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1. 发明申请

US20080032886A1 Doped solid acid catalyst composition, process of conversion using same and conversion products thereof 审中-公开
标题翻译：掺杂固体酸催化剂组合物，使用其的转化方法及其转化产物
公开(公告)号：US20080032886A1
公开(公告)日：2008-02-07
申请号：US11498655
申请日：2006-08-03
申请人： Chuen Y. Yeh , Jinsuo Xu , Philip J. Angevine
发明人： Chuen Y. Yeh , Jinsuo Xu , Philip J. Angevine
IPC分类号： B01J37/00
CPC分类号： B01J23/6527 , B01J23/002 , B01J23/8993 , B01J27/055 , B01J37/0009 , B01J37/0201 , B01J2523/31 , B01J2523/48 , B01J2523/69 , C10G11/04 , C10G29/16 , C10G45/62 , C10G47/14 , C10G50/00
摘要： A doped solid acid catalyst composition comprising at least one solid acid catalyst, at least one metal promoter for solid acid catalyst (a), at least one basic dopant for solid acid catalyst (a), at least one noble metal; and, optionally, at least one refractory binder.
摘要翻译：包含至少一种固体酸催化剂，至少一种用于固体酸催化剂（a）的金属助催化剂，至少一种固体酸催化剂（a）的碱性掺杂剂，至少一种贵金属的掺杂固体酸催化剂组合物; 和任选的至少一种耐火粘合剂。

2. 发明授权

US07316127B2 Hydrocarbon gas processing for rich gas streams 有权
标题翻译：富气气体的烃气处理
公开(公告)号：US07316127B2
公开(公告)日：2008-01-08
申请号：US11102947
申请日：2005-04-11
申请人： Robert R. Huebel , Jorge H. Foglietta , Sanjiv N. Patel
发明人： Robert R. Huebel , Jorge H. Foglietta , Sanjiv N. Patel
IPC分类号： F25J3/00
CPC分类号： C07C7/09 , F25J3/0209 , F25J3/0219 , F25J3/0233 , F25J3/0238 , F25J2200/08 , F25J2200/70 , F25J2200/76 , F25J2200/78 , F25J2210/06 , F25J2210/12 , F25J2270/04
摘要： A process for the recovery of ethane and heavier hydrocarbon components from a hydrocarbon feed gas stream. Feed gas stream is cooled into a first and second cooled streams. First and second cooled streams are sent to a cold absorber and separated into a first gas stream and a first liquid stream. First gas stream is expanded and sent to a fractionation tower. At least a part of the first liquid stream is sent to a pre-demethanizer stripper tower. Stripper tower produces a stripper overhead stream and a stripper bottoms stream. Stripper overhead vapor stream is cooled and sent to the fractionation tower as second reflux stream. Stripper bottoms stream is supplied to the fractionation tower. Temperatures and pressures of the streams and columns are maintained to recover a major portion of ethane and heavier hydrocarbon components as a bottoms product stream, and produce a residue gas stream at the fractionation tower overhead. At least a portion of the residue gas stream is recycled, cooled and sent to the fractionation tower as first reflux stream.
摘要翻译：一种从烃进料气流中回收乙烷和较重烃组分的方法。进料气流被冷却成第一和第二冷却流。将第一和第二冷却流送至冷吸收器并分离成第一气流和第一液流。将第一气流膨胀并送入分馏塔。第一液体流的至少一部分被送到脱甲烷塔脱气塔。汽提塔产生汽提塔塔顶馏出物和汽提塔底部物流。汽提器塔顶蒸气流被冷却并作为第二回流流送到分馏塔。汽提塔底部料流被提供给分馏塔。维持流和塔的温度和压力以回收大部分乙烷和较重的烃组分作为塔底产物流，并在分馏塔顶部产生残余气流。残余气流的至少一部分被再循环，冷却并作为第一回流流送入分馏塔。

