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    • 2. 发明授权
    • Treatment of industrial wastewaters
    • 工业废水处理
    • US4465597A
    • 1984-08-14
    • US291439
    • 1981-08-10
    • Stewart T. HermanJames B. PfeifferRichard T. Sewald, Sr.Charles J. Sterner
    • Stewart T. HermanJames B. PfeifferRichard T. Sewald, Sr.Charles J. Sterner
    • C02F1/62C02F1/52C02F1/66C02F9/00
    • C02F9/00C02F1/5281C02F1/66C02F2101/20Y10S210/912
    • An industrial wastewater treatment method is described whereby heavy metals dissolved in the wastewater are precipitated as a slurry which, when allowed to settle, will form a sludge containing at least 10 weight percent solids. In the method, an aqueous suspension or solution of a neutralizing agent is introduced into a first reactor. A suspension containing particles of carrier agent is also introduced into the first reactor. A portion, if not all, of the neutralizing agent is adsorbed on the surface of the particles of the carrier, which are maintained in suspension in the first reactor. The carrier, with its adsorbed neutralizing agent, is passed to a second reactor and simultaneously the contaminated industrial wastewater is added to the second reactor. The pH of the wastewater is adjusted to a range between 8.4 and 10.6 by the neutralizing agent. Within such pH range, a substantial portion, if not all, of the heavy metals are precipitated in the form of a slurry. The mixture in the second reactor is passed to a solids separation device. The solids in the slurry settle to the bottom of the device to form a sludge which is removed therefrom. Purified water is removed as an overflow from the separation device. Optionally, a flocculant may be added to aid in settling the solids.Insoluble calcium salts may also be precipitated in the second reactor. Such insoluble salts are adsorbed on the surface of the carrier and/or the heavy metal slurry particles and become part of the sludge formed in the separation device.
    • 描述了一种工业废水处理方法,其中溶解在废水中的重金属作为浆料沉淀,当其沉降时,将形成含有至少10重量%固体的污泥。 在该方法中,将中和剂的水性悬浮液或溶液引入第一反应器。 含有载体剂颗粒的悬浮液也被引入到第一反应器中。 中和剂的一部分(如果不是全部)被吸附在保持在第一反应器中的载体颗粒的表面上。 将其吸附的中和剂的载体通入第二反应器,同时将污染的工业废水加入到第二反应器中。 通过中和剂将废水的pH调节至8.4至10.6之间。 在这样的pH范围内,大部分(如果不是全部)的重金属以浆料的形式沉淀。 将第二反应器中的混合物送入固体分离装置。 浆料中的固体沉淀到装置的底部以形成从其中除去的污泥。 净化水从分离装置溢出时被去除。 任选地,可以加入絮凝剂以帮助沉降固体。 不溶性钙盐也可以在第二反应器中沉淀。 这种不溶性盐被吸附在载体和/或重金属浆料颗粒的表面上并成为在分离装置中形成的污泥的一部分。