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    • 85. 发明授权
    • Organometallic intercalates
    • 有机金属插层
    • US4237061A
    • 1980-12-02
    • US191
    • 1979-01-02
    • Jack W. Johnson
    • Jack W. Johnson
    • C07F15/02C07F5/00C07F7/00C07F11/00C07F15/04C07F15/06C07F17/00F02B37/00F02B41/10F02B73/00
    • C07F5/00C07F11/005C07F15/06C07F17/00C07F7/003
    • A new group of materials comprises intercalates of organometallic compounds in layered structures of water-insoluble salts comprised of a tetravalent metal cation and an acid phosphate, arsenate or vanadate anion. Related materials comprise intercalates of organometallic compounds in layered structures of uranyl and transuranyl phosphates, arsenates and vanadates. Intercalation hosts are represented either by the formula M(H.sub.1-y A.sub.y XO.sub.4).sub.2.nH.sub.2 O or by the formula H.sub.1-y A.sub.y TO.sub.2 XO.sub.4.nH.sub.2 O, where M is at least one tetravalent cation selected from the group consisting of zirconium, titanium, hafnium, cerium, thorium, tin, lead and germanium, A is at least one monovalent cation selected from the group consisting of lithium, sodium, potassium, rubidium, cesium, ammonium and substituted ammonium, X is at least one element selected from the group consisting of phosphorus, arsenic and vanadium, T is at least one element selected from the group consisting of uranium and transuranic elements, "y" ranges from 0 to 1 and "n" ranges from 0 to 6. Intercalated guests comprise an organometallic cation with a transition metal to which from 2 to 6 ligands are bonded.
    • 一组新材料包括由四价金属阳离子和酸式磷酸盐,砷酸盐或钒酸盐阴离子组成的水不溶性盐的层状结构中的有机金属化合物的插层。 相关材料包括铀酰和芴烷基磷酸盐,砷酸盐和钒酸盐的分层结构中的有机金属化合物的插层。 嵌入主体由式M(H1-yAyXO4)2·nH2O或式H1-yAyTO2XO4·nH2O表示,其中M是选自锆,钛,铪,铈,钍中的至少一种四价阳离子 锡,铅和锗,A是选自锂,钠,钾,铷,铯,铵和取代铵中的至少一种一价阳离子,X是选自磷,砷中的至少一种元素 和钒,T是选自铀和铀元素中的至少一种元素,“y”为0至1,“n”的范围为0至6.插层客体包括具有过渡金属的有机金属阳离子, 2至6个配体键合。