3. 发明授权

US07301062B2 Process for the selective hydrogenation of alkynes and/or dienes in an olefin-containing hydrocarbon stream 有权
标题翻译：在含烯烃的烃流中选择氢化炔烃和/或二烯烃的方法
公开(公告)号：US07301062B2
公开(公告)日：2007-11-27
申请号：US10899644
申请日：2004-07-27
申请人： Robert J. Gartside , Thomas Skourlis
发明人： Robert J. Gartside , Thomas Skourlis
IPC分类号： C07C5/08 , C07C5/09
CPC分类号： C07C7/163 , C07C7/167 , C07C2523/50 , Y02P20/127 , Y02P20/52 , C07C11/08 , C07C11/06 , C07C11/04
摘要： A process for the selective hydrogenation of one or more alkyne and/or one or more diene in an olefin-containing hydrocarbon feed includes contacting the hydrocarbon feed with a catalyst under selective hydrogenation conditions, the catalyst including from about 0.01 to about 0.1 weight percent palladium and from about 0.005 to about 0.6 weight percent of at least one Group IB metal incorporated into an inorganic support, wherein the surface area of the support is from about 2 to about 20 m2/g, the pore volume is greater than about 0.4 cc/g, at least about 90% of the pore volume is contained in pores with pore diameters larger than about 500 Å, and the pore volume of the pores with a pore diameter from about 500 to about 1,000 Å comprise from about 1% to about 2% of the total pore volume.
摘要翻译：在含烯烃的烃进料中一种或多种炔和/或一种或多种二烯的选择性氢化的方法包括在选择性氢化条件下使烃进料与催化剂接触，所述催化剂包括约0.01至约0.1重量％的钯和约0.005至约0.6重量％的至少一种掺入无机载体中的IB族金属，其中载体的表面积为约2至约20m 2 / g，孔体积大于约0.4cc / g，孔体积的至少约90％包含在孔径大于约500的孔中，并且孔直径为约500至约1000埃的孔的孔体积占总孔体积的约1％至约2％。

4. 发明授权

US07232785B2 Solid catalytic component and catalytic system of the ziegler-natta type, process for their preparation and their use in the polymerization of alk-1-enes 失效
标题翻译：齐格勒 - 纳塔型固体催化组分和催化体系，其制备方法及其在烷-1-烯的聚合中的应用
公开(公告)号：US07232785B2
公开(公告)日：2007-06-19
申请号：US10504702
申请日：2003-01-28
申请人： Wolf Spaether , John Lynch , Joachim Rösch , Rainer Hemmerich
发明人： Wolf Spaether , John Lynch , Joachim Rösch , Rainer Hemmerich
IPC分类号： B01J37/00 , B01J31/12
CPC分类号： C08F110/06 , C08F4/651 , C08F4/025 , C08F4/6546 , C08F2500/12 , C08F2500/15 , C08F2500/24
摘要： The present invention relates to a new solid catalytic component, which can be used in combination with an aluminum compound as co-catalyst and optionally an external electron donor as additional co-catalyst to form a catalytic system of the Ziegler-Natta-catalyst-type. The solid catalytic system comprises titanium or vanadium compound, a compound of magnesium containing at least one halogen, a particulate porous support, and optionally an internal electron donor.
摘要翻译：本发明涉及一种新的固体催化组分，其可以与作为助催化剂的铝化合物和任选的外部电子给体一起用作另外的助催化剂以形成齐格勒 - 纳塔催化剂型催化体系。固体催化体系包括钛或钒化合物，含有至少一个卤素的镁的化合物，颗粒状多孔载体和任选的内部电子给体。

5. 发明授权

US07223895B2 Production of propylene from steam cracking of hydrocarbons, particularly ethane 有权
标题翻译：从烃类特别是乙烷的蒸汽裂解生产丙烯
公开(公告)号：US07223895B2
公开(公告)日：2007-05-29
申请号：US10716232
申请日：2003-11-18
申请人： Charles Sumner
发明人： Charles Sumner
IPC分类号： C07C6/02
CPC分类号： C10G9/06 , C07C6/04 , C07C11/06 , Y02P30/44
摘要： An ethane or other hydrocarbon feedstock is steam cracked to produce an ethylene stream which is processed in an ethylene plant recovery section to separate an ethane recycle and a polymer grade or chemical grade ethylene product stream. A portion of the ethylene product stream may then be reacted by dimerization to produce a butene stream. These formed butenes and/or butenes recovered from other sources and another portion of the ethylene product stream are reacted by metathesis to produce a propylene stream which is deethanized and separated from heavier hydrocarbons to produce the propylene product. The butene product stream may also be deethanized and is separated from heavier hydrocarbons. The overhead from the metathesis section deethanizer may be recycled to the ethylene plant recovery section. The reflux for the metathesis section deethanizer may be generated from the overhead or may be a portion of the ethylene product stream.
摘要翻译：乙烷或其他烃原料蒸汽裂化以产生乙烯料流，其在乙烯装置回收段中加工以分离乙烷再循环和聚合物级或化学级乙烯产物流。然后可以通过二聚反应将一部分乙烯产物流反应以产生丁烯流。从其他来源回收的这些形成的丁烯和/或丁烯和乙烯产物流的另一部分通过复分解反应以产生丙烯料流，该丙烯料流与较重的烃脱乙基化并分离以产生丙烯产物。丁烯产物流也可以脱乙烷并与较重的烃分离。来自复分解段脱乙烷器的塔顶馏出物可以再循环到乙烯装置回收部分。复分解段脱乙烷器的回流可以从塔顶产生，也可以是乙烯产物流的一部分。

