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    • 83. 发明授权
    • Permanent antistatic acid copolymer/quaternary amine polymeric films
    • 永久抗静电酸共聚物/季胺聚合物膜
    • US5171641A
    • 1992-12-15
    • US558354
    • 1990-07-25
    • William P. RobertsMarvin R. Havens
    • William P. RobertsMarvin R. Havens
    • B32B27/28C07C211/63C07C217/08C07C303/32C08J5/18C08K5/19
    • C08J5/18B32B27/28C07C211/63C07C217/08C07C303/32C08K5/19C08J2323/02Y10T428/31913
    • An acid copolymer/quaternary amine mixture is disclosed which is permanently antistatic. The acid copolymer is a copolymer of (i) a major amount by mol % of an alpha-olefin of the formula RCH.dbd.CH.sub.2 wherein R is H or C.sub.1 to C.sub.8 alkyl, and (ii) a minor amount by mol % of an alpha,beta-ethylenically unsaturated carboxylic acid. The quaternary amine is of the formula [(R.sup.1)(R.sup.2)(R.sup.3)(R.sup.4)N].sup.+ [X].sup.- wherein R.sup.1 is selected from H, aryl, or C.sub.1 to C.sub.50 alkyl optionally having one or more non-contiguous C.dbd.O or NHC.dbd.O or --S-- or --O-- in the carbon chain, or the same as R.sup.2 ; each of R.sup.2, R.sup.3, and R.sup.4 is the same or different and selected from H, C.sub.1 to C.sub.18 alkyl optionally substituted with one or more OH or from --(R.sup.5 --O).sub.a --H where a is an integer from 1 to 10 and R.sup.5 is ethylene or propylene; and X is an anion selected from chloride, bromide, iodide, nitrate, fluoborate, phosphate, C.sub.1 to C.sub.8 alkyl phosphate, sulfate, C.sub.1 to C.sub.8 alkyl sulfate, formate, C.sub.1 to C.sub.8 alkyl or C.sub.6 to C.sub.24 alkaryl or aryl sulfonate, acetate, citrate, trifluoroacetate, propionate, tartrate or carbonate.
    • 公开了一种永久抗静电的酸共聚物/季胺混合物。 酸共聚物是(i)主要含摩尔%的式RCH = CH 2的α-烯烃,其中R是H或C 1至C 8烷基的共聚物,和(ii)少量的摩尔%的α ,β-烯属不饱和羧酸。 季胺具有式[(R 1)(R 2)(R 3)(R 4)N] + [X] - 其中R 1选自H,芳基或任选具有一个或多个不连续C = O或NHC = O或-S-或-O-,或与R2相同; R 2,R 3和R 4各自相同或不同,并且选自H,任选被一个或多个OH取代的C 1至C 18烷基或 - (R 5 -O)a H,其中a是1至10的整数,R 5是 乙烯或丙烯; X为阴离子,选自氯化物,溴化物,碘化物,硝酸盐,氟硼酸盐,磷酸盐,C1至C8烷基磷酸盐,硫酸盐,C1至C8烷基硫酸盐,甲酸盐,C1至C8烷基或C6至C24烷芳基或芳基磺酸盐, 柠檬酸盐,三氟乙酸盐,丙酸盐,酒石酸盐或碳酸盐。
    • 85. 发明授权
    • No-post-cure method of curing polyacrylate polymers
    • 固化聚丙烯酸酯聚合物的后固化方法
    • US5081194A
    • 1992-01-14
    • US684782
    • 1991-04-15
    • Fred R. Wolf
    • Fred R. Wolf
    • C08K5/00C08K5/19C08K5/50
    • C08K5/19C08K5/0025C08K5/50
    • A no-post-cure method of curing polyacrylates having dual cure sites is accomplished with a two-part curing system or a combined one-part curing system. The two-part curing system consists of one or more metallic acid salts and an ammonium and/or phosphonium quaternary salt. The one-part curing system consists of an ammonium or phosphonium quaternary acid salt. The polyacrylate rubber must have both a halogen and a carboxyl cure site. The method consists of blending the curative with the polyacrylate rubber and heating the resultant composition until the composition cures. Because the mixed composition is shelf stable, it is not necessary to immediately heat the composition to cure it. The method may optionally include the step of storing the mixed composition until it is desired to cure it.
    • 具有双重固化位点的固化聚丙烯酸酯的无后固化方法通过两部分固化体系或组合的一部分固化体系实现。 两部分固化体系由一种或多种金属酸盐和铵和/或鏻季盐组成。 一部分固化体系由铵或鏻季铵盐组成。 聚丙烯酸酯橡胶必须同时具有卤素和羧基固化部位。 该方法包括将固化剂与聚丙烯酸酯橡胶混合并加热所得组合物直到组合物固化。 由于混合组合物是稳定的,所以不需要立即加热组合物来固化。 该方法可以任选地包括存储混合组合物的步骤,直到需要使其固化。
    • 88. 发明授权
    • No-post-cure method of curing polyacrylate polymers
    • 固化聚丙烯酸酯聚合物的后固化方法
    • US5008345A
    • 1991-04-16
    • US551098
    • 1990-05-18
    • Fred R. Wolf
    • Fred R. Wolf
    • C08K5/00C08K5/19C08K5/50
    • C08K5/19C08K5/0025C08K5/50
    • A no-post-cure method of curing polyacrylates having dual cure sites is accomplished with a two-part curing system or a combined one-part curing system. The two-part curing system consists of one of more metallic acid salts and an ammonium and/or phosphonium quaternary salt. The one-part curing system consists of an ammonium or phosphonium quaternary acid salt. The polyacrylate rubber must have both a halogen and a carboxyl cure site. The method consists of blending the curative with the polyacrylate rubber and heating the resultant composition until the composition cures. Because the mixed composition is shelf stable, it is not necessary to immediately heat the composition to cure it. The method may optionally include the step of storing the mixed composition until it is desired to cure it.
    • 具有双重固化位点的固化聚丙烯酸酯的无后固化方法通过两部分固化体系或组合的一部分固化体系实现。 两部分固化体系由更多的金属酸盐和铵和/或鏻季盐组成。 一部分固化体系由铵或鏻季铵盐组成。 聚丙烯酸酯橡胶必须同时具有卤素和羧基固化部位。 该方法包括将固化剂与聚丙烯酸酯橡胶混合并加热所得组合物直到组合物固化。 由于混合组合物是稳定的,所以不需要立即加热组合物来固化。 该方法可以任选地包括存储混合组合物的步骤,直到需要使其固化。