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    • 2. 发明授权
    • Process for the production of multicoat protective and/or decorative
coatings on substrate surfaces
    • 在基材表面上生产多层保护和/或装饰涂层的方法
    • US5512322A
    • 1996-04-30
    • US334476
    • 1994-11-04
    • Hans-Dieter HilleStefan C. WieditzArnold DobbelsteinHorst Muller
    • Hans-Dieter HilleStefan C. WieditzArnold DobbelsteinHorst Muller
    • B05D7/16C08G18/08C08G18/12C08G18/40C08G18/66C09D175/04B05D1/36C08G18/34C08G18/42
    • B05D7/532C08G18/0819C08G18/12C08G18/4018C08G18/6625C09D175/04
    • The invention relates to a basecoat/clearcoat process in which the basecoat composition used contains as a film former a polyurethane resin which can be prepared by preparing an intermediate from(A) a mixture obtained from 10 to 90 mol % of linear polyether diols and 90 to 10 mol % of polyester diols,(B) diisocyanates,(C) compounds which contain two groups reactive toward isocyanate groups, at least some of these compounds having at least one group capable of forming anions,and the free isocyanate groups of the said intermediate are then reacted with(D) polyols containing at least three hydroxyl groups, and the reaction product obtained in this manner is transferred into an aqueous base, whereina) the polyester diol is prepared from diols and an acid component which consists of 60 to 100% by weight of aliphatic dicarboxylic acids of more than 18 carbon atoms and of 40 to 0% by weight of aliphatic dicarboxylic acids of 2 to 18 carbon atoms,b) the equivalent ratio of the NCO groups to the total of the OH groups of (A) and the reactive groups of (C) is 2:1 to 1.05:1 andc) the equivalent of the OH groups of the component (D) to the NCO groups of the intermediate is 0.5:1 to 4:1.
    • 本发明涉及一种底漆/透明涂料方法,其中所用的底漆组合物包含作为成膜剂的聚氨酯树脂,其可以通过从(A)得到的线性聚醚二醇和10至90摩尔的直链聚醚二醇的混合物制备中间体 至10mol%的聚酯二醇,(B)二异氰酸酯,(C)含有两个对异氰酸酯基反应的基团的化合物,至少一些具有至少一个能够形成阴离子基团的化合物,以及所述 然后使中间体与(D)含有至少三个羟基的多元醇反应,将以这种方式获得的反应产物转移到碱的水溶液中,其中a)聚酯二醇由二醇和酸组分制备,其由60至 碳原子数为18以上的脂肪族二羧酸100重量%,碳原子数2〜18的脂肪族二羧酸40〜0重量%,b)NCO基的当量比 (A)的OH基团和(C)的反应性基团的总数为2:1至1.05:1,和c)组分(D)的OH基相当于中间体的NCO基团的当量 为0.5:1至4:1。