6. 发明授权

US07084087B2 Zeolite composite, method for making and catalytic application thereof 失效
标题翻译：沸石复合材料，其制备方法和催化应用
公开(公告)号：US07084087B2
公开(公告)日：2006-08-01
申请号：US10691358
申请日：2003-10-22
申请人： Zhiping Shan , Peter Wilhelm Gerhard Waller , Bowden George Maingay , Philip J. Angevine , Jacobus Cornelis Jansen , Chuen Y. Yeh , Thomas Maschmeyer , Frits M. Dautzenberg , Leonardo Marchese , Heloise de Oliveira Pastore
发明人： Zhiping Shan , Peter Wilhelm Gerhard Waller , Bowden George Maingay , Philip J. Angevine , Jacobus Cornelis Jansen , Chuen Y. Yeh , Thomas Maschmeyer , Frits M. Dautzenberg , Leonardo Marchese , Heloise de Oliveira Pastore
IPC分类号： B01J29/06
CPC分类号： C10G11/04 , B01J21/06 , B01J21/12 , B01J23/26 , B01J23/38 , B01J23/44 , B01J23/50 , B01J23/52 , B01J29/005 , B01J29/0308 , B01J29/04 , B01J29/041 , B01J29/084 , B01J29/166 , B01J29/18 , B01J29/40 , B01J29/60 , B01J29/65 , B01J29/70 , B01J29/7007 , B01J29/80 , B01J29/85 , B01J29/87 , B01J29/88 , B01J29/89 , B01J35/002 , B01J35/1023 , B01J35/1028 , B01J35/1038 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J35/108 , B01J37/0018 , B01J37/033 , B01J37/10 , B01J2229/183 , B01J2229/186 , B01J2229/32 , B01J2229/36 , B01J2229/42 , B01J2229/62 , C01B13/366 , C01B33/126 , C01B37/005 , C01B37/02 , C01P2006/12 , C01P2006/14 , C01P2006/16 , C07C2/66 , C07C45/46 , C07D215/227 , C07D301/06 , C07D301/10 , C10G2/332 , C10G11/05 , C10G27/04 , C10G29/205 , C10G45/00 , C10G45/04 , C10G45/12 , C10G45/60 , C10G45/62 , C10G45/64 , C10G45/68 , C10G47/00 , C10G47/14 , C10G47/16 , C10G49/02 , C10G49/08 , C10G50/00 , C10G2300/1096 , C10G2300/301 , C10G2300/4018 , C10G2400/04 , C10G2400/10 , C10G2400/30 , C07C15/073 , C07C49/84
摘要： A catalytic material includes microporous zeolites supported on a mesoporous inorganic oxide support. The microporous zeolite can include zeolite Beta, zeolite Y (including “ultra stable Y”—USY), mordenite, Zeolite L, ZSM-5, ZSM-11, ZSM-12, ZSM-20, Theta-1, ZSM-23, ZSM-34, ZSM-35, ZSM-48, SSZ-32, PSH-3, MCM-22, MCM-49, MCM-56, ITQ-1, ITQ-2, ITQ-4, ITQ-21, SAPO-5, SAPO-11, SAPO-37, Breck-6, ALPO4-5, etc. The mesoporous inorganic oxide can be e.g., silica or silicate. The catalytic material can be further modified by introducing some metals e.g. aluminum, titanium, molybdenum, nickel, cobalt, iron, tungsten, palladium and platinum. It can be used as catalysts for acylation, alkylation, dimerization, oligomerization, polymerization, hydrogenation, dehydrogenation, aromatization, isomerization, hydrotreating, catalytic cracking and hydrocracking reactions.
摘要翻译：催化材料包括负载在介孔无机氧化物载体上的微孔沸石。微孔沸石可以包括沸石β，沸石Y（包括“超稳定Y”-USY），丝光沸石，沸石L，ZSM-5，ZSM-11，ZSM-12，ZSM-20，Theta-1，ZSM-23， ZSM-34，ZSM-35，ZSM-48，SSZ-32，PSH-3，MCM-22，MCM-49，MCM-56，ITQ-1，ITQ-2，ITQ-4，ITQ-21，SAPO- 5，SAPO-11，SAPO-37，Breck-6，ALPO 4 -5等。介孔无机氧化物可以是例如二氧化硅或硅酸盐。催化材料可以通过引入一些金属进一步改性，例如铝，钛，钼，镍，钴，铁，钨，钯和铂。可用作酰化，烷基化，二聚，低聚，聚合，氢化，脱氢，芳构化，异构化，加氢处理，催化裂化和加氢裂化反应的催化剂。

