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    • 3. 发明申请
    • Lubricant and additive formulation
    • 润滑剂和添加剂配方
    • US20050124504A1
    • 2005-06-09
    • US10915251
    • 2004-08-10
    • Zhigiang ZhangThomas SmithGefei WuFrances LockwoodRichard BaumgartMichael Dituro
    • Zhigiang ZhangThomas SmithGefei WuFrances LockwoodRichard BaumgartMichael Dituro
    • C10M125/02C10M161/00C10M169/04
    • B82Y30/00C10M125/02C10M161/00C10M169/044C10M2201/041C10M2215/064C10M2223/045C10M2227/061C10N2210/06C10N2220/082C10N2230/02C10N2240/10
    • A lubricant composition for use as a concentrate and motor oil having an enhanced thermal conductivity. One preferred composition contains a lubricant composition, nanomaterial, and a dispersing agent or surfactant for the purpose of stabilizing the nanomaterial. One preferred nanomaterial is a high thermal conductivity graphite, exceeding 80 W/m in thermal conductivity. Carbon nano material or nanostructures such as nanotubes, nanofibrils, and nanoparticles formed by grounding and/or milling graphite to obtain a mean particle size less than 500 nm in diameter, and preferably less than 100 nm, and most preferably less than 50 nm. Other high thermal conductivity carbon materials are also acceptable. To confer long-term stability, the use of one or more chemical dispersants or surfactants is useful. The graphite nanomaterials contribute to the overall fluid viscosity and providing a very high viscosity index. Particle size and dispersing chemistry is controlled to get the desired combination of viscosity and thermal conductivity increase from the lubricant. The resulting fluids have unique properties due to the high thermal conductivity and high viscosity index of the suspended particles, as well as their small size.
    • 用作浓缩物和具有增强的导热性的机油的润滑剂组合物。 一种优选的组合物包含润滑剂组合物,纳米材料和用于稳定纳米材料的分散剂或表面活性剂。 一种优选的纳米材料是导热系数高于80W / m的高导热性石墨。 通过将石墨接地和/或研磨形成碳纳米材料或纳米结构,例如纳米管,纳米原纤维和纳米颗粒,以获得直径小于500nm,优选小于100nm,最优选小于50nm的平均粒度。 其他高导热性碳材料也是可以接受的。 为了赋予长期稳定性,使用一种或多种化学分散剂或表面活性剂是有用的。 石墨纳米材料有助于整体流体粘度和提供非常高的粘度指数。 控制粒度和分散化学,以获得润滑剂所需的粘度和热导率增加的组合。 所得到的流体由于悬浮颗粒的高导热性和高粘度指数以及它们的小尺寸而具有独特的性质。
    • 5. 发明申请
    • Monocarboxylic acid based antifreeze composition
    • 单羧酸防冻组合物
    • US20040227124A1
    • 2004-11-18
    • US10755713
    • 2004-01-12
    • ASHLAND INC.
    • David E. TurcotteMichael A. DituroArnold L. Coffey JR.Alden W. OlsenCarl R. Stephens
    • C09K005/00
    • C23F11/08C09K5/20
    • The present invention relates to a carboxylic acid based antifreeze coolant formulation for heavy duty applications such as for diesel engines which may be used for inhibition and prevention erosion and corrosion of aluminum and the corrosion of other metals exposed to an aqueous liquid in automotive coolant systems. The formulation further inhibits mineral scale. It may be packaged as an ethylene glycol based additive for use in new engines or in a concentrated inhibition package as an additive as for reinhibition of used coolant. The combination of a mixture of ethylene or propylene glycol, a monobasic carboxylic organic acid, azoles, low levels of molybdates, a nitrite salt and/or nitrate salt and/or siloxane stabilized silicate, and combinations thereof, polyvinylpyrrolidone, provide a synergistic protective effect against the cavitation corrosion of aluminum in aqueous liquids reducing the corrosion rate and is effective at relatively low concentrations and varying pH ranges.
    • 本发明涉及用于重型应用的羧酸基防冻剂冷却剂制剂,例如用于柴油发动机,其可用于抑制和防止铝的侵蚀和腐蚀以及暴露于汽车冷却剂系统中的含水液体的其它金属的腐蚀。 该制剂进一步抑制矿物垢。 它可以作为用于新发动机的乙二醇基添加剂或作为添加剂的浓缩抑制包装被包装,用于重新抑制用过的冷却剂。 乙烯或丙二醇的混合物,一元羧酸有机酸,唑类,低水平的钼酸盐,亚硝酸盐和/或硝酸盐和/或硅氧烷稳定的硅酸盐的混合物及其组合,聚乙烯吡咯烷酮的组合​​提供了协同的保护作用 防止铝在水性液体中的气穴腐蚀降低腐蚀速率,并且在相对低的浓度和不同的pH范围内是有效的。
    • 6. 发明申请
    • Enhancing thermal conductivity of fluids with graphite nanoparticles and carbon nanotube
    • 用石墨纳米颗粒和碳纳米管提高流体的导热性
    • US20040209782A1
    • 2004-10-21
    • US10730762
    • 2003-12-08
    • ASHLAND INC.
