a copper chromite hydrogenation catalyst to form a mixture comprising 1,4-butanediol and the corresponding alkanol. In a preferred embodiment, dibutyl butoxy succinate is converted to 1,4-butanediol and n-butanol at high selectivities.
摘要翻译：公开了一种制备1,4-丁二醇的改进方法，其中在亚铬酸铜加氢催化剂存在下，在高温和高压下使含二烷基烷基琥珀酸酯的混合物与氢气接触以形成包含1,4-丁二醇和相应的链烷醇。在优选的实施方案中，琥珀酸二丁酯以高选择性转化为1,4-丁二醇和正丁醇。

8. 发明授权

US4123388A Catalyst and process for preparing maleic anhydride from C.sub.4 hydrocarbons 失效
标题翻译：催化剂和从C {HD 4 {B烃
公开(公告)号：US4123388A
公开(公告)日：1978-10-31
申请号：US812582
申请日：1977-07-05
申请人： Ralph O. Kerr , Bruno J. Barone
发明人： Ralph O. Kerr , Bruno J. Barone
IPC分类号： B01J23/84 , B01J23/89 , B01J27/198 , C07C51/215 , B01J27/18
CPC分类号： B01J23/8472 , B01J23/84 , B01J23/898 , B01J27/198 , C07C51/215
摘要： A catalyst complex useful for converting normal C.sub.4 hydrocarbons to maleic anhydride in vapor phase comprising as components vanadium, phosphorus, copper, an element selected from the group of Te, Zr, Ni, Ce, W, Pd, Ag, Mn, Cr, Zn, Mo, Re, Sm, La, Hf, Ta, Th, Co, U, and Sn, preferably with an alkali or alkaline earth metal.
摘要翻译：一种催化剂配合物，用于将蒸气相中的正常C 4烃转化为马来酸酐，其中包含钒，磷，铜，选自Te，Zr，Ni，Ce，W，Pd，Ag，Mn，Cr，Zn ，Mo，Re，Sm，La，Hf，Ta，Th，Co，U和Sn，优选用碱金属或碱土金属。

9. 发明授权

US4071539A Process for preparing maleic anhydride from C.sub.4 hydrocarbons 失效
标题翻译：从C {HD 4 {B烃
公开(公告)号：US4071539A
公开(公告)日：1978-01-31
申请号：US667623
申请日：1976-03-17
申请人： Ralph O. Kerr , Bruno J. Barone
发明人： Ralph O. Kerr , Bruno J. Barone
IPC分类号： B01J23/84 , B01J23/89 , B01J27/198 , C07C51/215 , C07C51/25 , C07D307/60
CPC分类号： C07C51/215 , B01J23/84 , B01J23/898 , B01J27/198 , C07C51/25 , C07C51/252
摘要： A catalyst complex useful for converting normal C.sub.4 hydrocarbons to maleic anhydride in vapor phase comprising as components vanadium, phosphorus, copper, an element selected from the group of Te, Zr, Ni, Ce, W, Pd, Ag, Mn, Cr, Zn, Mo, Re, Sm, La, Hf, Ta, Th, Co, U, and Sr, preferably with an alkali or alkaline earth metal.
摘要翻译：一种催化剂配合物，用于将蒸气相中的正常C 4烃转化为马来酸酐，其中包含钒，磷，铜，选自Te，Zr，Ni，Ce，W，Pd，Ag，Mn，Cr，Zn ，Mo，Re，Sm，La，Hf，Ta，Th，Co，U和Sr，优选用碱金属或碱土金属。

10. 发明授权

US4251390A Partial oxidation catalyst 失效
标题翻译：部分氧化催化剂
公开(公告)号：US4251390A
公开(公告)日：1981-02-17
申请号：US47323
申请日：1979-06-11
申请人： Bruno J. Barone
发明人： Bruno J. Barone
IPC分类号： C07D307/60 , B01J23/22 , B01J27/18 , B01J27/198 , C01B25/37 , C07B61/00 , C07C51/215 , C07C51/25 , B01J27/14 , B01J31/02
CPC分类号： C07C51/215 , B01J23/22 , B01J27/198 , C07C51/252 , B01J2523/00
摘要： An improvement in the oxidation catalyst used for the partial oxidation of n-butane and containing vanadium and phosphorus mixed oxides which comprises adding a zinc compound in an amount of from about 0.15 to 0.001/l Zn/V to the catalyst during the digestion of the reduced vanadium component by concentrated phosphoric acid. The addition of zinc produces a catalyst which is more easily activated and which is very stable to heat upset of the reaction system. Small amounts of lithium and silicon compounds also have additional desirable catalytic effects without dimunition of the zinc compound benefit.
摘要翻译：用于正丁烷并含有钒和磷混合氧化物的部分氧化的氧化催化剂的改进包括在消化过程中向催化剂中加入约0.15至0.001 / l Zn / V的锌化合物用浓磷酸还原钒组分。锌的添加产生更容易活化的催化剂，并且其对于反应体系的热不安非常稳定。少量的锂和硅化合物还具有额外的期望的催化效果，而不会使锌化合物的益处不变。

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