7. 发明申请

US20040181104A1 Catalyst and process for alkyl group dehydrogenation of organic compounds 审中-公开
标题翻译：有机化合物烷基脱氢的催化剂和方法
公开(公告)号：US20040181104A1
公开(公告)日：2004-09-16
申请号：US10791565
申请日：2004-03-02
申请人： ABB Lummus Global Inc.
发明人： Chuen Y. Yeh , Zhiping Shan , Philip J. Angevine , Dinesh Gandhi
IPC分类号： C07C004/02 , B01J031/00
CPC分类号： B01J29/0308 , B01J31/1633 , B01J31/18 , B01J2531/0244 , B01J2531/10 , B01J2531/80 , C07C5/3332 , C07C5/367 , C07C2521/08 , Y02P20/127 , Y02P20/52 , Y02P20/588 , C07C15/46 , C07C15/06
摘要： A dehydrogenation catalyst includes an organometallic pincer complex bonded to a mesoporous inorganic oxide support, the organometallic pincer complex possessing catalytic activity for alkyl group dehydrogenation. The pincer complex includes at least one element selected from Group VIII or Group IB of the Periodic Table of the elements, and at least one element selected from Group VA of the Periodic Table of the elements in each of two molecular arms, the Group VIII or Group IB element being bonded to each of the Group VA elements. The catalyst is advantageously employed in conjunction with catalytic distillation to permit the dehydrogenation of organic compounds at lower temperatures and at lower cost than conventional methods.
摘要翻译：脱氢催化剂包括与介孔无机氧化物载体结合的有机金属夹子络合物，具有烷基脱氢催化活性的有机金属螯合物。钳形复合物包括选自元素周期表第VIII族或第IB族中的至少一种元素，以及选自两种分子臂中的每一种元素的元素周期表第VA族中的至少一种元素，第VIII族或 IB族元素键合到每个VA族元素上。催化剂有利地与催化蒸馏结合使用以允许有机化合物在较低温度下以比常规方法更低的成本脱氢。

8. 发明授权

US6008415A Cyclohexane oxidation 失效
标题翻译：环己烷氧化
公开(公告)号：US6008415A
公开(公告)日：1999-12-28
申请号：US119074
申请日：1998-07-10
申请人： Marvin I. Greene , Charles Summer , Robert J. Gartside
发明人： Marvin I. Greene , Charles Summer , Robert J. Gartside
IPC分类号： C07C29/50 , C07C45/33
CPC分类号： C07C29/50 , C07C45/33 , C07C2101/14
摘要： Cyclohexane is catalytically oxidized to produce cyclohexanol and cyclohexanone and precursors of these products. The oxidation is carried out in a liquid oxidation reactor at high oxygen concentrations (greater than 30% and preferably greater than 90% oxygen concentration) and at relatively low temperatures (less than 160.degree. C.). The use of the liquid oxidation reactor permits the use of these high oxygen concentrations without forming dangerously high levels of oxygen in the overhead gas phase. The result is an increased yield and selectivity of the desired products.
摘要翻译：催化氧化环己烷以产生环己醇和环己酮以及这些产物的前体。在高氧浓度（大于30％，优选大于90％氧气浓度）和相对低的温度（小于160℃）的液体氧化反应器中进行氧化。使用液体氧化反应器允许使用这些高氧浓度，而不会在塔顶气相中形成危险的高水平的氧。结果是所需产物的产率和选择性提高。