    • Zhigiang ZhangFrances E. Lockwood
    • C10M125/02
    • B82Y30/00C10M125/02C10M141/06C10M169/04C10M2201/041C10M2205/0285C10M2215/28C10N2220/082C10N2220/086C10N2270/00Y10S977/742Y10S977/745
    • Fluid compositions that have enhanced thermal conductivity, up to 250% greater than their conventional analogues, and methods of preparation for these fluids are identified. The compositions contain at a minimum, a fluid media such as oil or water, and a selected effective amount of carbon nanomaterials necessary to enhance the thermal conductivity of the fluid. One of the preferred carbon nanomaterials is a high thermal conductivity graphite, exceeding that of the neat fluid to be dispersed therein in thermal conductivity, and ground, milled, or naturally prepared with mean particle size less than 500 nm, and preferably less than 200 nm, and most preferably less than 100 nm. The graphite is dispersed in the fluid by one or more of various methods, including ultrasonication, milling, and chemical dispersion. Carbon nanotube with graphitic structure is another preferred source of carbon nanomaterial, although other carbon nanomaterials are acceptable. To confer long term stability, the use of one or more chemical dispersants is preferred. The thermal conductivity enhancement, compared to the fluid without carbon nanomaterial, is somehow proportional to the amount of carbon nanomaterials (carbon nanotubes and/or graphite) added.
    • 确定了具有增强的导热性,高于其常规类似物250%的流体组合物以及这些流体的制备方法。 组合物至少包含诸如油或水的流体介质和选择的有效量的碳纳米材料,以增强流体的导热性。 优选的碳纳米材料之一是高导热性石墨,超过要在其中分散在其中的纯净流体的导热性,并且研磨,研磨或天然制备的平均粒度小于500nm,优选小于200nm ,最优选小于100nm。 石墨通过一种或多种各种方法分散在流体中,包括超声波处理,研磨和化学分散。 具有石墨结构的碳纳米管是碳纳米材料的另一优选来源,尽管其他碳纳米材料是可接受的。 为了赋予长期稳定性,优选使用一种或多种化学分散剂。 与没有碳纳米材料的流体相比,热导率增强与添加的碳纳米材料(碳纳米管和/或石墨)的量成比例。
    • 10. 发明授权
    • Valve assembly with flush and sample capability
    • 具有冲洗和取样功能的阀门组件
    • US6125871A
    • 2000-10-03
    • US235886
    • 1999-01-22
    • Gilbert J. DrabChristopher M. SweeneyAkimoto Ochi
    • Gilbert J. DrabChristopher M. SweeneyAkimoto Ochi
    • B08B9/02F16L37/08F16L37/28G01N1/20G01N1/10B08B3/04
    • B08B9/0321B08B9/021F16L37/08F16L37/28G01N2001/205Y10T137/0424Y10T137/4259Y10T137/87105Y10T137/87925
    • A chemical fluid valve transfer (e.g., load/unload) assembly is formed from a male valve assembly and a female valve assembly. The male valve assembly is fitted with a male connector which houses a chamber that is connected to a flush inlet line, and a flush outlet line, and a chemical transport line. The female valve assembly is fitted with a female connector which mates with the male valve assembly male connector for interconnecting the male valve and female valve assemblies, and fitted with a chemical transport line. Another aspect of the present invention is a method for transferring a chemical fluid between a tanker fitted with a female coupler and a fill/unload station fitted with a male coupler and hose assembly. This method involves the connecting of the tanker hose and the fill station hose with the valve assembly described above. Next, the male and female connectors and said chamber are purged with liquid or gaseous cleaning fluid admitted via the flush inlet flush line and withdrawn via the flush outlet line. One of the male valve assembly or the female valve assembly then is opened to permit the chemical fluid to enter into the chamber for withdrawal therefrom via the flush outline line for its sampling. Finally, the chemical fluid is transferred between the tanker and the fill station through the valve assembly.
    • 化学流体阀传递(例如,装载/卸载)组件由阳阀组件和阴阀组件形成。 阳阀组件装有一个阳连接器,该阳连接器容纳连接到冲洗入口管线的一个室,以及一个冲洗出口管线和一个化学输送管线。 阴阀组件配有阴连接器,该阴连接器与阳阀组件公连接器配合,用于互连阳阀和阴阀组件,并配有化学输送管线。 本发明的另一方面是一种用于在装配有母耦合器的油罐车和装有阳联接器和软管组件的填充/卸载站之间转移化学流体的方法。 该方法涉及使用上述阀组件连接油罐软管和填充站软管。 接下来,阳,阴连接器和所述腔室被清洗通过冲洗入口冲洗管线通过冲洗出口管线排出的液体或气体清洁流体。 阳阀组件或阴阀组件中的一个然后被打开以允许化学流体进入腔室中,以通过冲洗轮廓线从其中取出用于其取样。 最后,化学液体通过阀门组件在油罐和加油站之间传送。