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    • 85. 发明授权
    • Thermosetting acrylic enamel containing iron pyrophosphate
    • 含有焦磷酸铁的热固性丙烯酸搪瓷
    • US4120835A
    • 1978-10-17
    • US878653
    • 1978-02-16
    • Carol Eve Goodell
    • Carol Eve Goodell
    • C08L1/14C08L61/28C09D133/06
    • C09D133/066C08L1/14C08L61/28Y10T428/31688Y10T428/31699
    • An improved thermosetting acrylic enamel containing a film-forming polymer blend of(1) an acrylic polymer containing reactive carboxyl and hydroxyl groups,(2) cellulose acetate butyrate having a 1-6 second viscosity, and(3) a melamine formaldehyde resin at least partially alkylated with an aliphatic monohydric alcohol;The improvement used in combination with the above comprises 0.1-5% by weight, based on the weight of the polymer blend, of iron pyrophosphate powder; this enamel forms a high quality finish on automobiles and trucks and the iron pyrophosphate provides improved gloss retention, and improved blister and darkening resistance under high temperature and humidity conditions.
    • 一种改进的热固性丙烯酸搪瓷,其包含(1)含有反应性羧酸和羟基的丙烯酸聚合物的成膜聚合物共混物,(2)具有1-6秒粘度的纤维素乙酸酯丁酸酯,和(3)至少一种甲醛甲醛树脂 部分碱性单碱性酒精; 与上述结合使用的改进包括0.1-5%的重量,基于聚合物混合物的重量,磷酸磷酸盐粉末的重量; 这个ENAMEL形式的汽车和卡车和铁磷酸盐的高品质表现提供了改进的GLOSS保持,并改善了在高温和湿度条件下的泡沫和耐久性。
    • 90. 发明授权
    • Water-borne bondable base coat and size coat for three piece, tin-free
steel beverage containers
    • 水性可粘合底涂层和三层无锡钢饮料容器的大小涂层
    • US4098745A
    • 1978-07-04
    • US608370
    • 1975-08-27
    • Robert F. Borman
    • Robert F. Borman
    • C09D201/02B65D25/14C08L61/00C08L61/20C09D129/00C09D133/00C09D133/08C09D133/10C09D133/26C09D177/00C08L61/10C08L61/28
    • C09D133/10B65D25/14B65D7/42C09D133/08C09D133/26C08L61/00C08L61/20Y10T428/31688
    • Water-borne or aqueous coating compositions which are especially suitable for use as bondable base coats and size coats in three piece, tin-free steel beverage containers comprise blends of an aqueous dispersion of an amine solubilized interpolymer with aldehyde condensation resins. The interpolymer is prepared in the absence of mercaptans, external surfactants and external dispersion stabilizers and is formed from substituted carboxylic acid amide units; ethylenically unsaturated acid units; hardening units from monomers such as styrene, vinyl toluene or alkyl methacrylate having from 1 to 4 carbon atoms and flexibilizing units from certain alkyl acrylates or methacrylates. The interpolymers are solubilized by neutralizing or partially neutralizing the acid units of the interpolymer with monomeric amines. Aldehyde condensation resins, such as phenol aldehyde resins, aminoplast resins or mixtures thereof are especially desirable. These compositions provide three piece beverage containers with cured base coats and size coats which exhibit excellent adhesion to both the tin-free steel metal and the adhesive employed in forming the container. In addition, the cured base coats and size coats formed from these compositions do not impart undesirable turbidity or taste characteristics to beverages packaged therein.
    • 特别适合用作三片无锡钢饮料容器中的可粘合的基底涂层和尺寸涂层的水性或水性涂料组合物包括胺溶解的互聚物的水分散体与醛缩合树脂的共混物。 在不存在硫醇,外部表面活性剂和外部分散稳定剂的情况下制备互聚物,并由取代的羧酸酰胺单元形成; 烯属不饱和酸单元; 具有1至4个碳原子的单体如苯乙烯,乙烯基甲苯或甲基丙烯酸烷基酯的固化单元和来自某些丙烯酸烷基酯或甲基丙烯酸烷基酯的柔性单元。 互聚物通过用单体胺中和或部分中和互聚物的酸单元来溶解。 醛缩合树脂,如酚醛树脂,氨基塑料树脂或其混合物是特别需要的。 这些组合物提供具有固化的基底涂层和尺寸涂层的三片饮料容器,其对无锡钢金属和用于形成容器的粘合剂都表现出优异的粘合性。 此外,由这些组合物形成的固化的基底涂层和尺寸涂层不会对包装在其中的饮料产生不期望的浊度或味道特性。