9. 发明授权

US5972205A FCC process using binary molecular sieves having a core and shell of different structures and compositions 失效
标题翻译： FCC方法使用具有不同结构和组成的核和壳的二元分子筛
公开(公告)号：US5972205A
公开(公告)日：1999-10-26
申请号：US81754
申请日：1998-05-20
申请人： Chih-Hao Mark Tsang , Pei-Shing Eugene Dai , Randall Hughes Petty
发明人： Chih-Hao Mark Tsang , Pei-Shing Eugene Dai , Randall Hughes Petty
IPC分类号： B01J29/00 , B01J29/40 , B01J29/84 , B01J29/85 , B01J37/02 , C10G11/05
CPC分类号： B01J37/0221 , B01J29/005 , B01J29/84 , B01J29/85 , B01J37/0246 , B01J29/40
摘要： Disclosed is a novel binary sieve catalyst useful for olefin upgrading and fluid catalytic cracking which comprisesa crystalline zeolite metallosilicate core and a shell selected from an aluminum phosphate molecular sieve (AlPO.sub.4), a silicon-substituted aluminophosphate (SAPO), a metal aluminophosphate (MeAPO), and a crystalline metal aluminophosphate (MeAPSO) and is generally synthesized by a method comprising:adding a powdered form of crystalline zeolite metallosilicate into an aqueous slurry comprising phosphoric acid, alumina source, metal salt and an amine, mixing the slurry for 1 to 12 hours in a Teflon liner at room temperature, sealing said slurry in an autoclave and placing said slurry in an oven at 130.degree. C. to 240.degree. C. for 12-168 hours to form said binary molecular sieve catalyst, washing and drying the product, calcining the product at 530 to 570.degree. C. in nitrogen for 5-15 hours, calcining the product in air for 1 to 3 hours to burn off the template.
摘要翻译：公开了一种用于烯烃提质和流化催化裂化的新型二元筛催化剂，其包括结晶沸石金属硅酸盐芯和选自磷酸铝分子筛（AlPO 4），硅取代磷酸铝（SAPO），金属磷酸铝（MeAPO））和结晶金属磷酸铝（MeAPSO），并且通常通过以下方法合成，所述方法包括：将粉末形式的结晶沸石金属硅酸盐添加到包含磷酸，氧化铝源，金属盐和胺的含水浆料中，将所述浆料混合1 在室温下在特氟龙衬里中12小时，将所述浆料密封在高压釜中，并将所述浆料置于130℃至240℃的烘箱中12-168小时以形成所述二元分子筛催化剂，洗涤并干燥产物，在530〜570℃的氮气中煅烧产物5-15小时，在空气中煅烧产物1〜3小时，烧掉模板。

10. 发明授权

US5935889A Catalyst and method of preparation 失效
标题翻译：催化剂及其制备方法
公开(公告)号：US5935889A
公开(公告)日：1999-08-10
申请号：US726367
申请日：1996-10-04
申请人： Lawrence Lee Murrell , Rudolf Alfred Overbeek , Ali M. Khonsari
发明人： Lawrence Lee Murrell , Rudolf Alfred Overbeek , Ali M. Khonsari
IPC分类号： B01J2/00 , B01J37/00 , B01J37/02 , B01J21/04 , B01J35/08
CPC分类号： B01J23/755 , B01J2/006 , B01J37/0221 , B01J37/0232 , B01J37/0242 , B01J23/28 , B01J23/32 , B01J23/40 , B01J23/70 , B01J35/006 , B01J35/0066 , B01J35/008
摘要： Catalyst particles are prepared by coating a core particle, which is usually catalytically inert with respect to the intended chemical reaction, in a fluidized bed coating apparatus. The coating technique involves repeatedly applying and drying small quantities of an atomized slurry containing the coating material in the form of a colloidal dispersion or in the form of very fine, non-colloidal particles preferably mixed with colloidal particles. In this way, incremental layers are formed to produce a final thin shell which has a highly uniform thickness, which is formed on the surface of the core and which does not penetrate porous cores. Various methods are disclosed for converting the coated particles to the desired catalyst form.
摘要翻译：催化剂颗粒通过在流化床涂布设备中涂覆通常催化惰性的核心颗粒来制备。涂覆技术包括反复施加和干燥少量含有胶体分散体形式的涂层材料的雾化浆料，或以非常细的非胶体颗粒的形式，优选与胶体颗粒混合。以这种方式，形成增量层以产生具有高度均匀厚度的最终薄壳，其形成在芯的表面上并且不穿透多孔芯。公开了用于将涂覆的颗粒转化为所需催化剂形式的各种方法。

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